Porous Organic Polymers with Built-in N-Heterocyclic Carbenes: Selective and Efficient Heterogeneous Catalyst for the Reductive N-Formylation of Amines with CO2
Bipyridyl-palladium catalyst embedded porous organic polymers (Bpy-Pd-POP) was synthesized and used as highly effective and reusable heterogeneous catalyst for the Suzuki–Miyaura coupling reaction.
The phosphorous-containing porous organic polymer is a trending material for the synthesis of heterogeneous catalysts. Decades of investigations have established phosphines as versatile ligands in homogeneous catalysis. Recently, phosphine-based heterogeneous...