Direct Observation of Plasma-Stimulated Activation of Surface Species Using Multimodal In Situ/Operando Spectroscopy Combining Polarization-Modulation Infrared Reflection-Absorption Spectroscopy, Optical Emission Spectroscopy, and Mass Spectrometry

Author(s):  
Garam Lee ◽  
David B. Go ◽  
Casey P. O’Brien
Coatings ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1221
Author(s):  
Jun-Hyoung Park ◽  
Ji-Ho Cho ◽  
Jung-Sik Yoon ◽  
Jung-Ho Song

We present a non-invasive approach for monitoring plasma parameters such as the electron temperature and density inside a radio-frequency (RF) plasma nitridation device using optical emission spectroscopy (OES) in conjunction with multivariate data analysis. Instead of relying on a theoretical model of the plasma emission to extract plasma parameters from the OES, an empirical correlation was established on the basis of simultaneous OES and other diagnostics. Additionally, we developed a machine learning (ML)-based virtual metrology model for real-time Te and ne monitoring in plasma nitridation processes using an in situ OES sensor. The results showed that the prediction accuracy of electron density was 97% and that of electron temperature was 90%. This method is especially useful in plasma processing because it provides in-situ and real-time analysis without disturbing the plasma or interfering with the process.


2018 ◽  
Vol 659 ◽  
pp. 36-40 ◽  
Author(s):  
Guanghong Wang ◽  
Chengying Shi ◽  
Lei Zhao ◽  
Libin Mo ◽  
Hongwei Diao ◽  
...  

2000 ◽  
Vol 9 (3) ◽  
pp. 331-339 ◽  
Author(s):  
K Aumaille ◽  
A Granier ◽  
M Schmidt ◽  
B Grolleau ◽  
C Vallée ◽  
...  

1997 ◽  
Vol 493 ◽  
Author(s):  
F. Ayguavives ◽  
P. Aubert ◽  
B. Ea-Kim ◽  
B. Agius

ABSTRACTLead zirconate titanate (PZT) thin films have been grown by rf magnetron sputtering on Si substrates from a metallic target of nominal composition Pb1.1(Zr0.4 Ti0.6 in a reactive argon / oxygen gas mixture. During plasma deposition, in situ Optical Emission Spectroscopy (OES) measurements show clearly a correlation between the evolution of characteristic atomic emission line intensities (Zr - 386.4 nm, Ti - 399.9 nm, Pb - 405.8 nm and O - 777.2 nm) and the thin-film composition determined by a simultaneous use of Rutherford Backscattering Spectroscopy (RBS) and Nuclear Reaction Analysis (NRA).


2015 ◽  
Vol 30 (12) ◽  
pp. 2496-2506 ◽  
Author(s):  
Andreas Bierstedt ◽  
Ulrich Panne ◽  
Knut Rurack ◽  
Jens Riedel

A dielectric barrier discharge probe has been developed, which enables switching between two individual product channels yielding either protonated or ammoniated molecules.


The Analyst ◽  
2018 ◽  
Vol 143 (11) ◽  
pp. 2563-2573 ◽  
Author(s):  
Evans A. Monyoncho ◽  
Vlad Zamlynny ◽  
Tom K. Woo ◽  
Elena A. Baranova

Infrared spectroscopy is a powerful non-destructive technique for the identification and quantification of organic molecules widely used in scientific studies.


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