In Situ Quantitative1H NMR Monitoring of Monomer Consumption:  A Simple and Fast Way of Estimating Reactivity Ratios

2002 ◽  
Vol 35 (6) ◽  
pp. 2036-2041 ◽  
Author(s):  
María Rosa Aguilar ◽  
Alberto Gallardo ◽  
María del Mar Fernández ◽  
Julio San Román
Keyword(s):  
2018 ◽  
Vol 57 (46) ◽  
pp. 15654-15662 ◽  
Author(s):  
Jiangyan Feng ◽  
Olabode O. Oyeneye ◽  
William Z. Xu ◽  
Paul A. Charpentier

e-Polymers ◽  
2007 ◽  
Vol 7 (1) ◽  
Author(s):  
Ichim Ionut Cameliu ◽  
Marius Ciprian Rusu ◽  
Mihai Rusu ◽  
Popa Marcel ◽  
Christelle Delaite ◽  
...  

AbstractAn important method used to make medical implants radiologically visible is based on introduction of radiopaque bromine or iodine containing methacrylic monomers. Thus, 2-(2-bromopropionyloxy) propyl methacrylate (BPPM) and 2-(2-bromoisobutyryloxy) propyl methacrylate (BIPM) were synthesized with the aim to use them as radiopaque agents. The free radical initiated copolymerization of BPPM and BIPM with methyl methacrylate (MMA) were performed directly in a thermostatic cell of the NMR spectrometer. The copolymer compositions obtained from 1H NMR spectra led to the determination of the reactivity ratios (rMMA = 1.08 ± 0.12; rBPPM = 1.01 ± 0.13 and rMMA = 0.95 ± 0.09; rBIPM = 0.95 ± 0.1). The reactivity ratios of these two monomers is similar to that of MMA suggesting that the length of the bromine containing monomers side chain does not affect significantly the reactivity of the methacrylic double bond. From the results we conclude the copolymers to have random structure.


Polymer ◽  
2005 ◽  
Vol 46 (7) ◽  
pp. 2040-2046 ◽  
Author(s):  
Elena Larraz ◽  
Carlos Elvira ◽  
Alberto Gallardo ◽  
Julio San Román

2019 ◽  
Vol 10 (22) ◽  
pp. 2863-2871 ◽  
Author(s):  
Jan Blankenburg ◽  
Erik Kersten ◽  
Kamil Maciol ◽  
Manfred Wagner ◽  
Sirus Zarbakhsh ◽  
...  

An investigation of the copolymerization of EO and PO by in situ1H NMR spectroscopy reveals striking differences in the monomer gradient, depending on the polymerization method.


1984 ◽  
Vol 75 ◽  
pp. 743-759 ◽  
Author(s):  
Kerry T. Nock

ABSTRACTA mission to rendezvous with the rings of Saturn is studied with regard to science rationale and instrumentation and engineering feasibility and design. Future detailedin situexploration of the rings of Saturn will require spacecraft systems with enormous propulsive capability. NASA is currently studying the critical technologies for just such a system, called Nuclear Electric Propulsion (NEP). Electric propulsion is the only technology which can effectively provide the required total impulse for this demanding mission. Furthermore, the power source must be nuclear because the solar energy reaching Saturn is only 1% of that at the Earth. An important aspect of this mission is the ability of the low thrust propulsion system to continuously boost the spacecraft above the ring plane as it spirals in toward Saturn, thus enabling scientific measurements of ring particles from only a few kilometers.


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