ChemInform Abstract: SOLUBILITY OF OXYGEN AND SULFUR DIOXIDE IN MOLTEN SODIUM SULFATE AND OXYGEN AND CARBON DIOXIDE IN MOLTEN SODIUM CARBONATE

1979 ◽  
Vol 10 (21) ◽  
Author(s):  
R. E. ANDRESEN
Keyword(s):  
Carbon Dioxide ◽  
Sulfur Dioxide ◽  
Sodium Carbonate ◽  
Sodium Sulfate ◽  
Molten Sodium ◽  
Solubility Of Oxygen

Effect of Temperature on the Synthesis of ZrO2-Mullite Powders in Molten Sodium Sulfate

2008 ◽  
Vol 368-372 ◽  
pp. 765-767 ◽  
Author(s):  
Bo Quan Zhu ◽  
Xue Dong Li ◽  
Hou Zhi Wang
Keyword(s):  
Sodium Carbonate ◽  
Reaction Temperature ◽  
Sodium Sulfate ◽  
Aluminum Sulfate ◽  
Effect Of Temperature ◽  
Tetragonal Zro2 ◽  
Sulfate Salt ◽  
Molten Sodium ◽  
Different Temperatures

ZrO2-mullite compound powders were synthesized with zircon and aluminum sulfate in molten sodium sulfate. Na2ZrSiO5 was prepared as intermediate with zircon and sodium carbonate at 900°C for 3h. Then the mixture of resultant Na2ZrSiO5 and aluminum sulfate was heated at different temperatures in molten sodium sulfate salt. The ZrO2-Al2O3-SiO2 compound powders were obtained after washing away the solvable salts. The results showed that the compound powders synthesized at 800°C were tetragonal ZrO2, SiO2 and Al2O3; the powders synthesized at 1000°C were monoclinal ZrO2 and mullite. The mullite in compound powders became to decompose when the reaction temperature increased over 1100°C.

The effect of particle size on the reactivity of active sodium carbonate towards sulfur dioxide

1979 ◽  
Vol 44 (12) ◽  
pp. 3419-3424
Author(s):  
Karel Mocek ◽  
Erich Lippert ◽  
Dušan Husek ◽  
Emerich Erdös
Keyword(s):  
Particle Size ◽  
Sulfur Dioxide ◽  
Sodium Carbonate ◽  
Reaction Rate ◽  
Active Form ◽  
Controlling Factor ◽  
Active Sodium ◽  
Effect Of Particle Size ◽  
Integral Reactor

The effect of particle size (0.33-1.0 mm) of the sodium carbonate on the reactivity of the active sodium carbonate prepared therefrom towards the sulfur dioxide was studied in a fixedbed integral reactor at a temperature of 150 °C. The found dependence of the reaction rate on the particle size exhibits an unexpected course; at sizes of about 0.65 mm, a distinct minimum appears. The reaction rate decreases approximately ten times in the first branch of this dependence. The controlling factor of the reactivity of sodium carbonate, however, remains to be the method of preparing the active form.

The Reactivity of Different Active Forms of Sodium Carbonate with Respect to Sulfur Dioxide

1992 ◽  
Vol 57 (11) ◽  
pp. 2302-2308
Author(s):  
Karel Mocek ◽  
Erich Lippert ◽  
Emerich Erdös
Keyword(s):  
Thermal Decomposition ◽  
Liquid Phase ◽  
Sulfur Dioxide ◽  
Specific Surface ◽  
Surface Area ◽  
Sodium Carbonate ◽  
Room Temperature ◽  
Active Form ◽  
The Other ◽  
Kinetics Of

The kinetics of the reaction of solid sodium carbonate with sulfur dioxide depends on the microstructure of the solid, which in turn is affected by the way and conditions of its preparation. The active form, analogous to that obtained by thermal decomposition of NaHCO3, emerges from the dehydration of Na2CO3 . 10 H2O in a vacuum or its weathering in air at room temperature. The two active forms are porous and have approximately the same specific surface area. Partial hydration of the active Na2CO3 in air at room temperature followed by thermal dehydration does not bring about a significant decrease in reactivity. On the other hand, if the preparation of anhydrous Na2CO3 involves, partly or completely, the liquid phase, the reactivity of the product is substantially lower.

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