scholarly journals Catalytic production of impurity-free V3.5+ electrolyte for vanadium redox flow batteries

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Jiyun Heo ◽  
Jae-Yun Han ◽  
Soohyun Kim ◽  
Seongmin Yuk ◽  
Chanyong Choi ◽  
...  

Abstract The vanadium redox flow battery is considered one of the most promising candidates for use in large-scale energy storage systems. However, its commercialization has been hindered due to the high manufacturing cost of the vanadium electrolyte, which is currently prepared using a costly electrolysis method with limited productivity. In this work, we present a simpler method for chemical production of impurity-free V3.5+ electrolyte by utilizing formic acid as a reducing agent and Pt/C as a catalyst. With the catalytic reduction of V4+ electrolyte, a high quality V3.5+ electrolyte was successfully produced and excellent cell performance was achieved. Based on the result, a prototype catalytic reactor employing Pt/C-decorated carbon felt was designed, and high-speed, continuous production of V3.5+ electrolyte in this manner was demonstrated with the reactor. This invention offers a simple but practical strategy to reduce the production cost of V3.5+ electrolyte while retaining quality that is adequate for high-performance operations.

2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
Sang-Ho Cha

The vanadium redox flow battery (VRB) has received considerable attention due to its long cycle life, flexible design, fast response time, deep-discharge capability, and low pollution emissions in large-scale energy storage. The key component of VRB is an ion exchange membrane that prevents cross mixing of the positive and negative electrolytes by separating two electrolyte solutions, while allowing the conduction of ions. This review summarizes efforts in developing nanocomposite membranes with reduced vanadium ion permeability and improved proton conductivity in order to achieve high performance and long life of VRB systems. Moreover, functionalized nanocomposite membranes will be reviewed for the development of next-generation materials to further improve the performance of VRB, focusing on their properties and performance of VRB.


Energies ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 176
Author(s):  
Iñigo Aramendia ◽  
Unai Fernandez-Gamiz ◽  
Adrian Martinez-San-Vicente ◽  
Ekaitz Zulueta ◽  
Jose Manuel Lopez-Guede

Large-scale energy storage systems (ESS) are nowadays growing in popularity due to the increase in the energy production by renewable energy sources, which in general have a random intermittent nature. Currently, several redox flow batteries have been presented as an alternative of the classical ESS; the scalability, design flexibility and long life cycle of the vanadium redox flow battery (VRFB) have made it to stand out. In a VRFB cell, which consists of two electrodes and an ion exchange membrane, the electrolyte flows through the electrodes where the electrochemical reactions take place. Computational Fluid Dynamics (CFD) simulations are a very powerful tool to develop feasible numerical models to enhance the performance and lifetime of VRFBs. This review aims to present and discuss the numerical models developed in this field and, particularly, to analyze different types of flow fields and patterns that can be found in the literature. The numerical studies presented in this review are a helpful tool to evaluate several key parameters important to optimize the energy systems based on redox flow technologies.


2011 ◽  
Vol 105-107 ◽  
pp. 2217-2220
Author(s):  
Mu Lan Wang ◽  
Jian Min Zuo ◽  
Kun Liu ◽  
Xing Hua Zhu

In order to meet the development demands for high-speed and high-precision of Computer Numerical Control (CNC) machine tools, the equipped CNC systems begin to employ the technical route of software hardening. Making full use of the advanced performance of Large Scale Integrated Circuits (LSIC), this paper puts forward using Field Programmable Gates Array (FPGA) for the functional modules of CNC system, which is called Intelligent Software Hardening Chip (ISHC). The CNC system architecture with high performance is constructed based on the open system thought and ISHCs. The corresponding programs can be designed with Very high speed integrate circuit Hardware Description Language (VHDL) and downloaded into the FPGA. These hardening modules, including the arithmetic module, contour interpolation module, position control module and so on, demonstrate that the proposed schemes are reasonable and feasibility.


Author(s):  
Vinay Sriram ◽  
David Kearney

High speed infrared (IR) scene simulation is used extensively in defense and homeland security to test sensitivity of IR cameras and accuracy of IR threat detection and tracking algorithms used commonly in IR missile approach warning systems (MAWS). A typical MAWS requires an input scene rate of over 100 scenes/second. Infrared scene simulations typically take 32 minutes to simulate a single IR scene that accounts for effects of atmospheric turbulence, refraction, optical blurring and charge-coupled device (CCD) camera electronic noise on a Pentium 4 (2.8GHz) dual core processor [7]. Thus, in IR scene simulation, the processing power of modern computers is a limiting factor. In this paper we report our research to accelerate IR scene simulation using high performance reconfigurable computing. We constructed a multi Field Programmable Gate Array (FPGA) hardware acceleration platform and accelerated a key computationally intensive IR algorithm over the hardware acceleration platform. We were successful in reducing the computation time of IR scene simulation by over 36%. This research acts as a unique case study for accelerating large scale defense simulations using a high performance multi-FPGA reconfigurable computer.


2020 ◽  
Vol 355 ◽  
pp. 136755 ◽  
Author(s):  
C. Busacca ◽  
O. Di Blasi ◽  
G. Giacoppo ◽  
N. Briguglio ◽  
V. Antonucci ◽  
...  

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