Exciplex-Based Electroluminescence: Over 21% External Quantum Efficiency and Approaching 100 lm/W Power Efficiency

2019 ◽  
Vol 10 (11) ◽  
pp. 2811-2816 ◽  
Author(s):  
Baoyan Liang ◽  
Jiaxuan Wang ◽  
Zong Cheng ◽  
Jinbei Wei ◽  
Yue Wang
Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4615
Author(s):  
Dovydas Blazevicius ◽  
Daiva Tavgeniene ◽  
Simona Sutkuviene ◽  
Ernestas Zaleckas ◽  
Ming-Ruei Jiang ◽  
...  

Pyridinyl-carbazole fragments containing low molar mass compounds as host derivatives H1 and H2 were synthesized, investigated, and used for the preparation of electro-phosphorescent organic light-emitting devices (PhOLEDs). The materials demonstrated high stability against thermal decomposition with the decomposition temperatures of 361–386 °C and were suitable for the preparation of thin amorphous and homogeneous layers with very high values of glass transition temperatures of 127–139 °C. It was determined that triplet energy values of the derivatives are, correspondingly, 2.82 eV for the derivative H1 and 2.81 eV for the host H2. The new derivatives were tested as hosts of emitting layers in blue, as well as in green phosphorescent OLEDs. The blue device with 15 wt.% of the iridium(III)[bis(4,6-difluorophenyl)-pyridinato-N,C2′]picolinate (FIrpic) emitter doping ratio in host material H2 exhibited the best overall characteristics with a power efficiency of 24.9 lm/W, a current efficiency of 23.9 cd/A, and high value of 10.3% of external quantum efficiency at 100 cd/m2. The most efficient green PhOLED with 10 wt% of Ir(ppy)3 {tris(2-phenylpyridine)iridium(III)} in the H2 host showed a power efficiency of 34.1 lm/W, current efficiency of 33.9 cd/A, and a high value of 9.4% for external quantum efficiency at a high brightness of 1000 cd/m2, which is required for lighting applications. These characteristics were obtained in non-optimized PhOLEDs under an ordinary laboratory atmosphere and could be improved in the optimization process. The results demonstrate that some of the new host materials are very promising components for the development of efficient phosphorescent devices.


2015 ◽  
Vol 3 (38) ◽  
pp. 9999-10006 ◽  
Author(s):  
Kunkun Liu ◽  
Xiang-Long Li ◽  
Ming Liu ◽  
Dongcheng Chen ◽  
Xinyi Cai ◽  
...  

A series of 9,9-diphenyl-9H-thioxanthene derivatives are reported as host materials in blue phosphorescent OLEDs, giving a maximum power efficiency of 69.7 lm W−1 and an external quantum efficiency of 29.0%.


2017 ◽  
Vol 41 (6) ◽  
pp. 2443-2457 ◽  
Author(s):  
Venugopal Thanikachalam ◽  
Elayaperumal Sarojpurani ◽  
Jayaraman Jayabharathi ◽  
Palanivel Jeeva

Blue emitting devices based on 2-(4′-9H-carbazol-9-yl)-[1,1′-styryl]-4-yl-1-benzylpiperidine-1H-phenanthro[9,10-d]imidazole (Cz-BPIS) exhibits blue emission with CIE coordinates of (0.16, 0.09), current density of 1.91 cd/A, power efficiency of 1.63 lm/W and external quantum efficiency of 2.61%.


2021 ◽  
Vol 16 (5) ◽  
pp. 844-848
Author(s):  
Beomsu Jang ◽  
Giwoong Han ◽  
Kiju Kim ◽  
Hakjun Lee ◽  
Young Kwan Kim ◽  
...  

In this study, two blue fluorescent using phenylanthracene-substituted furan derivatives were synthesized for organic light-emitting diodes (OLEDs) and subsequently characterized. To study the electroluminescent properties of the materials, OLED devices were fabricated using these two materials as an emissive layer (EML). The device using 7,7-diphenyl-9-(10-phenylanthracen-9-yl)-7H-fluoreno[4,3-b]benzofuran in the emitting layer showed the highest external quantum efficiency (EQE) value, 3.10%. It also showed the maximum luminance efficiency of 2.41 cd/A and maximum power efficiency of 1.90 lm/W with CIE coordinates of (0.15, 0.08).


