Stability of SiNx Prepared by Plasma-Enhanced Chemical Vapor Deposition at Low Temperature

In this paper, the environmental stability of silicon nitride (SiNx) films deposited at 80 °C by plasma-enhanced chemical vapor deposition was studied systematically. X-ray photoelectron spectroscopy and Fourier transform infrared reflection were used to analyze the element content and atomic bond structure of the amorphous SiNx films. Variation of mechanical and optical properties were also evaluated. It is found that SiNx deposited at low temperature is easily oxidized, especially at elevated temperature and moisture. The hardness and elastic modulus did not change significantly with the increase of oxidation. The changes of the surface morphology, transmittance, and fracture extensibility are negligible. Finally, it is determined that SiNx films deposited at low-temperature with proper processing parameters are suitable for thin-film encapsulation of flexible devices.

A Flexible Turning and Sensing System for Pressure Ulcers Prevention

Pressure ulcers (PU) are one of the most frequent hazards of long-term bedridden patients. With the continuous increase of aging, the number of long-term bedridden disabled and semi-disabled elderly people is increasing. At the same time, there is a serious shortage of professional pressure ulcer nursing staff. There is also a lack of flexible turning equipment for PU prevention. The research in the field of pressure ulcer prevention at home and abroad is carried out steadily, and the equipment for turning over by pneumatic or mechanical drive is developed. However, these devices often have insurmountable defects, such as complex structure, cost constraints, difficult control, weak body feeling, and so on. Under these circumstances, a set of pneumatic turnover mattresses based on clinical nursing methods have been developed. The mattress is divided into a turnover area and two support areas. The turnover airbag is linked with the support airbag to improve the patient’s comfort when passively turning over. The turnover amplitude and interval can be adjusted to provide a personalized turnover experience for bedridden patients. To improve the safety of the turning mattress during automatic turning, we also add a temperature sensor based on the principle of infrared reflection to monitor the status of bedridden patients, which can realize real-time temperature measurement, monitoring of getting out of bed and monitoring of the turning process.

Peculiarities of specular infrared reflection spectra of ZnO-based ceramics

Undoped and Mn-doped ZnO ceramics were theoretically and experimentally investigated using specular infrared reflection method. It was shown that infrared reflection spectra can be modeled using the parameters explored for ZnO single crystals. For ceramic samples, it was shown that ZnO grains with orientation of the C-axis along the normal to the electric field ( ) give the main contribution to IR reflection spectra. It has been ascertained that the surface roughness is manifested in these spectra mainly within the range 450…550 cm–1 giving negligible effect for the frequencies above longitudinal phonon frequency. This allowed the electrophysical parameters of ZnO crystallites to be evaluated. In the case of undoped ceramics, the obtained results were found to be consistent with the values of direct current measurements. This finding supports the utility of infrared spectroscopy for determination of the electrophysical parameters of polycrystalline ceramic materials. For Mn-doped ceramic samples, the conductivity value measured using the direct current method was found to be essentially lower than those determined from simulation of infrared reflection spectra. This phenomenon was explained by barrier formation at the grain boundaries in Mn-doped ZnO ceramics.

Study on Conventional and Rheological Properties of Corn Stalk Bioasphalt/PPA Composite Modified Asphalt

As a new type of pavement material, bioasphalt has received more and more attention. However, the high-temperature behavior of bioasphalt is poor after blending with asphalt binder. In order to solve this problem and facilitate the waste utilization and resource conservation, the corn stalk bioasphalt/PPA composite modified asphalt was proposed. The conventional performance tests and rheological tests were conducted to evaluate high-temperature and low-temperature behavior. Fourier transform infrared reflection (FTIR) test was undertaken to analyze the mechanism of modified asphalt. The results indicated that blended asphalt penetration and ductility gradually decrease with the PPA content increasing. The softening point and viscosity of the modified asphalt increased, which led to an improvement of blended asphalt’s rigidity. The PPA increased the rutting index of corn stalk bioasphalt/PPA composite modified asphalt. However, bioasphalt had a negative effect on its high-temperature performance. The corn stalk bioasphalt/PPA composite modified asphalt could meet the specification requirement at −18°C considering the creep rate and stiffness modulus, indicating it had outstanding crack resistance. When the PPA and bioasphalt respect to the weight of neat asphalt were 6%–8% and 10%–16%, respectively, the corn stalk bioasphalt/PPA composite modified asphalt performance was optimal. However, shear time and shear rate merely affected the proposed modified asphalt performance. The bioasphalt did not affect the chemical structure of asphalt. However, PPA generated new functional groups (P-O single bond, phosphate (RO)3P = O, and P=O double bond) causing a chemical modification in the asphalt binder. This study can provide a basis for applying bioasphalt, making road engineering more economical and environmentally friendly.

The Effect of Tytanit Foliar Application and Different Nitrogen on Fibre Fraction Content and the Feed Value of Festulolium braunii

The aim of the present study was to determine the effect of Tytanit foliar application, also comparing it with that of nitrogen, on the content of Festulolium braunii fibre fractions, its nutritional value and feed intake. The experiment showed that forage of better quality could be obtained by reducing the amounts of traditional nitrogen fertilisers, or excluding them and using a product containing titanium instead. The experiment commenced in the spring of 2014 in the field of the University of Natural Sciences and Humanities in Siedlce. The plant used in the experiment was the Felopa variety of Festulolium braunii. The effects of Tytanit foliar application at a concentration of 0.2% and 1% and of mineral nitrogen at a dose of 80 and 160 kg ha−1 were studied. Festulolium braunii was harvested three times a year in the period 2015–2017. The amounts of NFD, ADF, and ADL in the plant material were determined by near-infrared reflection spectroscopy (NIRS) using the NIRFex N-500. Relative feed value (RFV) and dry matter intake (DMI) were calculated. The higher dose of Tytanit supplied to Festulolium braunii contributed to an increase in NDF and ADF fraction content and a reduction in RFV and ADL fraction and DMI.