Effect of Structure of Pd/WO3-ZrO2 Catalyst on Its Activity for Direct Oxidation of Ethylene to Acetic Acid

2009 ◽  
Vol 30 (9) ◽  
pp. 864-872 ◽  
Author(s):  
Lixia WANG ◽  
Shuliang XU ◽  
Wenling CHU ◽  
Weishen YANG
2009 ◽  
Vol 6 (s1) ◽  
pp. S324-S328 ◽  
Author(s):  
Alireza Badiei ◽  
Javad Gholami ◽  
Yeganeh Khaniani

Direct oxidation of benzene to phenol in liquid phase by H2O2peroxide was examined over Ti/ LUS-1 catalyst in methanol and acetic acid as solvents. The maximum yield and selectivity of the phenol produced was obtained in the presence of acetic acid. It can be attributed to the stabilization of H2O2as peroxy acetic acid species in the radical mechanism for this reaction. Acetic acid interacts with hydrogen peroxide over Ti/LUS-1 and produces acetoxy radicals.


1929 ◽  
Vol 19 (4) ◽  
pp. 627-648 ◽  
Author(s):  
V. Subrahmanyan

(1) In absence of decomposing organic matter addition of nitrate led to no loss of nitrogen.(2) On addition of small quantities of fermentable matter such as glucose there was (a) rapid depletion of nitrates and oxygen, but no denitrification, and (b) increase in acidity, carbon dioxide and bacteria. The greater part of the soluble nitrogen was assimilated by microorganisms or otherwise converted and the greater part of the added carbohydrate was transformed into lactic, acetic and butyric acids.(3) The organic acids were formed from a variety of carbohydrates. Lactic acid was the first to be observed and appeared to be formed mainly by direct splitting of the sugar. It decomposed readily, forming acetic and butyric acids. Some acetic acid was formed by direct oxidation of lactic acid, with pyruvic acid as the intermediate product. All the acids were, on standing, converted into other forms by micro-organisms.


2016 ◽  
Vol 34 (2) ◽  
pp. 305-313 ◽  
Author(s):  
Ya-ping Xue ◽  
Chang-feng Yan ◽  
Xiao-yong Zhao ◽  
Shi-lin Huang ◽  
Chang-qing Guo

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