Multinary Thioantimonates(III) with d10 Transition Metals: Ionothermal Synthesis, Crystal Structures and Physical Properties

2021 ◽  
Author(s):  
Gang Yang ◽  
Chao Wu ◽  
Jinfang Zhang ◽  
Chi Zhang
Keyword(s):  
Transition Metals ◽  
Physical Properties ◽  
Crystal Structures ◽  
Ionothermal Synthesis

scholarly journals Crystal-to-Crystal Transformation from K2[Co(C2O4)2(H2O)2]·4H2O to K2[Co(μ-C2O4)(C2O4)]

2021 ◽  
Vol 7 (6) ◽  
pp. 77
Author(s):  
Bin Zhang ◽  
Yan Zhang ◽  
Guangcai Chang ◽  
Zheming Wang ◽  
Daoben Zhu
Keyword(s):  
Hydrogen Bond ◽  
Physical Properties ◽  
Crystal Structures ◽  
Molecular Crystal ◽  
Trigonal Prism ◽  
Space Group ◽  
Cell Parameters ◽  
Oxalate Anion ◽  
Crystal Transformation ◽  
Antiferromagnetic Ordering

Crystal-to-crystal transformation is a path to obtain crystals with different crystal structures and physical properties. K2[Co(C2O4)2(H2O)2]·4H2O (1) is obtained from K2C2O4·2H2O, CoCl2·6H2O in H2O with a yield of 60%. It is crystallized in the triclinic with space group P1 and cell parameters: a = 7.684(1) Å, b = 9.011(1) Å, c = 10.874(1) Å, α = 72.151(2)°, β = 70.278(2)°, γ = 80.430(2)°, V = 670.0(1) Å3, Z = 2 at 100 K. 1 is composed of K+, mononuclear anion [Co(C2O4)2(H2O)22−] and H2O. Co2+ is coordinated by two bidentated oxalate anion and two H2O in an octahedron environment. There is a hydrogen bond between mononuclear anion [Co(C2O4)2(H2O)22−] and H2O. K2[Co(μ-C2O4)(C2O4)] (2) is obtained from 1 by dehydration. The cell parameters of 2 are a = 8.460(5) Å, b = 6.906 (4) Å, c = 14.657(8) Å, β = 93.11(1)°, V = 855.0(8) Å3 at 100 K, with space group in P2/c. It is composed of K+ and zigzag [Co(μ-C2O4)(C2O42−]n chain. Co2+ is coordinated by two bisbendentate oxalate and one bidentated oxalate anion in trigonal-prism. 1 is an antiferromagnetic molecular crystal. The antiferromagnetic ordering at 8.2 K is observed in 2.

scholarly journals Intermolecular interaction energies in transition metal coordination compounds

CrystEngComm ◽  
2015 ◽  
Vol 17 (48) ◽  
pp. 9300-9310 ◽  
Author(s):  
Andrew G. P. Maloney ◽  
Peter A. Wood ◽  
Simon Parsons
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Crystal Structures ◽  
Intermolecular Interaction ◽  
Coordination Compounds ◽  
Metal Coordination ◽  
Interaction Energies

The PIXEL method has been parameterised and validated for transition metals, extending its applicability from ~40% to ~85% of all published crystal structures.

Physical properties of some ternary Ce intermetallics with the transition metals Ni and Pd

1993 ◽  
Vol 128 (1-2) ◽  
pp. 124-128 ◽  
Author(s):  
R.J. Cava ◽  
A.P. Ramirez ◽  
H. Takagi ◽  
J.J. Krajewski ◽  
W.F. Peck
Keyword(s):  
Transition Metals ◽  
Physical Properties

Die Kristallstrukturen der isotypen Verbindungen Ba3[MoN4] und Ba3[WN4] / The Crystal Structures of the Isotypic Compounds Ba3[MoN4] and Ba3[WN4]

