Thermodynamic analysis of aqueous phase reforming of three model compounds in bio-oil for hydrogen production

2011 ◽  
Vol 36 (24) ◽  
pp. 15561-15572 ◽  
Author(s):  
Jianjun Xie ◽  
Deren Su ◽  
Xiuli Yin ◽  
Chuangzhi Wu ◽  
Jingxu Zhu
2017 ◽  
Vol 2 (5) ◽  
pp. 679-687 ◽  
Author(s):  
F. J. Gutiérrez Ortiz ◽  
F. J. Campanario ◽  
P. Ollero

The effect of mixing model compounds on the hydrogen yield under supercritical conditions is studied by proposed potential pathways.


2013 ◽  
Vol 33 (3) ◽  
pp. 1008-1016 ◽  
Author(s):  
Huaqing Xie ◽  
Qingbo Yu ◽  
Kun Wang ◽  
Xiaobo Shi ◽  
Xinhui Li

2019 ◽  
Vol 44 (29) ◽  
pp. 14605-14623 ◽  
Author(s):  
Lidia I. Godina ◽  
Hans Heeres ◽  
Sonia Garcia ◽  
Steve Bennett ◽  
Stephen Poulston ◽  
...  

2019 ◽  
Vol 49 (4) ◽  
pp. 297-302
Author(s):  
Yanina P. Maidana ◽  
Eduardo Izurieta ◽  
Andres I. Casoni ◽  
Maria A. Volpe ◽  
Eduardo Lopez ◽  
...  

This work focuses on the study of hydrogen production process departing from waste lignocellulosic biomass. The bio-oil was first obtained by non-catalytic fast pyrolysis of sunflower seed hulls. Subsequently, it was upgraded to reduce the concentration of higher molecular weight compounds by water addition and mixing. A 1/1 bio-oil:water ratio was selected here. Later, a thermodynamic analysis based on free energy minimization was profited to study the steam reforming process of the upgraded bio-oil sample. The influence of the operation temperature on the reforming was analyzed. The highest hydrogen yields were obtained at ~740°C. A comparison with acetic acid used as model compound of the bio-oil is included. Results show that acetic acid is not a good approximation of a real aqueous phase of upgraded bio oil fraction. The study concludes with an analysis on the energetic efficiency, showing that its maximum is presented at lower temperatures than the maximum yield, due to the thermal requirements of preheating.


2020 ◽  
Vol 45 (27) ◽  
pp. 13848-13861 ◽  
Author(s):  
Yoondo Kim ◽  
Minkyeong Kim ◽  
Hyangsoo Jeong ◽  
Yongmin Kim ◽  
Sun Hee Choi ◽  
...  

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