A novel method dubbed ZULF-TOCSY results from the combination of Zero and Ultra-Low Field (ZULF) with high-field, high-resolution NMR, leading to a generalization of the concept of total correlation spectroscopy...
Abstract
The magnetostatic and magnetic resonance properties of the Y0.5Sr0.5Cr0.5Mn0.5O3 polycrystalline system have been experimentally studied. The intracrystalline ferromagnetic interaction turned out to be prevalent while the intercrystalline interaction appears to have antiferromagnetic character. We found that two absorption lines are observed in the spectrum in the magnetic ordering region at T < 80 K. The high-field line corresponds to the interacting parts of polycrystal related to the disordered shells and the low-field peak is system of ferromagnetic particles.
Diluted solutions of potassium disilanyl, 2-potassium trisilanyl and 2-potassium isotetrasilanyl in m onoglym e have been prepared from potassium silyl and di- or trisilane under suitable reaction conditions. The purity of the silanyls varies between 95 and 99%. Their stability increases from potassium di- to 2-potassium isotetrasilanyl. The 29Si NMR spectra exhibit a strong high field shift for the metal substituted silicon atoms and a m oderate low field shift for the other silicon atoms compared with the signals of the corresponding silanes.
The high temperature – low field expansions of the Ising model are derived from the low temperature – high field expansions and the coefficients for several lattices are presented.
Magnetic and resonance properties of the Y0.5Sr0.5Cr0.5Mn0.5O3 polycrystal