ChemInform Abstract: X-Ray Absorption (EXAFS/XANES) Study of Supported Vanadium Oxide Catalysts. Structure of Surface Vanadium Oxide Species on Silica and γ-Alumina at a Low Level of Vanadium Loading.

ChemInform ◽  
1989 ◽  
Vol 20 (2) ◽  
Author(s):  
T. TANAKA ◽  
H. YAMASHITA ◽  
R. TSUCHITANI ◽  
T. FUNABIKI ◽  
S. YOSHIDA
1996 ◽  
Vol 61 (8) ◽  
pp. 1131-1140 ◽  
Author(s):  
Abd El-Aziz Ahmed Said

Vanadium oxide catalysts doped or mixed with 1-50 mole % Fe3+ ions were prepared. The structure of the original samples and those calcined from 200 up to 500 °C were characterized by TG, DTA, IR and X-ray diffraction. The SBET values and texture of the solid catalysts were investigated. The catalytic dehydration-dehydrogenation of isopropanol was carried out at 200 °C using a flow system. The results obtained showed an observable decrease in the activity of V2O5 on the addition of Fe3+ ions. Moreover, Fe2V4O13 is the more active and selective catalyst than FeVO4 spinels. The results were correlated with the active sites created on the catalyst surface.


2009 ◽  
Vol 64 (3) ◽  
pp. 281-286 ◽  
Author(s):  
Suliman Nakhal ◽  
Wilfried Hermes ◽  
Thorsten Ressler ◽  
Rainer Pöttgen ◽  
Martin Lerch

Ammonolysis of vanadium sulfide leads to the formation of bixbyite-type vanadium oxide nitrides. Small amounts of nitrogen incorporated in the structure result in the stabilization of the bixbyite type not known for vanadium oxides. The crystal structure was investigated using X-ray diffraction and X-ray absorption spectroscopy. At temperatures above 550 °C the powders decompose to corundumtype V2O3 containing no detectable amount of nitrogen. Below 39 K magnetic ordering is observed.


2021 ◽  
Vol 62 (1) ◽  
pp. 160-171
Author(s):  
A. M. Kremneva ◽  
A. V. Fedorov ◽  
A. A. Saraev ◽  
O. A. Bulavchenko ◽  
V. A. Yakovlev ◽  
...  

ChemInform ◽  
2005 ◽  
Vol 36 (27) ◽  
Author(s):  
Guido Schimanke ◽  
Manfred Martin ◽  
Jan Kunert ◽  
Herbert Vogel

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