Supplemental Material: Ordovician–Silurian back-arc silicic magmatism in the southernmost Appalachians

Sample Preparation and Geochemical Analysis Methodology; Table S1: Major oxide percentages for metaigneous rocks of the Wedowee-Emuckfaw-Dahlonega basin; Table S2: Measured isotope ratios and normalized U-Pb ages calculated without 204Pb Correction; Table S3: Lu-Hf isotope analyses; Table S4: Latitude-longitude (WGS84), geologic unit, and age information for samples analyzed as part of this project.

Supplemental Material: Ordovician–Silurian back-arc silicic magmatism in the southernmost Appalachians

Sample Preparation and Geochemical Analysis Methodology; Table S1: Major oxide percentages for metaigneous rocks of the Wedowee-Emuckfaw-Dahlonega basin; Table S2: Measured isotope ratios and normalized U-Pb ages calculated without 204Pb Correction; Table S3: Lu-Hf isotope analyses; Table S4: Latitude-longitude (WGS84), geologic unit, and age information for samples analyzed as part of this project.

Supplemental Material: Ordovician–Silurian back-arc silicic magmatism in the southernmost Appalachians

Sample Preparation and Geochemical Analysis Methodology; Table S1: Major oxide percentages for metaigneous rocks of the Wedowee-Emuckfaw-Dahlonega basin; Table S2: Measured isotope ratios and normalized U-Pb ages calculated without 204Pb Correction; Table S3: Lu-Hf isotope analyses; Table S4: Latitude-longitude (WGS84), geologic unit, and age information for samples analyzed as part of this project.

Supplemental Material: Ordovician–Silurian back-arc silicic magmatism in the southernmost Appalachians

Sample Preparation and Geochemical Analysis Methodology; Table S1: Major oxide percentages for metaigneous rocks of the Wedowee-Emuckfaw-Dahlonega basin; Table S2: Measured isotope ratios and normalized U-Pb ages calculated without 204Pb Correction; Table S3: Lu-Hf isotope analyses; Table S4: Latitude-longitude (WGS84), geologic unit, and age information for samples analyzed as part of this project.

Oxides for Rectenna Technology

The quest to harvest untapped renewable infrared energy sources has led to significant research effort in design, fabrication and optimization of a self-biased rectenna that can operate without external bias voltage. At the heart of its design is the engineering of a high-frequency rectifier that can convert terahertz and infrared alternating current (AC) signals to usable direct current (DC). The Metal Insulator Metal (MIM) diode has been considered as one of the ideal candidates for the rectenna system. Its unparalleled ability to have a high response time is due to the fast, femtosecond tunneling process that governs current transport. This paper presents an overview of single, double and triple insulator MIM diodes that have been fabricated so far, in particular focusing on reviewing key figures of merit, such as zero-bias responsivity (β0), zero-bias dynamic resistance (R0) and asymmetry. The two major oxide contenders for MInM diodes have been NiO and Al2O3, in combination with HfO2, Ta2O5, Nb2O5, ZnO and TiO2. The latter oxide has also been used in combination with Co3O4 and TiOx. The most advanced rectennas based on MI2M diodes have shown that optimal (β0 and R0) can be achieved by carefully tailoring fabrication processes to control oxide stoichiometry and thicknesses to sub-nanometer accuracy.

Provenance of the Sawa Formation Sandstones, Vindhyan Super Group, Southeast Rajasthan, India

Integrated petrographical and geochemical analysis of Sawa Formation sandstones was analyzed to reconstruct their source area weathering, paleoclimate, tectonic setting and provenance conditions. Petrographically, quartz is dominant detrital mineral followed by feldspar, mica, rock fragments and heavy minerals. Sawa Formation sandstones have been classified as quartzarenite with subordinate sub-arkose and sub-litharenite type. Major oxide element abundances revealed the sandstones have high SiO2 concentration, high K2O/ Na2O ratio, which is consistent with the petrographic data. These sandstones were derived mainly from stable cratonic with minor collision suture and fold thrust belt source and deposited in rifted continental margin basin setting, reflecting high maturity of sediments and high stability of the source area. The CIA, CIW and PIA values of these sandstones indicate high intensity of weathering condition in the source area under warm and humid climate.

