Syntheses and Structural Characterization of Triorganotin Derivatives of 3-Mercapto-4-methyl-4H-1,2,4-triazol: X-ray Crystal Structures of One-dimensional Zigzag Polymeric chain of Me3Sn[SC3H4N3] and Ph3Sn[SC3H4N3]

2006 ◽  
Vol 16 (2) ◽  
pp. 139-145 ◽  
Author(s):  
Chunlin Ma ◽  
Guangru Tian ◽  
Rufen Zhang
Keyword(s):  
Crystal Structures ◽  
Structural Characterization ◽  
Polymeric Chain ◽  
One Dimensional ◽  
X Ray ◽  
Derivatives Of

Synthesis of tetraarylborates via tetralithio intermediates and the effect of polar functional groups and cations on their crystal structures

2018 ◽  
Vol 47 (46) ◽  
pp. 16627-16637 ◽  
Author(s):  
Patryk Tomaszewski ◽  
Marcin Wiszniewski ◽  
Janusz Serwatowski ◽  
Krzysztof Woźniak ◽  
Krzysztof Durka ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Functional Groups ◽  
Structural Characterization ◽  
X Ray ◽  
Polar Functional Groups

The synthesis and X-ray structural characterization of functionalized (COOH, CHO, C(O)NHtBu, B(OH)2) tetraphenyl- and tetrakis(4′-biphenylyl)borates is reported.

scholarly journals Synthesis and Structural Characterization of a Series of One-Dimensional Heteronuclear Dirhodium-Silver Coordination Polymers

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 111 ◽  
Author(s):  
Paula Cruz ◽  
Estefania Fernandez-Bartolome ◽  
Miguel Cortijo ◽  
Patricia Delgado-Martínez ◽  
Rodrigo González-Prieto ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Structural Characterization ◽  
Similar Reaction ◽  
Molecular Compound ◽  
Silver Complexes ◽  
One Dimensional ◽  
Wavy Structure ◽  
Solvent Molecules

Herein, we describe the preparation of heteronuclear dirhodium-silver complexes by reaction between molecular Rh(II)-Rh(II) compounds [Rh2(μ-O2CR)4L2] (R = Me, Ph (1), CH2OEt (2); L = solvent molecules) with paddlewheel structure and PPh4[Ag(CN)2]. One-dimensional coordination polymers of (PPh4)n[Rh2(μ-O2CR)4Ag(CN)2]n (R = Me (3), Ph (4), CH2OEt (5)) formula have been obtained by replacement of the two labile molecules in the axial positions of the paddlewheel structures by a [Ag(CN)2]− bridging unit. The crystal structures of 3–5 display a similar arrangement, having anionic chains with a wavy structure and bulky (PPh4)+ cations placed between the chains. The presence of the (PPh4)+ cations hinders the existence of intermolecular Ag-Ag interactions although several C-H····π interactions have been observed. A similar reaction between [Rh2(μ-O2CCMe3)4(HO2CCMe3)2] and PPh4[Ag(CN)2] led to the molecular compound (PPh4)2{Rh2(μ-O2CCMe3)4[Ag(CN)2]2} (6) by replacement of the axial HO2CCMe3 ligands by two [Ag(CN)2]− units. The trimethylacetate ligand increases the solubility of the complex during the crystallization favouring the formation of discrete heteronuclear species.

One- and two-dimensional PbII compounds resulting from reaction of PbBr2 and Pb(SCN)2 with pyrimidine-2-thione

2021 ◽  
Vol 77 (7) ◽  
Author(s):  
Vânia Denise Schwade ◽  
Bárbara Tirloni
Keyword(s):  
Structural Characterization ◽  
Diffuse Reflectance ◽  
Tautomeric Form ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Ft Ir ◽  
Compound Ii

Pyrimidine-2-thione (HSpym) reacts with lead(II) thiocyanate and lead(II) bromide in N,N-dimethylformamide (DMF) to form poly[(μ-isothiocyanato-κ2 N:S)(μ4-pyrimidine-2-thiolato-κ6 N 1,S:S:S:S,N 3)lead(II)], [Pb(C4H3N2S)(NCS)] n or [Pb(Spym)(NCS)] n , (I), and the polymeric one-dimensional (1D) compound catena-poly[[μ4-bromido-di-μ-bromido-(μ-pyrimidine-2-thiolato-κ3 N 1,S:S)(μ-pyrimidine-2-thione-κ3 N 1,S:S)dilead(II)] N,N-dimethylformamide monosolvate], {[Pb2Br3(C4H3N2S)(C4H4N2S)]·C3H7NO} n or {[Pb2Br3(Spym)(HSpym)]·DMF} n , (IIa), respectively. Poly[μ4-bromido-di-μ3-bromido-(μ-pyrimidine-2-thiolato-κ3 N 1,S:S)(μ-pyrimidine-2-thione-κ3 N 1,S:S)dilead(II)], [Pb2Br3(C4H3N2S)(C4H4N2S)] n or [Pb2Br3(Spym)(HSpym)] n , (IIb), could be obtained as a mixture with (IIa) when using a lesser amount of solvent. In the crystal structures of the pseudohalide/halide PbII stable compounds, coordination of anionic and neutral HSpym has been observed. Both Spym− (in the thiolate tautomeric form) and NCS− ligands were responsible for the two-dimensional (2D) arrangement in (I). The Br− ligands establish the 1D polymeric arrangement in (IIa). Eight-coordinated metal centres have been observed in both compounds, when considering the Pb...S and Pb...Br interactions. Both compounds were characterized by FT–IR and diffuse reflectance spectroscopies, as well as by powder X-ray diffraction. Compound (IIa) and its desolvated version (IIb) represent the first structurally characterized PbII compounds containing neutral HSpym and anionic Spym− ligands. After a prolonged time in solution, (IIa) is converted to another compound due to complete deprotonation of HSpym. The structural characterization of (I) and (II) suggests HSpym as a good candidate for the removal of PbII ions from solutions containing thiocyanate or bromide ions.

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