Preparation of isotropic pitch precursors for general purpose carbon fibers (GPCF) by air blowing—I. Preparation of spinnable isotropic pitch precursor from coal tar by air blowing

Carbon ◽  
1993 ◽  
Vol 31 (3) ◽  
pp. 407-412 ◽  
Author(s):  
Toyohiro Maeda ◽  
Shu Ming Zeng ◽  
Katsuhisa Tokumitsu ◽  
Juji mondori ◽  
Isao Mochida
Carbon ◽  
1993 ◽  
Vol 31 (3) ◽  
pp. 413-419 ◽  
Author(s):  
Shu Ming Zeng ◽  
Toyohiro Maeda ◽  
Katsuhisa Tokumitsu ◽  
Juji Mondori ◽  
Isao Mochida

Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6280
Author(s):  
Seon Ho Lee ◽  
Song Mi Lee ◽  
Seungjoo Park ◽  
Seong-Ho Yoon ◽  
Haksoo Han ◽  
...  

An inexpensive and general-purpose carbon fiber was prepared using coal tar pitch. In contrast to the solvent extraction process employing expensive solvents, a low-cost centrifugal separation method facilitated the reduction of loss due to the pitch purification and an overall yield increase. The coal tar pitch purified by centrifugation and subsequently co-carbonized with pyrolysis fuel oil improved in spinnability. Moreover, the resulting spinnable pitch had a softening point of 250 °C. The obtained carbon fibers were heat-treated at 1000 °C for 5 min, resulting in a tensile strength of approximately 1000 MPa and an average diameter of 9 μm. In this study, we present an effective method for obtaining low-cost general-purpose isotropic carbon fibers.


2012 ◽  
Vol 182-183 ◽  
pp. 198-202
Author(s):  
Zhi Wu Yang ◽  
Jia Ming Zheng ◽  
Ming Ming Chen ◽  
Cheng Yang Wang

In this paper, besides the single method of air blowing and thermal condensation, a new two-step combining method was taken to modulate the pitch precursor for carbon fibers: the ethylene tar pitch was first air-blown under 280 °C for 10 h, and then thermal-condensed in nitrogen under 380 °C. Then group composition, elemental and thermal analysis, FT-IR, SEM and polarized optical micrographs were used in this paper, and the influence of different methods of modulation on the performance of pitches was discussed. The results revealed that neither in the method of air blowing nor thermal treatment can the pitch with a high softening point and coking value but no mesophase be produced. However, isotropic spinnable pitch with high softening point (286 °C), coking value (80.2%) and superior thermal stabilities can be synthesized in the two-step combining method. Carbon fibers from such pitches had been produced through melt-spinning, stabilization and carbonization, they showed uniform diameters (about 15.5 μm) with smooth and homogeneous surfaces. After stabilization and carbonization, the shrinkage of carbon fibers’ diameter was limited to 6%.


TANSO ◽  
2000 ◽  
Vol 2000 (194) ◽  
pp. 248-253 ◽  
Author(s):  
Juji Mondori ◽  
Chiharu Yamaguchi ◽  
Isao Mochida

Carbon ◽  
1997 ◽  
Vol 35 (8) ◽  
pp. 1079-1087 ◽  
Author(s):  
J. Alcañiz-Monge ◽  
D. Cazorla-Amorós ◽  
A. Linares-Solano ◽  
A. Oya ◽  
A. Sakamoto ◽  
...  

2021 ◽  
Vol 11 (16) ◽  
pp. 7223
Author(s):  
Dengyu Xiong ◽  
Mingliang Wu ◽  
Wei Xie ◽  
Rong Liu ◽  
Haifeng Luo

To address the problems of high damage rate, low seeding accuracy, and poor seeding generally in the seeding process, a general-purpose seeding device was designed in this study based on the principle of mechanical pneumatic combined seeding. The air-blowing-type cleaning and seed unloading of the device laid the conditions for precise seeding and flexible seeding. In addition, single-factor experiments were performed on seeds (e.g., soybeans, corn, and rape-seeds) with different particle sizes and shapes to verify the general properties of the seed metering device. A multi-factor response surface optimization experiment was performed by applying soybean seeds as the test object to achieve the optimal performance parameters of the seed metering device. At a seed-clearing air velocity of 16.7 m/s, a seed feeding drum speed of 13.7 r/min, and a hole cone angle of 35.6°, corresponding to the optimal performance index, the qualified index, the replay index, and the missed index reached 97.94%, 0.03%, and 2.03%, respectively. The verification test results are consistent with the optimized ones. As indicated from the results, the seed metering device exhibits good general properties, low damage rate, great precision, and high efficiency; it is capable of meeting general seeding operations of different crop seeds and technically supporting for the reliability and versatility of the seeder.


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