Computational Study of Intramolecular Coordination Enhanced Oxidative Addition to form PdIV-Pincer Complexes, and Selectivity in Aryloxide Attack at PdIVCH2CRR′ Motifs in Palladium-Mediated Organic Synthesis

2021 ◽  
Author(s):  
Allan J. Canty ◽  
Alireza Ariafard
Keyword(s):  
Organic Synthesis ◽  
Computational Study ◽  
Oxidative Addition ◽  
Pincer Complexes ◽  
Intramolecular Coordination

ChemInform Abstract: Taylor-Made Palladium Pincer Complexes: A New Source of More Efficient Catalysts for Sustainable Organic Synthesis

ChemInform ◽  
2010 ◽  
Vol 41 (46) ◽  
pp. no-no
Author(s):  
Isabel Moreno ◽  
Raul SanMartin ◽  
Blanca Ines ◽  
Fatima Churruca ◽  
Esther Dominguez
Keyword(s):  
Organic Synthesis ◽  
Pincer Complexes

Computational study of the C I bimetallic oxidative addition at Pt M (M = Ni, Pd and Pt) reaction centers

Polyhedron ◽  
2019 ◽  
Vol 164 ◽  
pp. 35-40
Author(s):  
Elahe Haddadi ◽  
S. Masoud Nabavizadeh ◽  
Fatemeh Niroomand Hosseini
Keyword(s):  
Computational Study ◽  
Oxidative Addition ◽  
Reaction Centers

Combined Experimental/Computational Study of Iridium and Palladium Hydride PP(O)P Pincer Complexes

2014 ◽  
Vol 33 (2) ◽  
pp. 571-577 ◽  
Author(s):  
Carmen Martin ◽  
Sonia Mallet-Ladeira ◽  
Karinne Miqueu ◽  
Ghenwa Bouhadir ◽  
Didier Bourissou
Keyword(s):  
Computational Study ◽  
Pincer Complexes ◽  
Palladium Hydride

Iodomethane oxidative addition to β-diketonatobis(triphenylphosphite)rhodium(I) complexes: A synthetic, kinetic and computational study

Polyhedron ◽  
2011 ◽  
Vol 30 (13) ◽  
pp. 2345-2353 ◽  
Author(s):  
Marrigje M. Conradie ◽  
Johannes J.C. Erasmus ◽  
Jeanet Conradie
Keyword(s):  
Computational Study ◽  
Oxidative Addition

Selective C−C vs C−H Bond Activation by Rhodium(I) PCP Pincer Complexes. A Computational Study

2000 ◽  
Vol 122 (29) ◽  
pp. 7095-7104 ◽  
Author(s):  
Andreas Sundermann ◽  
Olivier Uzan ◽  
David Milstein ◽  
Jan M. L. Martin
Keyword(s):  
Bond Activation ◽  
Computational Study ◽  
Pincer Complexes ◽  
Pcp Pincer

Activation of C–F, Si–F, and S–F Bonds by N-Heterocyclic Carbenes and Their Isoelectronic Analogues

Synlett ◽  
2020 ◽  
Vol 31 (14) ◽  
pp. 1349-1360 ◽  
Author(s):  
Eunsung Lee ◽  
Ewa Pietrasiak
Keyword(s):  
Nucleophilic Substitution ◽  
Organic Synthesis ◽  
Bond Activation ◽  
Bond Cleavage ◽  
Oxidative Addition ◽  
Main Group ◽  
Heterocyclic Carbenes ◽  
Full Potential ◽  
Short Summary ◽  
Special Case

Reactions involving C–F, Si–F, and S–F bond cleavage with N-heterocyclic carbenes and isoelectronic species are reviewed. Most examples involve activation of aromatic C–F bond via an SNAr pathway and nucleophilic substitution of fluorine in electron-deficient olefins. The mechanism of the C–F bond activation depends on the reaction partners and the reaction can proceed via addition–elimination, oxidative addition (concerted or stepwise) or metathesis. The adducts formed upon substitution find applications in organic synthesis, as ligands and as stable radical precursors, but in most cases, their full potential remains unexplored.1 Introduction1.1 The C–F Bond1.2 C–F Bond Activation: A Short Summary1.3 C–F Bond Activation: A Special Case of SNAr1.4 N-Heterocyclic Carbenes (NHCs)1.5 The Purpose of this Article2 C–F bond Activation in Acyl Fluorides3 Activation of Vinylic C–F Bonds4 Activation of Aromatic C–F Bonds5 X–F Bond Activation (X = S or Si)6 C–F Bond Activation by Main Group Compounds Isoelectronic with NHCs7 Conclusions and Outlook

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