Microfibrillated cellulose – Its barrier properties and applications in cellulosic materials: A review

2012 ◽  
Vol 90 (2) ◽  
pp. 735-764 ◽  
Author(s):  
Nathalie Lavoine ◽  
Isabelle Desloges ◽  
Alain Dufresne ◽  
Julien Bras
2021 ◽  
Vol 11 (14) ◽  
pp. 6445
Author(s):  
David Ibarra ◽  
Raquel Martín-Sampedro ◽  
Bernd Wicklein ◽  
Úrsula Fillat ◽  
María E. Eugenio

Motivated by the negative impact of fossil fuel consumption on the environment, the need arises to produce materials and energy from renewable sources. Cellulose, the main biopolymer on Earth, plays a key role in this context, serving as a platform for the development of biofuels, chemicals and novel materials. Among the latter, micro- and nanocellulose have been receiving increasing attention in the last few years. Their many attractive properties, i.e., thermal stability, high mechanical resistance, barrier properties, lightweight, optical transparency and ease of chemical modification, allow their use in a wide range of applications, such as paper or polymer reinforcement, packaging, construction, membranes, bioplastics, bioengineering, optics and electronics. In view of the increasing demand for traditional wood pulp (e.g., obtained from eucalypt, birch, pine, spruce) for micro/nanocellulose production, dedicated crops and agricultural residues can be interesting as raw materials for this purpose. This work aims at achieving microfibrillated cellulose production from fast-growing poplar and olive tree pruning using physical pretreatment (PFI refining) before the microfibrillation stage. Both raw materials yielded microfibrillated cellulose with similar properties to that obtained from a commercial industrial eucalypt pulp, producing films with high mechanical properties and low wettability. According to these properties, different applications for cellulose microfibers suspensions and films are discussed.


Cellulose ◽  
2010 ◽  
Vol 17 (3) ◽  
pp. 559-574 ◽  
Author(s):  
Christian Aulin ◽  
Mikael Gällstedt ◽  
Tom Lindström

2014 ◽  
Vol 49 (7) ◽  
pp. 2879-2893 ◽  
Author(s):  
Nathalie Lavoine ◽  
Isabelle Desloges ◽  
Bertine Khelifi ◽  
Julien Bras

2013 ◽  
Vol 469 ◽  
pp. 87-90
Author(s):  
Li Liu ◽  
Yun Zhi Chen ◽  
Zheng Jian Zhang

Microfibrillated cellulose (MFC) was prepared from the bleached kraft hardwood pulp using TEMPO/NaClO/NaBr oxidation system and high pressure homogenization. By changing dosages of the TEMPO, NaClO and NaBr, the pressure and times of homogenization, pretreatment and homogenization process were optimized. Experimental investigation indicated that for making MFC of high quality, 0.25%TEMPO, 2.5%NaBr, 60%NaClO (based on oven dry pulp), 20 times of homogenization, pressure of 60MPa in the process of treatment were required. At last, the mechanical and barrier properties were tested after the base paper was coated by homemade MFC. The study suggested that mechanical properties (especially 5 times increase of the folding strength) increased substantially and air permeability decreased by 100times.


2020 ◽  
Vol 15 ◽  
pp. 155892502091087
Author(s):  
Pei-wei Bian ◽  
Bin-qing Sun ◽  
Li-qiang Huang

This study aimed to improve the strength and hydrophobic properties of polyvinyl alcohol/microfibrillated-cellulose composite films and thereby solve problems such as the poor water resistance of polyvinyl alcohol films and defects in the packaging. Polyvinyl alcohol/microfibrillated-cellulose composite films were prepared with the silane coupling agent KH151. The mechanical, optical, crystalline, and other properties of the composite films were tested. After the modification of the polyvinyl alcohol/microfibrillated-cellulose films, their strength and hydrophobic and barrier property were greatly improved. Moreover, their oxygen transmittance decreased by 85.9%, and the water contact angle of the film surface increased by 44%. The internal structure of a polyvinyl alcohol/microfibrillated-cellulose film is formed by KH151, which improves the strength and barrier properties of the film, forms an alkane-based layer on the film surface, and improves the hydrophobic property of the film. Thermogravimetric analysis shows that the thermal stability of composite materials has been greatly improved.


Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4977
Author(s):  
Tomasz Ganicz ◽  
Krystyna Rózga-Wijas

The results of the application of a new hydrophobization agent based on a triethoxymethylsilane and standard starch aqueous mixture for mass-produced cellulosic materials—printing paper, paperboard, and sack paper—have been evaluated to examine whether such a mixture can be used in industrial practice. The application of this agent on laboratory sheets prepared in a repetitive recycling process was performed to investigate its influence on the formation and properties of the products, as well as the contamination of circulating water. Measurements of the water contact angle, Cobb tests, and water penetration dynamics (PDA) were performed to test the barrier properties of the resulting materials. The effects of the applied coatings and recycling process on the paper’s tensile strength, tear index, roughness, air permeance, and ISO brightness were studied. Studies have proven that this formulation imparts relatively high surface hydrophobicity to all materials tested (contact angles above 100°) and a significant improvement in barrier properties while maintaining good mechanical and optical performance. The agent also does not interfere with the pulping and re-forming processes during recycling and increases circulation water contamination to an acceptable degree. Attenuated total reflectance Fourier-transform infrared (FT-IR) spectra of the paper samples revealed the presence of a polysiloxane network on the surface.


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