The role of the termination reaction hydrogen atoms + methyl radicals .fwdarw. methane in the pyrolysis of propane in the temperature range 1100-1300 K

The reaction of methyl radicals with a group of amines and amine-like compounds has been investigated in the temperature range 125° to 157 °C. The abstraction activation energies of hydrogen atoms from these compounds, the corresponding pre-exponential factors, and the actual reaction rates indicate that the N—H hydrogen atoms are more labile than the C—H atoms in these compounds.

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Radical displacement reactions: The vapor phase reaction of methyl radicals with allyl formate

Canadian Journal of Chemistry ◽

10.1139/v68-397 ◽

1968 ◽

Vol 46 (14) ◽

pp. 2451-2454

Author(s):

G. Greig ◽

J. C. J. Thynne

Keyword(s):

Vapor Phase ◽

Phase Reaction ◽

Displacement Reaction ◽

Methyl Radicals ◽

Hydrogen Atoms ◽

Temperature Range ◽

Principal Reaction ◽

Displacement Reactions ◽

Vapor Phase Reaction

Trideuteromethyl radicals have been reacted in the vapor phase with allyl formate and the principal reaction over the temperature range 100–250 °C has been shown to be the displacement reaction[Formula: see text][Formula: see text]Hydrogen atoms generated by this decomposition also react readily to produce propylene by the reaction[Formula: see text]

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Heterogeneous reactions of hydrogen atoms and methyl radicals with a diamond surface in the 300-1133 K temperature range

The Journal of Physical Chemistry ◽

10.1021/j100147a036 ◽

1993 ◽

Vol 97 (45) ◽

pp. 11787-11796 ◽

Cited By ~ 56

Author(s):

Lev N. Krasnoperov ◽

Ilia J. Kalinovski ◽

Hae Nuh Chu ◽

David Gutman

Keyword(s):

Heterogeneous Reactions ◽

Diamond Surface ◽

Methyl Radicals ◽

Hydrogen Atoms ◽

Temperature Range

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Ethanol conversion over Ga2O3-ZrO2 solid solution: empirical evidences of the reaction pathway, the surface acid–base property, and role of isolated gallium ion

Catalysis Science & Technology ◽

10.1039/d0cy02271c ◽

2021 ◽

Author(s):

Takashi Yamamoto ◽

Akihito Kurimoto ◽

Riona Sato ◽

Shoki Katada ◽

Hirotaka Mine ◽

...

Keyword(s):

Solid Solution ◽

Reaction Pathway ◽

Ethanol Conversion ◽

Acid Base ◽

Base Property ◽

Temperature Range ◽

Acid Base Property

Ethanol conversion by Ga2O3-ZrO2 solid solution was examined in the temperature range 573–773 K, and acetone/isobutene formation was confirmed under cofeeding of H2O vapor. The reaction pathway was empirically investigated...

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