Studies on alternating radical copolymerization: analysis of microstructures of styrene-maleic anhydride, styrene-acrylonitrile, and styrene-methyl methacrylate copolymers by fluorescence spectroscopy

1989 ◽  
Vol 22 (11) ◽  
pp. 4204-4208 ◽  
Author(s):  
Weiping Zeng ◽  
Yasuhiko Shirota
Keyword(s):  
Maleic Anhydride ◽  
Fluorescence Spectroscopy ◽  
Methyl Methacrylate ◽  
Radical Copolymerization ◽  
Methacrylate Copolymers ◽  
Styrene Acrylonitrile ◽  
Styrene Maleic Anhydride

Living radical copolymerization of styrene/maleic anhydride

2000 ◽  
Vol 38 (12) ◽  
pp. 2239-2244 ◽  
Author(s):  
Eun-Soo Park ◽  
Mal-Nam Kim ◽  
Ik-Mo Lee ◽  
Han Sup Lee ◽  
Jin-San Yoon
Keyword(s):  
Maleic Anhydride ◽  
Radical Copolymerization ◽  
Styrene Maleic Anhydride

Rigid Interior of Styrene−Maleic Anhydride Copolymer Aggregates Probed by Fluorescence Spectroscopy

Langmuir ◽  
2002 ◽  
Vol 18 (10) ◽  
pp. 3829-3835 ◽  
Author(s):  
Jérôme Claracq ◽  
Sergio F. C. R. Santos ◽  
Jean Duhamel ◽  
Christophe Dumousseaux ◽  
Jean-Marc Corpart
Keyword(s):  
Maleic Anhydride ◽  
Fluorescence Spectroscopy ◽  
Styrene Maleic Anhydride ◽  
Maleic Anhydride Copolymer

Study on Synthesis and Characterization of Styrene-Maleic Anhydride Random Copolymer by Xylene

2013 ◽  
Vol 750-752 ◽  
pp. 1075-1078
Author(s):  
Ting Ting Li ◽  
Zhi Ming Zhang ◽  
He Ti Li ◽  
Jie Cao
Keyword(s):  
Maleic Anhydride ◽  
Molar Fraction ◽  
Evaluation Criteria ◽  
Random Copolymer ◽  
Radical Copolymerization ◽  
Alternating Copolymer ◽  
Styrene Maleic Anhydride ◽  
Maleic Anhydride Copolymer ◽  
Alternating Copolymerization

Radical copolymerization of styrene (St) and maleic anhydride (MA) were typically alternating copolymerization, which generated copolymer styrene-maleic anhydride (SMA). The copolymer was synthesized by solution polymerization method,with benzoyl peroxide (BPO) as initiator and xylene as solvent, and using the yield of copolymer as evaluation criteria, the reaction conditions were researched. The maleic anhydride of molar fraction was 45% in the copolymer measured by chemical titration, combined with the theoretical that the synthesis of styrene-maleic anhydride copolymer was confirmed to be the alternating copolymer. The structure and character of the copolymer was also confirmed by IR. The glass-transition temperature of the alternating copolymer was tested by DSC.

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