2020 ◽  
Vol 20 (11) ◽  
pp. 6683-6687
Author(s):  
Soo Kyung Kang ◽  
Jeongkyu Woo ◽  
Ju Hee Han ◽  
Ki Ju Kim ◽  
Hakjun Lee ◽  
...  

In this study, we designed and synthesized two phosphorescent emitting materials based on tetradentate pyridine-containing ligands. Their photophysical properties were examined for OLEDs and multilayer devices using these materials were fabricated in the following sequence; ITO (180 nm)/4,4′,4″-Tris[2-naphthyl(phenyl)amino]triphenylamine (2-TNATA) (30 nm)/N,N′-di(1-naphthyl)-N,N′-diphenyl-1,1′-biphenyl)4,4′-diamine (NPB) (20 nm)/Tris(4-carbazoyl-9-ylphenyl)amine (TCTA) (10 nm)/4,4′-Bis(N-carbazolyl)-1,1′-biphenyl(CBP): 5, 8, 15% Platinum (II) complexes (20 nm)/1,3,5-Tris(1-Phenyl-1H-benzimidazol-2-yl)benzene) (TPBi) (40 nm)/Liq (2 nm)/Al (100 nm). In particularly, a device using Platinum (II) complex based on A/-(3,5-di-tert-butylphenyl)-6-phenyl-N-(6-phenylpyridin-2-yl)pyridin-2-amine ligand showed the efficient emission, with luminous efficiency, power efficiency, and external quantum efficiency, and the Commission International de LEclairge (CIE) coordinates of 29.29 cd/A, 9.37 lm/W, 8.66% at 20 mA/cm2, and (0.32, 0.62) at 8.0 V, respectively.


RSC Advances ◽  
2020 ◽  
Vol 10 (15) ◽  
pp. 8866-8879 ◽  
Author(s):  
Jayaraman Jayabharathi ◽  
Jagathratchagan Anudeebhana ◽  
Venugopal Thanikachalam ◽  
Sekar Sivaraj

OLED with C6/C9 substituted phenanthroimidazoles (DDPPPA/DDPBA) show blue emission with maximum external quantum efficiency (ηex), current efficiency (ηc) and power efficiency (ηp) of 5.7/6.0%, 10.5/12.0 cd A−1 and 8.3/9.2 lm W−1, respectively.


2017 ◽  
Vol 5 (46) ◽  
pp. 12050-12056 ◽  
Author(s):  
Chih-Chien Lee ◽  
Chun-Jen Shih ◽  
Gautham Kumar ◽  
Sajal Biring ◽  
Somaditya Sen ◽  
...  

An exciplex-forming phosphorescent OLED with nano-pinhole sputtered ITO exhibiting a maximum external quantum efficiency (power efficiency) of 34% (132.8 lm W−1) was achieved.


2016 ◽  
Vol 4 (12) ◽  
pp. 2274-2278 ◽  
Author(s):  
Ryutaro Komatsu ◽  
Hisahiro Sasabe ◽  
Yuki Seino ◽  
Kohei Nakao ◽  
Junji Kido

A series of TADF emitters composed of pyrimidine/acridine moieties are developed. The optimized device realized its highest power efficiency of 62 lm W−1, a high external quantum efficiency of 25%, and a low turn-on voltage of 2.8 V with light-blue emission.


RSC Advances ◽  
2016 ◽  
Vol 6 (68) ◽  
pp. 63200-63205 ◽  
Author(s):  
Yanan Li ◽  
Liang Zhou ◽  
Yunlong Jiang ◽  
Rongzhen Cui ◽  
Xuesen Zhao ◽  
...  

High performance green electroluminescent device with maximum brightness, current efficiency, power efficiency and external quantum efficiency (EQE) up to 113 610 cd m−2, 112.30 cd A−1, 97.95 lm W−1 and 29.4%, was realized.


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