Weathering of an argillaceous rock in the presence of atmospheric conditions: A flow-through experiment and modelling study

2018 ◽  
Vol 96 ◽  
pp. 252-263 ◽  
Author(s):  
Nicolas C.M. Marty ◽  
Adeline Lach ◽  
Catherine Lerouge ◽  
Sylvain Grangeon ◽  
Francis Claret ◽  
...  
1997 ◽  
Vol 36 (6-7) ◽  
pp. 311-316 ◽  
Author(s):  
J. C. Van den Heuvel ◽  
E. E. Beuling ◽  
D. Van Dusschoten ◽  
O. L. Roosenschoon ◽  
P. G. Verschuren

Gas bubbles entrapped in biocatalyst particles subjected to hydrostatic pressure oscillations, e.g. during recirculation in loop reactors, will induce intraparticle liquid flows, and thereby enhance mass transfer in excess of diffusion. This ‘breathing particle’ mechanism was already demonstrated in methanogenic granules from an IC reactor, and led to an average macroscopic activity increase of 13%. The existence of the alternating convective liquid flow responsible for this higher activity has now been established independently with pulsed field gradient NMR, as the intraparticle water mobility during pressure oscillations was found 16.5% larger. Micro-electrode measurements of the internal pH of a granule revealed the occurrence of a fast liquid flow through a channel between a central cavity and the periphery during pressure cycling, and the subsequent diffusive relaxation under atmospheric conditions.


2021 ◽  
Author(s):  
Stanislaus J. Schymanski ◽  
Benjamin Dewals ◽  
Henk A. Dijkstra ◽  
Hisashi Ozawa ◽  
Erwin Zehe

<p>Ecohydrological systems are a result of long-term co-evolution of soils, biota and atmospheric conditions, and often respond to perturbations in non-intuitive ways. Their short-term responses can be explained and sometimes predicted if we understand the underlying dynamic processes and if we can observe the initial state precisely enough. However, how do they co-evolve in the long-term after a change in the boundary conditions? In 1922, Alfred Lotka hypothesised that the natural selection governing the evolution of biota and composition of ecosystems may be obeying some thermodynamic principles related to maximising energy flow through these systems. Similar thoughts have been formulated for various components of the Earth system and individual processes, such as heat transport in the atmosphere and oceans, erosion and sediment transport in river systems and estuaries, the formation of vegetation patterns, and many others. Different thermodynamic optimality principles have been applied to predict or explain a given system property or behaviour, of which the maximum entropy production and the maximum power principles are most widespread. However, the different studies did not use a common systematic approach for the formulation of the relevant system boundaries, state variables and exchange fluxes, resulting in considerable ambiguity about the application of thermodynamic optimality principles in the scientific community. Such a systematic framework has been developed recently and can be tested online at:</p><p><span><span>https://renkulab.io/projects/stanislaus.schymanski/thermodynamic_optimality_blueprint</span></span></p><p>In the present study, we illustrate how such a common framework can be used to classify and compare different applications of thermodynamic optimality principles in the literature, and discuss the insights gained and key criteria for a more rigorous testing of such principles.</p>


1985 ◽  
Vol 107 (3) ◽  
pp. 202-207 ◽  
Author(s):  
F. Haghighat ◽  
T. E. Unny ◽  
M. Chandrashekar

Solar radiation and temperature vary during the day. These variations are also subject to “random” fluctuations caused by rapid changes in atmospheric conditions. In this paper a procedure has been developed to model the rate of heat flow through a building wall with consideration given to the stochastic character of the problem. The stochastic method generates outputs that reflect fluctuations in the input variables (and parameters). This enables the analyst to select or design components for specified confidence levels. The validity of the procedure is demonstrated through examples.


Author(s):  
Richard L. Leino ◽  
Jon G. Anderson ◽  
J. Howard McCormick

Groups of 12 fathead minnows were exposed for 129 days to Lake Superior water acidified (pH 5.0, 5.5, 6.0 or 6.5) with reagent grade H2SO4 by means of a multichannel toxicant system for flow-through bioassays. Untreated water (pH 7.5) had the following properties: hardness 45.3 ± 0.3 (95% confidence interval) mg/1 as CaCO3; alkalinity 42.6 ± 0.2 mg/1; Cl- 0.03 meq/1; Na+ 0.05 meq/1; K+ 0.01 meq/1; Ca2+ 0.68 meq/1; Mg2+ 0.26 meq/1; dissolved O2 5.8 ± 0.3 mg/1; free CO2 3.2 ± 0.4 mg/1; T= 24.3 ± 0.1°C. The 1st, 2nd and 3rd gills were subsequently processed for LM (methacrylate), TEM and SEM respectively.Three changes involving chloride cells were correlated with increasing acidity: 1) the appearance of apical pits (figs. 2,5 as compared to figs. 1, 3,4) in chloride cells (about 22% of the chloride cells had pits at pH 5.0); 2) increases in their numbers and 3) increases in the % of these cells in the epithelium of the secondary lamellae.


Author(s):  
H. S. Kim ◽  
R. U. Lee

A heating element/electrical conduit assembly used in the Orbiter Maneuvering System failed a leak test during a routine refurbishment inspection. The conduit, approximately 100 mm in length and 12 mm in diameter, was fabricated from two tubes and braze-joined with a sleeve. The tube on the high temperature side (heating element side) and the sleeve were made of Inconel 600 and the other tube was stainless steel (SS) 316. For the filler metal, a Ni-Cr-B brazing alloy per AWS BNi-2, was used. A Helium leak test spotted the leak located at the joint between the sleeve and SS 316 tubing. This joint was dissected, mounted in a plastic mold, polished, and examined with an optical microscope. Debonding of the brazed surfaces was noticed, more pronounced toward the sleeve end which was exposed to uncontrolled atmospheric conditions intermittently. Initially, lack of wetting was suspected, presumably caused by inadequate surface preparation or incomplete fusion of the filler metal. However, this postulation was later discarded based upon the following observations: (1) The angle of wetting between the fillet and tube was small, an indication of adequate wetting, (2) the fillet did not exhibit a globular microstructure which would be an indication of insufficient melting of the filler metal, and (3) debonding was intermittent toward the midsection of the sleeve.


Author(s):  
Heinz Gross ◽  
Katarina Krusche ◽  
Peter Tittmann

Freeze-drying followed by heavy metal shadowing is a long established and straight forward approach to routinely study the structure of dehydrated macromolecules. Very thin specimens such as isolated membranes or single macromolecules are directly adsorbed on C-coated grids. After rapid freezing the grids are transferred into a suitable vacuum equipment for freeze-drying and heavy metal shadowing.To improve the resolution power of shadowing films we introduced shadowing at very low specimen temperature (−250°C). To routinely do that without the danger of contamination we developed in collaboration with Balzers an UHV (p≤10-9 mbar) machine (BAF500K, Fig.2). It should be mentioned here that at −250°C the specimen surface acts as effective cryopump for practically all impinging residual gas molecules from the residual gas atmosphere.Common high resolution shadowing films (Pt/C, Ta/W) have to be protected from alterations due to air contact by a relatively thick C-backing layer, when transferred via atmospheric conditions into the TEM. Such an additional C-coat contributes disturbingly to the contrast at high resolution.


Author(s):  
Tian-Chyi Yeh ◽  
Raziuddin Khaleel ◽  
Kenneth C. Carroll
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