Argon and nitrogen isotopes of trapped air in the GISP2 ice core during the Holocene epoch (0–11,500 B.P.): Methodology and implications for gas loss processes

2008 ◽  
Vol 72 (19) ◽  
pp. 4675-4686 ◽  
Author(s):  
Takuro Kobashi ◽  
Jeffrey P. Severinghaus ◽  
Kenji Kawamura
Keyword(s):  
Nitrogen Isotopes ◽  
Ice Core ◽  
The Holocene ◽  
Trapped Air ◽  
Gas Loss

scholarly journals Towards orbital dating of the EPICA Dome C ice core using δO<sub>2</sub>/N<sub>2</sub>

2011 ◽  
Vol 7 (3) ◽  
pp. 2217-2259 ◽  
Author(s):  
A. Landais ◽  
G. Dreyfus ◽  
E. Capron ◽  
K. Pol ◽  
M. F. Loutre ◽  
...  
Keyword(s):  
Data Quality ◽  
Ice Core ◽  
Marine Isotopic Stage ◽  
Tuning Method ◽  
Trapped Air ◽  
Measurement Series ◽  
Orbital Tuning ◽  
Quality Filtering ◽  
Gas Loss ◽  
Grain Properties

Abstract. Based on a composite of several measurement series performed on ice samples stored at −25 °C or −50 °C, we present and discuss the first δO2/N2 record of trapped air from the EPICA Dome C (EDC) ice core covering the period between 300 and 800 ka (thousands of years before present). The samples stored at −25 °C show clear gas loss affecting the precision and mean level of the δO2/N2 record. Two different gas loss corrections are proposed to account for this effect, without altering the spectral properties of the original datasets. Although processes at play remain to be fully understood, previous studies have proposed a link between surface insolation, ice grain properties at close-off and δO2/N2 in air bubbles, from which an orbitally tuned chronologies of the Vostok and Dome Fuji ice core records have been derived over the last four climatic cycles. Here, we show that limitations caused by data quality and resolution, data filtering and uncertainties in the orbital tuning target limit the precision of this tuning method for EDC to at least 2.5 kyrs (thousands of years). Moreover, our extended record includes two periods of low eccentricity. During these intervals (around 400 ka and 750 ka), the matching between δO2/N2 and the different insolation curves is ambiguous because some local insolation maxima cannot be identified in the δO2/N2 record (and vice versa). Recognizing these limitations, we restrict the use of our δO2/N2 record to show that the EDC3 age scale is generally correct within its published uncertainty (6 kyrs) over the 300–800 ka period. We illustrate the uncertainties associated with data quality, filtering and tuning target for periods of low eccentricity by highlighting the difficulty to constrain the duration of Marine Isotopic Stage 11 based on the EDC δO2/N2 information.

scholarly journals Towards orbital dating of the EPICA Dome C ice core using δO<sub>2</sub>/N<sub>2</sub>

2012 ◽  
Vol 8 (1) ◽  
pp. 191-203 ◽  
Author(s):  
A. Landais ◽  
G. Dreyfus ◽  
E. Capron ◽  
K. Pol ◽  
M. F. Loutre ◽  
...  
Keyword(s):  
Ice Core ◽  
Air Bubbles ◽  
Before Present ◽  
Data Filtering ◽  
Tuning Method ◽  
Trapped Air ◽  
Measurement Series ◽  
Orbital Tuning ◽  
Gas Loss ◽  
Grain Properties

Abstract. Based on a composite of several measurement series performed on ice samples stored at −25 °C or −50 °C, we present and discuss the first δO2/N2 record of trapped air from the EPICA Dome C (EDC) ice core covering the period between 300 and 800 ka (thousands of years before present). The samples stored at −25 °C show clear gas loss affecting the precision and mean level of the δO2/N2 record. Two different gas loss corrections are proposed to account for this effect, without altering the spectral properties of the original datasets. Although processes at play remain to be fully understood, previous studies have proposed a link between surface insolation, ice grain properties at close-off, and δO2/N2 in air bubbles, from which orbitally tuned chronologies of the Vostok and Dome Fuji ice core records have been derived over the last four climatic cycles. Here, we show that limitations caused by data quality and resolution, data filtering, and uncertainties in the orbital tuning target limit the precision of this tuning method for EDC. Moreover, our extended record includes two periods of low eccentricity. During these intervals (around 400 ka and 750 ka), the matching between δO2/N2 and the different insolation curves is ambiguous because some local insolation maxima cannot be identified in the δO2/N2 record (and vice versa). Recognizing these limitations, we restrict the use of our δO2/N2 record to show that the EDC3 age scale is generally correct within its published uncertainty (6 kyr) over the 300–800 ka period.

