The Building Block [FeIII(pzphen)(CN)4]-and its Lanthanide Complexes: Synthesis, Crystal Structure, and Magnetic Properties

2016 ◽  
Vol 642 (24) ◽  
pp. 1466-1471 ◽  
Author(s):  
Jian-Qing Tao ◽  
Wen-Wen Ju ◽  
Zhou Zhou ◽  
Li-Yong Jia ◽  
Ning-Ning Chen ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Building Block ◽  
Lanthanide Complexes

Synthesis, Characterization, Crystal Structure and Magnetic Properties of [(en)CuII(ImH)2](ClO4)2 (en = Ethylenediamine, ImH = Imidazole): A Metalloligand as a Building Block for Heterometal Chains

2003 ◽  
Vol 58 (6) ◽  
pp. 505-510 ◽  
Author(s):  
Thorsten Glaser ◽  
Maik Heidemeier ◽  
F. Ekkehardt Hahn ◽  
Tania Pape ◽  
Thomas Lügger
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Building Block ◽  
Exchange Interactions ◽  
High Yield ◽  
Magnetic Data ◽  
X Ray ◽  
X Ray Crystallography ◽  
Structural And Electronic Properties ◽  
Dark Blue

The reaction of Cu(ClO4)2·6H2O, imidazole (ImH), and ethylenediamine (en) in a 1 : 2 : 1 ratio afforded in high yield dark-blue single-crystals of [(en)CuII(ImH)2](ClO4)2, 1, which can be used after deprotonation as a building block for heterometallic ferrimagnetic chains. The structural and electronic properties of 1 were examined by X-ray crystallography, FTIR, ESI-MS, electrochemistry, UV/vis/NIR, EPR, and magnetic susceptibility measurements. The structure of 1 exhibits intermolecular π-π interactions and hydrogen bonds but the magnetic data exclude the presence of intermolecular exchange interactions.

Synthesis, crystal structure and magnetic properties of a cyanide-bridged FeIII–MnIII bimetallic chain based on [Fe(bipy)(CN)4]− building block

2009 ◽  
Vol 921 (1-3) ◽  
pp. 341-345 ◽  
Author(s):  
Yan Xu ◽  
Xiao-Ping Shen ◽  
Hu Zhou ◽  
He-Qing Shu ◽  
Wenxian Li ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Building Block
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