1991 ◽  
Vol 46 (5) ◽  
pp. 566-572 ◽  
Author(s):  
Axel Gudat ◽  
Peter Höhn ◽  
Rüdiger Kniep ◽  
Albrecht Rabenau
Keyword(s):  
Transition Metals ◽  
Single Crystal ◽  
Crystal Structures ◽  
Structure Type ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ternary Compounds ◽  
The Third

The isotypic ternary compounds Ba3[MoN4] and Ba3[WN4] were prepared by reaction of the transition metals with barium (Ba3N2, resp.) under nitrogen. The crystal structures were determined by single crystal X-ray diffraction: Ba3[MoN4] (Ba3[WN4]): Pbca; Z = 8; a = 1083.9(3) pm (1091.8(3) pm), b = 1030.3(3) pm (1037.5(3) pm), c = 1202.9(3) pm (1209.2(4) pm). The structures contain isolated tetrahedral anions [MN4]6- (M = Mo, W) which are arranged in form of slightly distorted hexagonal layers and which are stacked along [010] with the sequence (···AB···). Two of the three Ba atoms are situated between, the third one is placed within the layers of [MN4]-groups. In this way the structures can be derived from the Na3As structure type.

Coordination of β-Ketoimine-Derived Ligands at Main Group and Transition Metals

2015 ◽  
Vol 68 (4) ◽  
pp. 641 ◽  
Author(s):  
Struan J. W. Cummins ◽  
H. Putri Fraser ◽  
J. Robin Fulton ◽  
Martyn P. Coles ◽  
Christopher M. Fitchett
Keyword(s):  
Transition Metals ◽  
Oxygen Atom ◽  
Crystal Structures ◽  
Main Group ◽  
Neutral Form ◽  
Tertiary Butyl ◽  
A Minor ◽  
Gallium Compounds

The β-ketoimine HC[MeC(O)][MeC(NHt-Bu)] (1H) (Me = methyl) was used as a ligand in the synthesis of organo-aluminium and gallium compounds. With Al, the NH functionality was deprotonated to form the N,O-chelating β-ketoiminate ligand in Al{HC[MeC(O)][MeC(Nt-Bu)]}Me2 (3) (t-Bu = tertiary butyl), whereas the neutral form coordinated to trimethylgallium via the oxygen atom to form the adduct GaMe3·{HC[MeC(O)][MeC(NHt-Bu)]} (4). Reaction of 1H with Ar†NH2 (Ar† = 2-t-BuC6H4) afforded the new N-aryl β-ketoimine HC[MeC(O)][MeC(NHAr†)] (2H), which reacted with Pd(OAc)2 (OAc = acetate = CH3CO2–) to afford the heteroleptic dimer {Pd[HC(MeC(O))(MeC(NAr†))](μ-OAc)}2 ([5]2). The homoleptic bis(β-ketoiminate) Pd{HC[MeC(O)][MeC(NAr†)]}2 (6) was isolated as a minor product of this reaction. The crystal structures of compounds 3, 4, [5]2, and 6 are reported.

scholarly journals PHYSICAL PROPERTIES AND CRYSTAL STRUCTURES OF POLY (META, PARA-XYLYLENE ADIPAMIDE) COPOLYMER

1973 ◽  
Vol 29 (9) ◽  
pp. T392-T404
Author(s):  
Youichi Kawaguchi ◽  
Masayoshi Shimada ◽  
Fumihide Fujimoto
Keyword(s):  
Physical Properties ◽  
Crystal Structures

Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe3Se8, K3Ga3Ge7S20, and K3Ga3Ge7Se20

2016 ◽  
Vol 45 (2) ◽  
pp. 532-538 ◽  
Author(s):  
Xiaoshuang Li ◽  
Chao Li ◽  
Pifu Gong ◽  
Zheshuai Lin ◽  
Jiyong Yao ◽  
...  
Keyword(s):  
Physical Properties ◽  
Crystal Structures ◽  
Layered Structure

NaGaGe3Se8 has a layered structure, while K3Ga3Ge7Q20 (Q = S, Se) are constructed by incompletely isolated quasi-2D layers, leading to large channels loosely occupied by K+ cations.

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