Deprotonated p-phenylenediamines as noninnocent ligands. Metal-to-ligand spin transfer in the ground state and ligand-to-metal charge transfer in the lowest excited state of low-spin manganese(II) complexes

1987 ◽  
Vol 26 (21) ◽  
pp. 3596-3600 ◽  
Author(s):  
Renate Gross ◽  
Wolfgang Kaim
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Ground State ◽  
Spin Transfer ◽  
Metal Charge ◽  
Metal Charge Transfer

scholarly journals Time-Resolved Spectroscopy of the Metal-to-Metal Charge Transfer Excited State in Dinuclear Cyano-Bridged Mixed-Valence Complexes

2005 ◽  
Vol 44 (15) ◽  
pp. 5530-5536 ◽  
Author(s):  
Brendan P. Macpherson ◽  
Paul V. Bernhardt ◽  
Andreas Hauser ◽  
Stéphane Pagès ◽  
Eric Vauthey
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Mixed Valence ◽  
Time Resolved ◽  
Metal Charge ◽  
Time Resolved Spectroscopy ◽  
Metal Charge Transfer

The ligand-to-metal charge transfer excited state of [Re(dmpe)3]2+

2021 ◽  
Author(s):  
Tayliz M. Rodriguez ◽  
Mawuli Deegbey ◽  
Elena Jakubikova ◽  
Jillian L. Dempsey
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Metal Charge ◽  
Metal Charge Transfer

Ferromagnetic coupling in d1–d3 linear oxido-bridged heterometallic complexes: ground-state models of metal-to-metal charge transfer excited states

2015 ◽  
Vol 44 (43) ◽  
pp. 18937-18944 ◽  
Author(s):  
Tao Huang ◽  
Xinyuan Wu ◽  
Xiao Song ◽  
Hao Xu ◽  
Tatyana I. Smirnova ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Excited States ◽  
Ground State ◽  
Magnetic Coupling ◽  
Heterometallic Complexes ◽  
Ferromagnetic Coupling ◽  
Metal Charge ◽  
State Models ◽  
Metal Charge Transfer

Linear heterobimetallic oxido-bridged d1–d3 compounds are described which are proposed as models for magnetic coupling of MMCT excited states.

Luminescence properties of Yb3+-doped SrTiO3: the significance of the oxygen–titanium charge transfer state on photon downshifting

2019 ◽  
Vol 48 (31) ◽  
pp. 11889-11896 ◽  
Author(s):  
Germán López-Pacheco ◽  
Rigoberto López-Juárez ◽  
María Elena Villafuerte-Castrejón ◽  
Ciro Falcony ◽  
Enrique Barrera-Calva ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Excited State ◽  
Charge Transfer ◽  
Energy Transfer Process ◽  
Spectral Responsivity ◽  
Metal Charge ◽  
Pv Cell ◽  
Uv Excitation ◽  
Metal Charge Transfer ◽  
Transfer State

Photon downshifting in SrTiO3:Yb3+ to wavelengths where a PV cell has its higher spectral responsivity is achieved upon UV excitation through an energy transfer process from a ligand-to-metal-charge transfer O2− → Ti4+ state to the Yb3+ excited state.

Excited State Properties of Myochrysin and Auranofin

1996 ◽  
Vol 51 (8) ◽  
pp. 1067-1071 ◽  
Author(s):  
Horst Kunkely ◽  
Arnd Vogler
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Solid State ◽  
Sodium Aurothiomalate ◽  
Metal Charge ◽  
Metal Charge Transfer

Myochrysin (sodium aurothiomalate hydrate) and auranofin [2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranosato-S)(triethylphospine)gold(I)] are luminescent in the solid state and in ethanol glasses at 77 K (myochrysin: λmax = 600 nm; auranofin: 618 nm). Aqueous myochrysin and auranofin in acetonitrile undergo a photodecomposition. It is assumed that the luminecence originates from a metal-centered ds excited state with partial ligand-to-metal charge transfer (LMCT) character while the photodecomposition is induced by LMCT excitation.

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