Thermally Activated Al(OH)3: Part I—Morphology and Porosity Evaluation

Aluminum hydroxide is an essential material for the industrial production of ceramics (especially insulators and refractories), desiccants, absorbents, flame retardants, filers for plastics and rubbers, catalysts, and various construction materials. The calcination process of Al(OH)3 first induces dehydration and, finally, results in α-Al2O3 formation. Nevertheless, this process contains various intermediary steps and has been proven to be complicated due to the development of numerous transitional alumina. Each step of the investigation is vital for the entire process because the final properties of materials based on aluminum trihydroxide are determined by their phase composition, morphology, porosity, etc. In this paper, five dried, milled, and size-classified aluminum hydroxide specimens were thermally treated at 260, 300, and 400 °C; then, they were studied in order to identify the effects of temperature on their properties, such as particle morphology, specific surface area, pore size, and pore distribution. The major oxide compounds identified in all samples were characteristic of bauxite—namely, Al2O3 * 3H2O, SiO2, Fe2O3, Na2O, and CaO. Particles with smaller sizes (<10 µm = 76.28%) presented the highest humidity content (~5 wt.%), while all samples registered a mass loss of ~25 wt.% on ignition at 400 °C. The identified particles had the shapes of hexagonal or quasi-hexagonal platelets and resulted in large spherulitic concretions. The obtained results suggest that ceramic powders calcined at 400 °C should be used for applications as adsorbents or catalysts due to their high specific area of about 200–240 m2/g and their small pore width (3–3.5 nm).

Grain size analytical and geochemical data of sediments from Ishakare and Alatan streams in Akungba-Akoko, Southwestern Nigeria

The identification of anomalous elemental concentrations and the prediction of their dispersal pattern play a key role in geochemical exploration. Stream sediments are important focus in this aspect. Nine (9) sediment samples collected from Ishakare and Alatan Streams in Akungba-Akoko were subjected to grain size and inorganic geochemical analyses in order to determine their grain sizes distribution, travel distances, elemental concentrations and origin. Results of grain size analysis show that streams sediments are mostly medium-grained, poorly-moderately sorted and ranged from fine to strongly coarse skewed suggesting that they have been transported relatively not too far away from their sources under high to low energy. SiO2 is a dominant major oxide with concentration values ranging between 64.81 and 71.59 wt.% with a mean value of 68.07 wt.%. Abundance of Al2O3 indicates that samples are from Aluminum-rich source bed rock. The weights of Fe2O3 and TiO2 also point to gneissic rocks as a probable source. Generally, concentrations of trace elements were found to be low indicating that the contamination statue of the sediments ranges from unpolluted to moderately polluted

Geochemistry of the Cheremkhovo and Lower Prisayan Formations from the Jurassic Irkutsk Coal-Bearing Basin: Evidence for Provenance and Climate Change in Pliensbachian–Toarcian

The Cheremkhovo formation (Pliensbachian) is the primary coal-bearing formation of the Irkutsk basin, Eastern Siberia. Still, few geochemical studies of the Jurassic sediments of the Irkutsk coal-bearing basin have been conducted, and there are no data on the geochemistry of the coal-bearing formation itself. This study presents geochemical data for 68 samples from the Cheremkhovo formation and the overlying Lower Prisayan formation. The age of the former has been estimated by U-Pb dating of zircon from a tonstein (altered volcanic ash) layer as Pliensbachian, whereas the age of the latter is estimated as Pliensbachian–Toarcian according to regional stratigraphy. Major oxide and trace element concentrations were obtained using X-ray fluorescence spectrometry. Geochemical indicators showed diversity between the two studied formations. The indicators used show the change in climate conditions, from warm and humid in the Cheremkhovo formation, to hot and arid during the deposition of the lower Prisayan formation. The provenance of the Irkutsk coal-bearing basin was mainly influenced by the source composition, not recycling, and sediments were mainly derived from felsic to intermediate igneous rocks with a mixture of other rock types.

Cumulate gabbros in the South Andaman Island Ophiolite Suite (India): their bearing on the tectonic setting.

The Andaman Ophiolite of south-eastern India is located on the outer arc of the Andaman-Java subduction zone. It is represented by thrust slices formed in the Mesozoic Neo-Tethyan Ocean. Lithologically, it consists of dismembered mafic and ultramafic rocks and associated oceanic pelagic sediments. The present study focuses on the mafic cumulate rocks of the Andaman Ophiolite preserved in the Kodiaghat and the Mundapahar area of the South Andaman Island. The mafic cumulates are represented by olivine-bearing and olivine-free gabbros. The sequence of crystallisation in the gabbros is olivines (Fo~80) ± chromian spinels (Cr# 59 - 57), plagioclases (An95−61), clinopyroxenes (Mg# = 89 - 82) and amphiboles (Mg-hornblende, edenite and pargasite). Major oxide and trace element whole rock geochemistry and mineral compositions are consistent with a hybrid signature of Island Arc Tholeiite (IAT) - Mid Oceanic Ridge Basalt (MORB). Geochemical modelling shows that trapped melt fractions of 0 – 20 % can produce the observed trace element signatures of these gabbros. Our findings suggest that the gabbroic cumulates of the Andaman ophiolite were formed in an oceanic back-arc and oceanic arc setting developed in the Neo-Tethyan oceanic domain between the Indian and the Burmese plates during Late Cretaceous age.