ChemInform Abstract: α,β-Epoxy Sulfoxides as Useful Intermediates in Organic Synthesis. Part 9. A Novel Synthesis of Alkyl Vinyl Ketones and Divinyl Ketones from Carbonyl Compounds and 1-Chloro-3-phenylthiopropyl Phenyl Sulfoxide as a Three-Carbon Homolog

10.1002/chin.198724141 ◽

1987 ◽

Vol 18 (24) ◽

Author(s):

T. SATOH ◽

T. KUMAGAWA ◽

A. SUGIMOTO ◽

K. YAMAKAWA

Keyword(s):

Organic Synthesis ◽

Carbonyl Compounds ◽

Novel Synthesis

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α,β-Epoxy Sulfoxides as Useful Intermediates in Organic Synthesis. IX. A Novel Synthesis of Alkyl Vinyl Ketones and Divinyl Ketones from Carbonyl Compounds and 1-Chloro-3-phenylthiopropyl Phenyl Sulfoxide as a Three-Carbon Homologating Agent

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.60.301 ◽

1987 ◽

Vol 60 (1) ◽

pp. 301-310 ◽

Author(s):

Tsuyoshi Satoh ◽

Takumi Kumagawa ◽

Atsushi Sugimoto ◽

Koji Yamakawa

Keyword(s):

Organic Synthesis ◽

Carbonyl Compounds ◽

Novel Synthesis

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ChemInform Abstract: α,β-Epoxy Sulfides as Useful Intermediates in Organic Synthesis. Part 6. A Novel Synthesis of Epoxides and Allylic Alcohols from Carbonyl Compounds through α,β-Epoxy Sulfoxides.

Chemischer Informationsdienst ◽

10.1002/chin.198644157 ◽

1986 ◽

Vol 17 (44) ◽

Author(s):

T. SATOH ◽

Y. KANEKO ◽

K. YAMAKAWA

Keyword(s):

Organic Synthesis ◽

Carbonyl Compounds ◽

Allylic Alcohols ◽

Novel Synthesis

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ChemInform Abstract: α,β-Epoxy Sulfoxides as Useful Intermediates in Organic Synthesis. Part 28. Novel Synthesis Including Asymmetric Synthesis of . alpha.,β-Unsaturated γ-Hydroxy Carbonyl Compounds from Enones with Carbon Homologation.

10.1002/chin.199310133 ◽

2010 ◽

Vol 24 (10) ◽

pp. no-no

Author(s):

T. SATOH ◽

S. MOTOHASHI ◽

N. TOKUTAKE ◽

K. YAMAKAWA

Keyword(s):

Asymmetric Synthesis ◽

Organic Synthesis ◽

Carbonyl Compounds ◽

Novel Synthesis

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One-Pot, Regioselective Synthesis of Homopropargyl Alcohols using Propargyl Bromide and Carbonyl Compound by the Mg-mediated Reaction under Solvent-free Conditions

Letters in Organic Chemistry ◽

10.2174/1570178616666190926104037 ◽

2020 ◽

Vol 17 (6) ◽

pp. 438-442

Author(s):

Xiaofang Ma ◽

Shunxi Li ◽

Samrat Devaramani ◽

Guohu Zhao ◽

Daqian Xu

Keyword(s):

Reaction Time ◽

Organic Synthesis ◽

Carbonyl Compounds ◽

Solvent Free ◽

Propargyl Bromide ◽

Important Goal ◽

One Pot ◽

Short Reaction Time ◽

Solvent Free Conditions ◽

Volatile Organic

The elimination of volatile organic solvents in organic synthesis is the most important goal in “Green” chemistry. We report a simple, efficient and facile method for the addition of progargyl bromide to carbonyl compounds using Mg metal as a mediator under solvent-free conditions which could regioselectively generate homopropargyl alcohols efficiently in good to excellent yields. The procedure has advantages such as short reaction time, operationally simple, excellent product yields, high regioselectivity and organic solvent-free.

