Investigation of silica-supported vanadium oxide catalysts: preparation and characterization by vanadium-51 NMR and x-ray photoelectron spectroscopy

1988 ◽  
Vol 92 (23) ◽  
pp. 6700-6705 ◽  
Author(s):  
B. Taouk ◽  
M. Guelton ◽  
J. Grimblot ◽  
J. P. Bonnelle
1996 ◽  
Vol 61 (8) ◽  
pp. 1131-1140 ◽  
Author(s):  
Abd El-Aziz Ahmed Said

Vanadium oxide catalysts doped or mixed with 1-50 mole % Fe3+ ions were prepared. The structure of the original samples and those calcined from 200 up to 500 °C were characterized by TG, DTA, IR and X-ray diffraction. The SBET values and texture of the solid catalysts were investigated. The catalytic dehydration-dehydrogenation of isopropanol was carried out at 200 °C using a flow system. The results obtained showed an observable decrease in the activity of V2O5 on the addition of Fe3+ ions. Moreover, Fe2V4O13 is the more active and selective catalyst than FeVO4 spinels. The results were correlated with the active sites created on the catalyst surface.


2003 ◽  
Vol 15 (16) ◽  
pp. 3227-3232 ◽  
Author(s):  
Sara Nordlinder ◽  
Andreas Augustsson ◽  
Thorsten Schmitt ◽  
Jinghua Guo ◽  
Laurent C. Duda ◽  
...  

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