Do Greenland Ice Cores Reflect NW European Interglacial Climate Variations?

1995 ◽  
Vol 43 (2) ◽  
pp. 125-132 ◽  
Author(s):  
Eiliv Larsen ◽  
Hans Petter Sejrup ◽  
Sigfus J. Johnsen ◽  
Karen Luise Knudsen
Keyword(s):  
Western Europe ◽  
Ice Core ◽  
Greenland Ice Sheet ◽  
Ice Cores ◽  
High Amplitude ◽  
Atlantic Water ◽  
Polar Front ◽  
Norwegian Sea ◽  
The Holocene ◽  
Climatic Evolution

AbstractThe climatic evolution during the Eemian and the Holocene in western Europe is compared with the sea-surface conditions in the Norwegian Sea and with the oxygen-isotope-derived paleotemperature signal in the GRIP and Renland ice cores from Greenland. The records show a warm phase (ca. 3000 yr long) early in the Eemian (substage 5e). This suggests that the Greenland ice sheet, in general, recorded the climate in the region during this time. Rapid fluctuations during late stage 6 and late substage 5e in the GRIP ice core apparently are not recorded in the climatic proxies from western Europe and the Norwegian Sea. This may be due to low resolution in the terrestrial and marine records and/or long response time of the biotic changes. The early Holocene climatic optimum recorded in the terrestrial and marine records in the Norwegian Sea-NW European region is not found in the Summit (GRIP and GISP2) ice cores. However, this warm phase is recorded in the Renland ice core. Due to the proximity of Renland to the Norwegian Sea, this area is probably more influenced by changes in polar front positions which may partly explain this discrepancy. A reduction in the elevation at Summit during the Holocene may, however, be just as important. The high-amplitude shifts during substage 5e in the GRIP core could be due to Atlantic water oscillating closer to, and also reaching, the coast of East Greenland. During the Holocene, Atlantic water was generally located farther east in the Norwegian Sea than during the Eemian.

Reconstructing Antarctic snow accumulation using nitrogen isotopes of nitrate

2021 ◽  
Author(s):  
Pete D. Akers ◽  
Joël Savarino ◽  
Nicolas Caillon ◽  
Mark Curran ◽  
Tas Van Ommen
Keyword(s):  
Nitrogen Isotopes ◽  
Full Range ◽  
Ice Core ◽  
Ice Cores ◽  
Snow Accumulation ◽  
East Antarctica ◽  
Accumulation Rates ◽  
Sea Levels ◽  
Antarctic Snow ◽  
Parallel Reconstruction

&lt;p&gt;Precise Antarctic snow accumulation estimates are needed to understand past and future changes in global sea levels, but standard reconstructions using water isotopes suffer from competing isotopic effects external to accumulation. We present here an alternative accumulation proxy based on the post-depositional photolytic fractionation of nitrogen isotopes (d&lt;sup&gt;15&lt;/sup&gt;N) in nitrate. On the high plateau of East Antarctica, sunlight penetrating the uppermost snow layers converts snow-borne nitrate into nitrogen oxide gas that can be lost to the atmosphere. This nitrate loss favors &lt;sup&gt;14&lt;/sup&gt;NO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;-&lt;/sup&gt; over &lt;sup&gt;15&lt;/sup&gt;NO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;-&lt;/sup&gt;, and thus the d&lt;sup&gt;15&lt;/sup&gt;N of nitrate remaining in the snow will steadily increase until the nitrate is eventually buried beneath the reach of light. Because the duration of time until burial is dependent upon the rate of net snow accumulation, sites with lower accumulation rates have a longer burial wait and thus higher d&lt;sup&gt;15&lt;/sup&gt;N values. A linear relationship (r&lt;sup&gt;2&lt;/sup&gt; = 0.86) between d&lt;sup&gt;15&lt;/sup&gt;N and net accumulation&lt;sup&gt;-1&lt;/sup&gt; is calculated from over 120 samples representing 105 sites spanning East Antarctica. These sites largely encompass the full range of snow accumulation rates observed in East Antarctica, from 25 kg m-&lt;sup&gt;2&lt;/sup&gt; yr&lt;sup&gt;-1&lt;/sup&gt; at deep interior sites to &gt;400 kg m-&lt;sup&gt;2&lt;/sup&gt; yr&lt;sup&gt;-1&lt;/sup&gt; at near coastal sites. We apply this relationship as a transfer function to an Aurora Basin ice core to produce a 700-year record of accumulation changes. Our nitrate-based estimate compares very well with a parallel reconstruction for Aurora Basin that uses volcanic horizons and ice-penetrating radar. Continued improvements to our database may enable precise independent estimates of millennial-scale accumulation changes using deep ice cores such as EPICA Dome C and Beyond EPICA-Oldest Ice.&lt;/p&gt;

