Recent Advances in Homogeneous Hydrogenation of Carbon-Carbon Multiple Bonds

1970 ◽  
pp. 3-75 ◽  
Author(s):  
R. S. Coffey
Keyword(s):  
Homogeneous Hydrogenation ◽  
Multiple Bonds ◽  
Recent Advances

ChemInform Abstract: Recent Advances in the Chemistry of Silicon-Heteroatom Multiple Bonds

ChemInform ◽  
2010 ◽  
Vol 30 (15) ◽  
pp. no-no
Author(s):  
Norihiro Tokitoh ◽  
Renji Okazaki
Keyword(s):  
Multiple Bonds ◽  
Recent Advances

The homogeneous hydrogenation of carbon-carbon multiple bonds with heteronuclear platinum clusters

1982 ◽  
Vol 308 (1501) ◽  
pp. 125-130 ◽  
Keyword(s):  
Selective Hydrogenation ◽  
Homogeneous Hydrogenation ◽  
Multiple Bonds ◽  
Molecular Rearrangements ◽  
Platinum Clusters ◽  
Terminal Acetylenes

The heteronuclear platinum clusters Pt 2 CO 2 (CO) 8 (PPh 3 ) 2 and Pt(C 6 H 11 NC) 2 [Mo(CO) 3 (n 5 -C 5 H 5 )] 2 are poor catalysts for the hydrogenation of olefins and internal acetylenes, but they show a reasonable activity for the hydrogenation of terminal acetylenes. In this latter case the selectivity towards olefins is low. Whereas the PtMo 2 cluster can be recovered unaltered from the reaction mixture, the Pt 2 CO 2 cluster undergoes rather complex molecular rearrangements, which take place under the catalytic conditions. Finally the Pt 2 CO 2 cluster, under well defined conditions, may act as a catalyst for the selective hydrogenation of diphenylacetylene to cis -stilbene.

Ruthenium-catalysed hydrosilylation of carbon–carbon multiple bonds

2016 ◽  
Vol 3 (10) ◽  
pp. 1337-1344 ◽  
Author(s):  
M. Zaranek ◽  
B. Marciniec ◽  
P. Pawluć
Keyword(s):  
Organic Synthesis ◽  
Multiple Bonds ◽  
Recent Advances

Recent advances in ruthenium-catalysed hydrosilylation of C–C multiple bonds and its application to organic synthesis are highlighted.

ChemInform Abstract: Recent Advances in Heterobimetallic Palladium(II)/Copper(II) Catalyzed Domino Difunctionalization of Carbon-Carbon Multiple Bonds

ChemInform ◽  
2014 ◽  
Vol 45 (40) ◽  
pp. no-no
Author(s):  
Egle M. Beccalli ◽  
Gianluigi Broggini ◽  
Silvia Gazzola ◽  
Alberto Mazza
Keyword(s):  
Multiple Bonds ◽  
Recent Advances

scholarly journals Recent advances in the gold-catalyzed additions to C–C multiple bonds

2011 ◽  
Vol 7 ◽  
pp. 897-936 ◽  
Author(s):  
He Huang ◽  
Yu Zhou ◽  
Hong Liu
Keyword(s):  
Organic Compounds ◽  
Lewis Acid ◽  
Gold Catalysis ◽  
Advanced Materials ◽  
Tandem Reactions ◽  
Multiple Bonds ◽  
Recent Advances ◽  
Asymmetric Additions ◽  
New Strategies ◽  
Cationic Gold

C–O, C–N and C–C bonds are the most widespread types of bonds in nature, and are the cornerstone of most organic compounds, ranging from pharmaceuticals and agrochemicals to advanced materials and polymers. Cationic gold acts as a soft and carbophilic Lewis acid and is considered one of the most powerful activators of C–C multiple bonds. Consequently, gold-catalysis plays an important role in the development of new strategies to form these bonds in more convenient ways. In this review, we highlight recent advances in the gold-catalyzed chemistry of addition of X–H (X = O, N, C) bonds to C–C multiple bonds, tandem reactions, and asymmetric additions. This review covers gold-catalyzed organic reactions published from 2008 to the present.

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