Template-free method for synthesizing sponge-like graphitic carbon nitride with a large surface area and outstanding nitrogen photofixation ability induced by nitrogen vacancies

2016 ◽  
Vol 42 (6) ◽  
pp. 6985-6992 ◽  
Author(s):  
Guang Wu ◽  
Yan Gao ◽  
Binghui Zheng
2019 ◽  
Vol 7 (10) ◽  
pp. 5324-5332 ◽  
Author(s):  
Mao Wu ◽  
Yansheng Gong ◽  
Tao Nie ◽  
Jin Zhang ◽  
Rui Wang ◽  
...  

Nanocage-like 3D porous graphitic carbon nitride (g-C3N4) with a high surface area and nitrogen defects was successfully prepared via a novel, template-free, cost-effective and hydrothermal-copolymerization route.


RSC Advances ◽  
2015 ◽  
Vol 5 (89) ◽  
pp. 72683-72690 ◽  
Author(s):  
Reny Thankam Thomas ◽  
N. Sandhyarani

Multifunctional solar active graphitic carbon nitride–titania mesoflowers with surface area of 147 m2 g−1 are synthesized by a one-step solvothermal process for environmental remediation.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Yunyan Wu ◽  
Pan Xiong ◽  
Jianchun Wu ◽  
Zengliang Huang ◽  
Jingwen Sun ◽  
...  

AbstractGraphitic carbon nitride (g-C3N4)-based photocatalysts have shown great potential in the splitting of water. However, the intrinsic drawbacks of g-C3N4, such as low surface area, poor diffusion, and charge separation efficiency, remain as the bottleneck to achieve highly efficient hydrogen evolution. Here, a hollow oxygen-incorporated g-C3N4 nanosheet (OCN) with an improved surface area of 148.5 m2 g−1 is fabricated by the multiple thermal treatments under the N2/O2 atmosphere, wherein the C–O bonds are formed through two ways of physical adsorption and doping. The physical characterization and theoretical calculation indicate that the O-adsorption can promote the generation of defects, leading to the formation of hollow morphology, while the O-doping results in reduced band gap of g-C3N4. The optimized OCN shows an excellent photocatalytic hydrogen evolution activity of 3519.6 μmol g−1 h−1 for ~ 20 h, which is over four times higher than that of g-C3N4 (850.1 μmol g−1 h−1) and outperforms most of the reported g-C3N4 catalysts.


2021 ◽  
Author(s):  
Vellaichamy Balakumar ◽  
Manivannan Ramalingam ◽  
Chitiphon Chuaicham ◽  
KARTHIKEYAN SEKAR ◽  
K. Sasaki

Hollow porous graphitic carbon nitride (porous CN) was synthesized via a simple tactic method, and the resulting porous CN showed an effectively modified surface area, crystal structure and enhanced photocatalytic...


2019 ◽  
Vol 3 (9) ◽  
pp. 1807-1815 ◽  
Author(s):  
Junsheng Ma ◽  
Mingpeng Yu ◽  
Huanyu Ye ◽  
Hongquan Song ◽  
Dongxue Wang ◽  
...  

A heterostructured host composed of porous g-C3N4 and N-doped graphene was fabricated by a template-free strategy. The hybrid display excellent cyclability and high coulombic efficiency due to the enhanced polysulfide anchoring-conversion capability.


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