scholarly journals Synchronizing the Greenland ice core and radiocarbon timescales over the Holocene – Bayesian wiggle-matching of cosmogenic radionuclide records

2016 ◽  
Vol 12 (1) ◽  
pp. 15-30 ◽  
Author(s):  
F. Adolphi ◽  
R. Muscheler
Keyword(s):  
Statistical Approach ◽  
Ice Core ◽  
Ice Cores ◽  
The Holocene ◽  
Counting Error ◽  
Climate Reconstructions ◽  
Uncertainty Measurement ◽  
Uncertainty Estimates ◽  
Paleoclimate Records ◽  
Cosmogenic Radionuclide

Abstract. Investigations of past climate dynamics rely on accurate and precise chronologies of the employed climate reconstructions. The radiocarbon dating calibration curve (IntCal13) and the Greenland ice core chronology (GICC05) represent two of the most widely used chronological frameworks in paleoclimatology of the past  ∼  50 000 years. However, comparisons of climate records anchored on these chronologies are hampered by the precision and accuracy of both timescales. Here we use common variations in the production rates of 14C and 10Be recorded in tree-rings and ice cores, respectively, to assess the differences between both timescales during the Holocene. Compared to earlier work, we employ a novel statistical approach which leads to strongly reduced and yet, more robust, uncertainty estimates. Furthermore, we demonstrate that the inferred timescale differences are robust independent of (i) the applied ice core 10Be records, (ii) assumptions of the mode of 10Be deposition, as well as (iii) carbon cycle effects on 14C, and (iv) in agreement with independent estimates of the timescale differences. Our results imply that the GICC05 counting error is likely underestimated during the most recent 2000 years leading to a dating bias that propagates throughout large parts of the Holocene. Nevertheless, our analysis indicates that the GICC05 counting error is generally a robust uncertainty measurement but care has to be taken when treating it as a nearly Gaussian error distribution. The proposed IntCal13-GICC05 transfer function facilitates the comparison of ice core and radiocarbon dated paleoclimate records at high chronological precision.

scholarly journals Brief communication: New evidence further constraining Tibetan ice core chronologies to the Holocene

2021 ◽  
Vol 15 (4) ◽  
pp. 2109-2114
Author(s):  
Shugui Hou ◽  
Wangbin Zhang ◽  
Ling Fang ◽  
Theo M. Jenk ◽  
Shuangye Wu ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
Ice Core ◽  
Ice Cores ◽  
Qilian Mountains ◽  
Time Range ◽  
The Holocene ◽  
Guliya Ice Core ◽  
Considerable Controversy ◽  
New Evidence

Abstract. There is considerable controversy regarding the age ranges of Tibetan ice cores. The Guliya ice core was reported to reach as far back as ∼760 ka (kiloannum, i.e. 1000 years), whereas chronologies of all other Tibetan cores cover at most the Holocene. Here we present ages for two new ice cores reaching bedrock, from the Zangser Kangri (ZK) glacier in the northwestern Tibetan Plateau and the Shulenanshan (SLNS) glacier in the western Qilian Mountains. We estimated bottom ages of 8.90±0.570.56 ka and 7.46±1.461.79 ka for the ZK and SLNS ice core respectively, further constraining the time range accessible by Tibetan ice cores to the Holocene.

