Synthesis and Alkali Metal Ion-Binding Properties of a Chromium(III) Triacetylide Complex

2002 ◽  
Vol 124 (39) ◽  
pp. 11588-11589 ◽  
Author(s):  
Louise A. Berben ◽  
Jeffrey R. Long
2000 ◽  
Vol 122 (7) ◽  
pp. 1486-1491 ◽  
Author(s):  
Michael T. Blanda ◽  
Dustin B. Farmer ◽  
Jennifer S. Brodbelt ◽  
Brian J. Goolsby

1995 ◽  
Vol 36 (7) ◽  
pp. 1093-1094 ◽  
Author(s):  
Hatsuo Yamamura ◽  
Hideki Nagaoka ◽  
Masao Kawai ◽  
Yasuo Butsugan ◽  
Kahee Fujita

2004 ◽  
Vol 69 (5) ◽  
pp. 1109-1125 ◽  
Author(s):  
George Ferguson ◽  
Alan J. Lough ◽  
Anna Notti ◽  
Sebastiano Pappalardo ◽  
Melchiorre F. Parisi ◽  
...  

The syntheses of 1,3-bis(α-picolyloxy)-p-tert-butylcalix[4]arene crown-6 and 1,1'-binaphthalene-2,2'-diyl crown-6 title conformers have been achieved by two complementary synthetic strategies, which differ in the order in which the polyether loop and the pendant picolyl groups are introduced. The structure and conformation of all new compounds have been firmly established by NMR spectroscopy, and further proven by X-ray analysis for the intermediate p-tert-butyl-25,27-(1,1'-binaphthalene-2,2'-diyl-crown-6)-26,28-dihydroxycalix[4]arene. Within each set of conformers, the nature of the polyether chain has little or no influence on the overall conformation of the calixarene platform. The alkali metal ion binding selectivities of the two series of calixarenes have been evaluated in competitive complexation experiments by electrospray ionization mass spectrometry. In the p-tert-butylcalix[4]arene crown-6 series, partial cone and 1,3-alternate conformers show a peak selectivity for the larger Cs+ ions, while the cone one preferentially binds the smaller Na+ ions. On the other hand, the cone and 1,3-alternate binaphthyl-containing analogues show a preference for Na+ ions, the partial cone being quite unselective.


2008 ◽  
Vol 112 (37) ◽  
pp. 8578-8584 ◽  
Author(s):  
Matthew F. Bush ◽  
Jos Oomens ◽  
Richard J. Saykally ◽  
Evan R. Williams

2010 ◽  
Vol 21 (7) ◽  
pp. 1245-1255 ◽  
Author(s):  
Eun Sun Hong ◽  
Hye-Joo Yoon ◽  
Byungjoo Kim ◽  
Yong-Hyeon Yim ◽  
Hun-Young So ◽  
...  

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