Synthesis and characterization of waterborne polyurethane based on aliphatic diamine sulphonate and liquefiable dimethylol propionic acid

2018 ◽  
Vol 118 ◽  
pp. 116-121 ◽  
Author(s):  
Jianru Wu ◽  
Dajun Chen
2004 ◽  
Vol 42 (7) ◽  
pp. 1758-1767 ◽  
Author(s):  
Michael Malkoch ◽  
Hans Claesson ◽  
Peter Löwenhielm ◽  
Eva Malmström ◽  
Anders Hult

1997 ◽  
Vol 50 (9) ◽  
pp. 939 ◽  
Author(s):  
Fang Chen ◽  
Parveen Akhtar ◽  
Leon A. P. Kane-Maguire ◽  
Gordon G. Wallace

A range of optically active pyrrole monomers have been synthesized in which a chiral sub- stituent is covalently bonded either to the pyrrole N or C3 ring position, namely (–)-(1R)-4-methyl-N-(1-phenylethyl)pyrrole-3-carboxamide, (+)-(1S)-4-methyl-N-(1-phenylethyl)pyrrole-3-carboxamide, (–)-(1R)-4-methyl-N-(1-naphthylethyl)pyrrole-3-carboxamide, (+)-(1S)-4-methyl-N-(1-naphthylethyl)pyrrole-3-carboxamide, (+)-(2S)-2-(1H-pyrrol-1-yl)propionic acid, (+)-(1S)-N-(1-phenyl-ethyl)pyrrole, and (–)-(1R)-N-(1-phenylethyl)pyrrole. Their chiroptical properties have been established by circular dichroism spectroscopy. Electropolymerization of the three N-substituted pyrrole monomers provided films of chiral conducting polymers, whose electrical and spectroscopic properties are described. Although oxidation of the C3 substituted pyrrole monomers was also facile, electrodeposition was poor and films of the associated polymers could not be obtained.


2014 ◽  
Vol 513-517 ◽  
pp. 251-254 ◽  
Author(s):  
Zheng Xiang Wang ◽  
Ji Tong Yuan ◽  
Qi Long Liu ◽  
Xi Mei Xiao ◽  
Yun Hua Li ◽  
...  

A novel waterborne polyurethane (WPU) modified by tung oil was prepared with 2,4-tolylene diisocyanate, polyethylene glycol, dimethylol propinic acid, 1,4-butanedilo as main materials via acetone process. The structure of WPU molecule was characterized by FT-IR. Adhesive behavior for non-polar and/or low surface energy soft packing films was studied. Water resistance of films were evaluated by water contact angle and water uptake and thermal properties determined by thermal analysis instruments. The results show that the modified WPU films have good water and heat resistance. Both of modified WPUs or not have good adherence on BOPP films.


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