Synthesis, thermal behavior and kinetic study of N-morpholinium dicationic ionic liquids by thermogravimetry

2021 ◽  
Vol 332 ◽  
pp. 115662
Author(s):  
Claudio Ferdeghini ◽  
Lorenzo Guazzelli ◽  
Christian S. Pomelli ◽  
Andrea Ciccioli ◽  
Bruno Brunetti ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Thermal Behavior ◽  
Kinetic Study ◽  
Dicationic Ionic Liquids

scholarly journals Expanding the Chemical Space of Benzimidazole Dicationic Ionic Liquids

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4211
Author(s):  
Andrea Mezzetta ◽  
Luca Guglielmero ◽  
Angelica Mero ◽  
Giorgio Tofani ◽  
Felicia D’Andrea ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Ionic Liquids ◽  
Thermal Behavior ◽  
Chemical Space ◽  
Fine Tuning ◽  
Reduction Peak ◽  
Spacer Length ◽  
Potential Shape ◽  
Electrochemical Window ◽  
Dicationic Ionic Liquids

Benzimidazole dicationic ionic liquids (BDILs) have not yet been widely explored in spite of their potential. Therefore, two structurally related families of BDILs, paired with either bromide or bistriflimide anions and bearing alkyl spacers ranging from C3 to C6, have been prepared. Their thermal properties have been studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), while their electrical properties have been assessed by cyclic voltammetry (CV). TG analysis confirmed the higher stability of the bistriflimide BDILs over the bromide BDILs, with minor variation within the two families. Conversely, DSC and CV allowed for ascertaining the role played by the spacer length. In particular, the thermal behavior changed dramatically among the members of the bistriflimide family, and all three possible thermal behavior types of ILs were observed. Furthermore, cyclic voltammetry showed different electrochemical window (C3(C1BenzIm)2/2Tf2N < C4(C1BenzIm)2/2Tf2N, C5(C1BenzIm)2/2Tf2N < C6(C1BenzIm)2/2Tf2N) as well as a reduction peak potential, shape, and intensity as a function of the spacer length. The results obtained highlight the benefit of accessing a more structurally diverse pool of compounds offered by dicationic ILs when compared to the parent monocationic ILs. In particular, gains are to be found in the ease of fine-tuning their properties, which translates in facilitating further investigations toward BDILs as designer solvents and catalysts.

Synthesis, Characterization and Applications of Dicationic Ionic Liquids in Organic Synthesis

2020 ◽  
Vol 17 (4) ◽  
pp. 450-464
Author(s):  
Mohammad Javaherian ◽  
Seyyed Jafar Saghanezhad
Keyword(s):  
Ionic Liquids ◽  
Organic Synthesis ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Dicationic Ionic Liquids ◽  
Physical And Chemical ◽  
Reaction Media ◽  
And Chemical Properties

Dicationic ionic liquids are an emerging group of Ionic Liquids (ILs) that are currently receiving much attention as green reaction media and catalysts. Because of a great number of possible combinations of cations and anions, the physical and chemical properties of dicationic ionic liquids are more tunable and broader than monocationic ILs. Therefore, their unique properties have made them the target of many applied and fundamental researches. Actually, dicationic ionic liquids are more effective and rather fascinating than traditional monocationic ILs. So, due to greater versatility and diversity, their applications in organic synthesis have been extensively grown. In this review, we have focused on the synthesis, characterization and applications of dicationic ionic liquids, especially, in organic synthesis.

scholarly journals Application of asymmetric dicationic ionic liquids for oil spill remediation in sea water

2021 ◽  
Vol 14 (5) ◽  
pp. 103123
Author(s):  
C.E. El shafiee ◽  
R.A. El-Nagar ◽  
M.I. Nessim ◽  
M.M.H. Khalil ◽  
M.E. Shaban ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Oil Spill ◽  
Sea Water ◽  
Dicationic Ionic Liquids ◽  
Oil Spill Remediation

Thermal behavior and kinetic study for co-pyrolysis of lignocellulosic biomass with polyethylene over Cobalt modified ZSM-5 catalyst by thermogravimetric analysis

2018 ◽  
Vol 247 ◽  
pp. 804-811 ◽  
Author(s):  
Zhongping Xiang ◽  
Jianghui Liang ◽  
Hervan Marion Morgan ◽  
Yuanyuan Liu ◽  
Hanping Mao ◽  
...  
Keyword(s):  
Thermogravimetric Analysis ◽  
Thermal Behavior ◽  
Kinetic Study ◽  
Lignocellulosic Biomass

Probing Molecular Interactions in Functionalized Asymmetric Quaternary Ammonium-Based Dicationic Ionic Liquids

2016 ◽  
Vol 120 (39) ◽  
pp. 7732-7744 ◽  
Author(s):  
Prakash L. Verma ◽  
Libero J. Bartolotti ◽  
Shridhar P. Gejji
Keyword(s):  
Ionic Liquids ◽  
Molecular Interactions ◽  
Quaternary Ammonium ◽  
Dicationic Ionic Liquids

Branched-chain dicationic ionic liquids for fatty acid methyl ester assessment by gas chromatography

2017 ◽  
Vol 410 (19) ◽  
pp. 4633-4643 ◽  
Author(s):  
Mohsen Talebi ◽  
Rahul A. Patil ◽  
Leonard M. Sidisky ◽  
Alain Berthod ◽  
Daniel W. Armstrong
Keyword(s):  
Gas Chromatography ◽  
Ionic Liquids ◽  
Fatty Acid ◽  
Methyl Ester ◽  
Fatty Acid Methyl Ester ◽  
Acid Methyl Ester ◽  
Acid Methyl ◽  
Dicationic Ionic Liquids ◽  
Branched Chain
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