Dicyanostilbene-derived two-photon fluorescence dyes with large two-photon absorption cross sections

2011 ◽  
Vol 1006 (1-3) ◽  
pp. 91-95 ◽  
Author(s):  
Chibao Huang ◽  
Changhua Lin ◽  
Anxiang Ren ◽  
Nianfa Yang
2019 ◽  
Vol 955 ◽  
pp. 37-43
Author(s):  
Martin Vala ◽  
Matouš Kratochvíl ◽  
Patricie Heinrichova ◽  
Martin Weiter

The paper deals with determination of two-photon absorption cross-sections of selected representatives of diketo-pyrrolo-pyrrole. The materials were optimized in order to test the influence of various substitutions on the diketo-pyrrolo-pyrrole basic molecule. The two-photon absorption cross-sections were determined using two-photon excited fluorescence technique. A considerably high two-photon absorption cross-section in order of 1000 GM was found for non-symmetrically substituted derivative with donor-acceptor structure. All of the derivatives showed strong fluorescence in solid state visible by naked eye. These results demonstrate that this class of materials can be used in e.g. two-photon fluorescence microscopy in the form of nanoparticles.


Absolute values of the two-photon absorption cross-sections of Rhodamine 6G, Rhodamine B, Acridine Red, Disodium Fluorescein and DODCI have been obtained by excitation with a neodymium: glass laser (1060 nm). Measurements over eight orders of magnitude of the exciting light flux were carried out by employing the laser both Q-switched and mode-locked. The two-photon fluorescence flux measurements were calibrated by single-photon fluorescence generated by excitation with second-harmonic laser pulses. The experimental results are compared with values predicted by semi-empirical theoretical models and good agreement is obtained. Two-photon amplification of the mode-locked neodymium laser by organic dyes is shown not to be practicable at present. Other possible two-photon oscillators are discussed.


2006 ◽  
Vol 12 (8) ◽  
pp. 2303-2317 ◽  
Author(s):  
Shin-ichiro Kato ◽  
Taisuke Matsumoto ◽  
Motoyuki Shigeiwa ◽  
Hideki Gorohmaru ◽  
Shuuichi Maeda ◽  
...  

2018 ◽  
Vol 42 (17) ◽  
pp. 14325-14331 ◽  
Author(s):  
Ruiqing Feng ◽  
Longlong Li ◽  
Bing Li ◽  
Jinhui Li ◽  
Dan Peng ◽  
...  

DMI could light up the RNA of the nucleus and the cytoplasm in living systems, which not only exhibits larger two-photon absorption cross-sections (981 GM), but also displays high-permeability to plasma membranes of vigorous cells.


2008 ◽  
Vol 33 (4) ◽  
pp. 931-934 ◽  
Author(s):  
K. Takemura ◽  
K. Kasatani ◽  
Y. Morita ◽  
H. Okamoto, ◽  
J. Kawamata

2015 ◽  
Vol 3 (4) ◽  
pp. 742-749 ◽  
Author(s):  
Anna Purc ◽  
Krzysztof Sobczyk ◽  
Yusuke Sakagami ◽  
Akihiro Ando ◽  
Kenji Kamada ◽  
...  

Decorating diketopyrrolopyrroles with strongly electron-rich heterocycles led to donor–acceptor–donor architectures possessing two-photon brightness 850–1900 GM.


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