Significant impact of lanthanide contraction on the structure of the phenanthroline complexes

2021 ◽  
Vol 31 (6) ◽  
pp. 853-855
Author(s):  
Pavel S. Lemport ◽  
Mariia V. Evsiunina ◽  
Yulia V. Nelyubina ◽  
Kseniya L. Isakovskaya ◽  
Victor N. Khrustalev ◽  
...  
Keyword(s):  
Lanthanide Contraction

Bond-length distributions for ions bonded to oxygen: Results for the lanthanides and actinides and discussion of the f-block contraction

2017 ◽  
Author(s):  
Olivier Charles Gagné
Keyword(s):  
Bond Length ◽  
Coordination Number ◽  
Lanthanide Ions ◽  
Lanthanide Contraction ◽  
Trivalent Lanthanide ◽  
Actinide Ions

Bond-length distributions have been examined for eighty-four configurations of the lanthanide ions and twenty-two configurations of the actinide ions bonded to oxygen. The lanthanide contraction for the trivalent lanthanide ions bonded to O<sup>2-</sup> is shown to vary as a function of coordination number and to diminish in scale with increasing coordination number.

Porous Frameworks Based on Carborane-Ln2(CO2)6: Architecture Influenced by Lanthanide Contraction and Selective CO2 Capture

ChemPlusChem ◽  
2012 ◽  
Vol 77 (2) ◽  
pp. 141-147 ◽  
Author(s):  
Sheng-Li Huang ◽  
Yue-Jian Lin ◽  
Wei-Bin Yu ◽  
Guo-Xin Jin
Keyword(s):  
Co2 Capture ◽  
Lanthanide Contraction

Coordination complexes based on pentacyclohexanocucurbit[5]uril and lanthanide(iii) ions: lanthanide contraction effect induced structural variation

CrystEngComm ◽  
2012 ◽  
Vol 14 (20) ◽  
pp. 6983 ◽  
Author(s):  
Jing-Xin Liu ◽  
Ying-Feng Hu ◽  
Rui-Lian Lin ◽  
Wen-Qi Sun ◽  
Xiang-Feng Chu ◽  
...  
Keyword(s):  
Structural Variation ◽  
Coordination Complexes ◽  
Lanthanide Contraction ◽  
Contraction Effect

Characterization of the extracted complexes of trivalent lanthanides with purified cyanex 301 in comparison with trivalent actinide complexes

2014 ◽  
Vol 43 (46) ◽  
pp. 17352-17357 ◽  
Author(s):  
Xihong He ◽  
Guoxin Tian ◽  
Jing Chen ◽  
Linfeng Rao
Keyword(s):  
Trivalent Lanthanides ◽  
Lanthanide Series ◽  
Lanthanide Contraction ◽  
Cyanex 301 ◽  
Trivalent Actinide

Dialkyldithiophosphinate forms different extracted Ln(iii) complexes across the lanthanide series not following the trend of lanthanide contraction.

scholarly journals Lanthanide(III)/Pyrimidine-4,6-dicarboxylate/Oxalate Extended Frameworks: A Detailed Study Based on the Lanthanide Contraction and Temperature Effects

2011 ◽  
Vol 50 (17) ◽  
pp. 8437-8451 ◽  
Author(s):  
Javier Cepeda ◽  
Rolindes Balda ◽  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Joaquín Fernández ◽  
...  
Keyword(s):  
Temperature Effects ◽  
Lanthanide Contraction

Ultrasensitive sorption behavior of isostructural lanthanide–organic frameworks induced by lanthanide contraction

2012 ◽  
Vol 22 (39) ◽  
pp. 21076 ◽  
Author(s):  
Zhongjun Lin ◽  
Ruqiang Zou ◽  
Wei Xia ◽  
Liangjie Chen ◽  
Xidong Wang ◽  
...  
Keyword(s):  
Sorption Behavior ◽  
Lanthanide Contraction

Lanthanide contraction for helicity fine-tuning and helix-winding control of single-helical metal complexes

2016 ◽  
Vol 45 (38) ◽  
pp. 14902-14906 ◽  
Author(s):  
Shiho Sairenji ◽  
Shigehisa Akine ◽  
Tatsuya Nabeshima
Keyword(s):  
Metal Complexes ◽  
Fine Tuning ◽  
Lanthanide Contraction ◽  
Tetranuclear Complexes

Lanthanide contraction was used for helicity fine-tuning and helix winding control of single-helical tetranuclear complexes LZn3Ln (Ln = La–Lu).

scholarly journals Nearly Identical but Not Isotypic: Influence of Lanthanide Contraction on Cs2NaLn(PS4)2 (Ln = La–Nd, Sm, and Gd–Ho)

2020 ◽  
Vol 59 (3) ◽  
pp. 1905-1916 ◽  
Author(s):  
Vladislav V. Klepov ◽  
Kristen A. Pace ◽  
Logan S. Breton ◽  
Vancho Kocevski ◽  
Theodore M. Besmann ◽  
...  
Keyword(s):  
Lanthanide Contraction
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