On the potential of coupling air content and O2/N2 from trapped air for establishing an ice core chronology tuned on local insolation

2011 ◽  
Vol 30 (23-24) ◽  
pp. 3280-3289 ◽  
Author(s):  
V.Ya. Lipenkov ◽  
D. Raynaud ◽  
M.F. Loutre ◽  
P. Duval
Keyword(s):  
Ice Core ◽  
Air Content ◽  
Trapped Air

scholarly journals Some comments on climatic reconstructions from ice cores drilled in areas of high melt

1997 ◽  
Vol 43 (143) ◽  
pp. 90-97 ◽  
Author(s):  
Roy M. Koerner
Keyword(s):  
Time Scales ◽  
Ice Core ◽  
Ice Cores ◽  
The Holocene ◽  
Ice Caps ◽  
Ice Cap ◽  
Thermal Maximum ◽  
Devon Ice Cap ◽  
Seasonal Signals ◽  
Cross Correlations

AbstractPoor consideration has been given in many Arctic circum-polar ice-core studies to the effect of summer snow melt on chemistry, stable-isotope concentrations and time-scales. Many of these corps are drilled close to the firn line where melt is intense. Some come from below the firn line where accumulation is solely in the form of super-imposed ice. In all cases, seasonal signals are reduced or removed and, in some, time gaps develop during periods of excessive melting which situate the drill site in the ablation zone. Consequently, cross correlations of assumed synchronous events among the cores are invalid, so that time-scales along the same cores differ between authors by factors of over 2. Many so-called climatic signals are imaginary rather than real. By reference to published analyses of cores from the superimposed ice zone on Devon Ice Cap (Koerner, 1970) and Meighen Ice Cap (Koerner and Paterson, 1974), it is shown how melt affects all the normally well-established ice-core proxies and leads to their misinterpretation. Despite these limitations, the cores can give valuable low-resolution records for all or part of the Holocene. They show that the thermal maximum in the circum-polar Arctic occurred in the early Holocene. This maximum, effected negative balances on all the ice caps and removed the smaller ones. Cooler conditions in the second half of the Holocene have caused the regrowth of these same ice caps.

scholarly journals High-resolution mineral dust and sea ice proxy records from the Talos Dome ice core

2013 ◽  
Vol 9 (6) ◽  
pp. 2789-2807 ◽  
Author(s):  
S. Schüpbach ◽  
U. Federer ◽  
P. R. Kaufmann ◽  
S. Albani ◽  
C. Barbante ◽  
...  
Keyword(s):  
Southern Ocean ◽  
Sea Ice ◽  
Ross Sea ◽  
Transport Model ◽  
Mineral Dust ◽  
Ice Core ◽  
Ice Cores ◽  
Last Interglacial ◽  
The Holocene ◽  
Proxy Records

Abstract. In this study we report on new non-sea salt calcium (nssCa2+, mineral dust proxy) and sea salt sodium (ssNa+, sea ice proxy) records along the East Antarctic Talos Dome deep ice core in centennial resolution reaching back 150 thousand years (ka) before present. During glacial conditions nssCa2+ fluxes in Talos Dome are strongly related to temperature as has been observed before in other deep Antarctic ice core records, and has been associated with synchronous changes in the main source region (southern South America) during climate variations in the last glacial. However, during warmer climate conditions Talos Dome mineral dust input is clearly elevated compared to other records mainly due to the contribution of additional local dust sources in the Ross Sea area. Based on a simple transport model, we compare nssCa2+ fluxes of different East Antarctic ice cores. From this multi-site comparison we conclude that changes in transport efficiency or atmospheric lifetime of dust particles do have a minor effect compared to source strength changes on the large-scale concentration changes observed in Antarctic ice cores during climate variations of the past 150 ka. Our transport model applied on ice core data is further validated by climate model data. The availability of multiple East Antarctic nssCa2+ records also allows for a revision of a former estimate on the atmospheric CO2 sensitivity to reduced dust induced iron fertilisation in the Southern Ocean during the transition from the Last Glacial Maximum to the Holocene (T1). While a former estimate based on the EPICA Dome C (EDC) record only suggested 20 ppm, we find that reduced dust induced iron fertilisation in the Southern Ocean may be responsible for up to 40 ppm of the total atmospheric CO2 increase during T1. During the last interglacial, ssNa+ levels of EDC and EPICA Dronning Maud Land (EDML) are only half of the Holocene levels, in line with higher temperatures during that period, indicating much reduced sea ice extent in the Atlantic as well as the Indian Ocean sector of the Southern Ocean. In contrast, Holocene ssNa+ flux in Talos Dome is about the same as during the last interglacial, indicating that there was similar ice cover present in the Ross Sea area during MIS 5.5 as during the Holocene.

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