Two families of centered zirconium cluster phases with M1,2M'Cl6.Zr6Cl12Z compositions

1993 ◽  
Vol 32 (9) ◽  
pp. 1566-1572 ◽  
Author(s):  
Jie Zhang ◽  
John D. Corbett
Keyword(s):  
1988 ◽  
Vol 110 (5) ◽  
pp. 1511-1516 ◽  
Author(s):  
Timothy. Hughbanks ◽  
Guy. Rosenthal ◽  
John D. Corbett

2008 ◽  
Vol 63 (5) ◽  
pp. 507-512 ◽  
Author(s):  
Henning W. Rohm ◽  
Martin Köckerling

Rb[(Zr6C)Cl15] was prepared by heating ZrCl4, Zr powder, RbCl and Al4C3 at 850 °C for 21 days. The crystal structure was determined by single crystal X-ray diffraction (space group Pmma, a = 18.484(3), b = 18.962(2), c = 9.708(1) Å, V = 2505.4(6) Å3, and Z = 4). Rb[(Zr6C)Cl15] crystallises in the Cs[Nb6Cl15]-type structure. It is built up from two interconnected types of cluster chains, one with linear Zr−Cla−a-Zr bridges, the other one with bent bridges. The rubidium cations are spread over three different sites within the cluster network which differs significantly from the cation distribution in the comparable potassium and caesium phases. The cation distribution can be rationalised considering the size of the cavities and the Coulombic interactions.


2019 ◽  
Vol 386 ◽  
pp. 32-49 ◽  
Author(s):  
Zhijie Chen ◽  
Sylvia L. Hanna ◽  
Louis R. Redfern ◽  
Dalal Alezi ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  

CrystEngComm ◽  
2018 ◽  
Vol 20 (35) ◽  
pp. 5132-5136 ◽  
Author(s):  
Bahareh Nateghi ◽  
Ishtvan Boldog ◽  
Konstiantyn V. Domasevitch ◽  
Christoph Janiak
Keyword(s):  

The largest known zirconium cluster with an idealized formula of [Zr26O18(OH)30(HCOO)38] was obtained via solvolysis of ZrOCl2 in DMF/HCOOH.


ChemInform ◽  
1988 ◽  
Vol 19 (22) ◽  
Author(s):  
T. HUGHBANKS ◽  
G. ROSENTHAL ◽  
J. D. CORBETT

2004 ◽  
Vol 43 (4) ◽  
pp. 1350-1358 ◽  
Author(s):  
A. Otero ◽  
J. Fernández-Baeza ◽  
A. Antiñolo ◽  
J. Tejeda ◽  
A. Lara-Sánchez ◽  
...  

1980 ◽  
Vol 19 (10) ◽  
pp. 3172-3175 ◽  
Author(s):  
James Kleppinger ◽  
Julie Wrazel ◽  
Joseph C. Calabrese ◽  
Edwin M. Larsen

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