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Hypervalent iodine in organic synthesis: α-functionalization of carbonyl compounds

Contemporary Organic Synthesis ◽

10.1039/co9950200121 ◽

1995 ◽

Vol 2 (2) ◽

pp. 121-131 ◽

Author(s):

Om Prakash ◽

Neena Saini ◽

Madan P. Tanwar ◽

Robert M. Moriarty

Keyword(s):

Organic Synthesis ◽

Carbonyl Compounds ◽

Hypervalent Iodine

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Fatty acid hydrazides in Organic Synthesis: Novel Synthesis of 6-alkyl-3-aryl-5-imino-7-oxo-2,5,6,7-tetrahydro-1H-1,2- diazepine-4-carbonitrile and 6-alkyl-3-aryl-5,7-dioxo-2,5,6,7-tetrahydro-1H-1,2-diazepine-4-carbonitrile

Heterocyclic Communications ◽

10.1515/hc.2003.9.3.293 ◽

2003 ◽

Vol 9 (3) ◽

Author(s):

Elham A.A. Yousef ◽

Μ.Ε.A. Zaki ◽

M.G. Megahed

Keyword(s):

Organic Synthesis ◽

Novel Synthesis

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ChemInform Abstract: METALATED NITROGEN DERIVATIVES OF CARBONIC ACID IN ORGANIC SYNTHESIS. XVI. SYNTHESIS OF 2-ALKYLIMINO- AND 2-ARYLIMINO-1,3-OXATHIOLANES FROM LITHIATED S,S′-DIALKYL IMIDODITHIOCARBONATES AND CARBONYL COMPOUNDS

Chemischer Informationsdienst ◽

10.1002/chin.198110255 ◽

1981 ◽

Vol 12 (10) ◽

Author(s):

D. HOPPE ◽

R. FOLLMANN ◽

L. BECKMANN

Keyword(s):

Organic Synthesis ◽

Carbonyl Compounds ◽

Carbonic Acid ◽

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ChemInform Abstract: Reaction of 3-Methyl-2-cyclopenten-1-one N,N-Dimethylhydrazone with . alpha.,β-Unsaturated Carbonyl Compounds. A Novel Synthesis of Bicyclic Compounds.

10.1002/chin.199313082 ◽

2010 ◽

Vol 24 (13) ◽

pp. no-no

Author(s):

K. MATSUMIYA ◽

Y. P. GUO ◽

M. YAMASHITA

Keyword(s):

Carbonyl Compounds ◽

Bicyclic Compounds ◽

Novel Synthesis

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ChemInform Abstract: Free Radicals in Organic Synthesis. A Novel Synthesis of Ethylene Glycol Based on Formaldehyde.

10.1002/chin.198802237 ◽

1988 ◽

Vol 19 (2) ◽

Author(s):

J. R. SANDERSON ◽

E. L. YEAKEY ◽

J. J. LIN ◽

R. G. DURANLEAU ◽

E. T. MARQUIS

Keyword(s):

Free Radicals ◽

Ethylene Glycol ◽

Organic Synthesis ◽

Novel Synthesis

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.alpha.,.beta.-Epoxy sulfoxides as useful intermediates in organic synthesis. 22. Stereospecific desulfinylation of sulfinylaziridines with alkylmetals: a novel synthesis including asymmetric synthesis of (Z)-N-arylaziridines and some mechanistic studies

The Journal of Organic Chemistry ◽

10.1021/jo00277a041 ◽

1989 ◽

Vol 54 (16) ◽

pp. 3973-3978 ◽

Author(s):

Tsuyoshi Satoh ◽

Takahiko Sato ◽

Teruhiko Oohara ◽

Koji Yamakawa

Keyword(s):

Asymmetric Synthesis ◽

Organic Synthesis ◽

Mechanistic Studies ◽

Novel Synthesis ◽

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