scholarly journals Elastic organic crystals with ultralong phosphorescence for flexible anti-counterfeiting

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Kaiwei Huang ◽  
Lulu Song ◽  
Kun Liu ◽  
Anqi Lv ◽  
Manjeet Singh ◽  
...  

AbstractUltralong organic phosphorescence (UOP) crystals have attracted increased attention due to the distinct photophysical property of a long-lived lifetime. However, organic crystals are generally brittle, leading to a serious problem for their application in flexible technology. Herein, we report three types of elastic organic crystals (EOCs) with ultralong phosphorescence via introducing halogen atoms (Cl, Br, I) into π-conjugated phosphorescent molecules. Especially, the crystal containing iodine atoms displayed both excellent elasticity (ε = 3.01%) and high phosphorescent efficiency (ΦPh = 19.1%) owing to the strong halogen bonds. Taking advantage of its highly efficient UOP and excellent elasticity, we successfully used a DCz4I crystal for anti-counterfeiting application. These findings may provide guidance for the development of elastic crystals with afterglow and expand the scope of potential applications on flexible materials.

MRS Bulletin ◽  
1997 ◽  
Vol 22 (6) ◽  
pp. 31-38 ◽  
Author(s):  
Yang Yang

Electroluminescence (EL) is the emission of light generated from the radiative recombination of electrons and holes electrically injected into a luminescent semiconductor. Conventional EL devices are made of inorganic direct-bandgap semiconductors, such as GaAs and InGaAs. Recently EL devices based on conjugated organic small molecules and polymers have attracted increasing attention due to easy fabrication of large areas, unlimited choice of colors, and mechanical flexibility. Potential applications of these organic/polymeric EL devices include backlights for displays, alphanumeric displays, and high-density information displays.Electroluminescence from an organic material was first demonstrated in the 1960s on anthracene crystals by Pope et al. at New York University. Subsequently several other groups also observed this phenomenon in organic crystals and thin films. These organic EL devices had high operating voltages and low quantum efficiency. Consequently they did not attract much attention. In 1987 a breakthrough was made by Tang and VanSlyke at Eastman Kodak who found that by using multilayers of sublimated organic molecules, the operating voltage of the organic EL devices was dramatically reduced and the quantum efficiency was significantly enhanced. This discovery touched off a flurry of research activity, especially in Japan. The Japanese researchers, as welt as the group at Kodak, have since improved the device efficiency and lifetime to meet commercial requirements. This progress is reviewed by Tsutsui in this issue.


2017 ◽  
Vol 53 (77) ◽  
pp. 10711-10714 ◽  
Author(s):  
Xian Zhang ◽  
Guoqiang Liu ◽  
Cuijiao Zhao ◽  
Guozhong Wang ◽  
Yunxia Zhang ◽  
...  

The introduction of Mn can effectively regulate the electronic structure of Ni hydroxides on CFC, exhibiting superior electrocatalytic oxidation activity toward urea and potential applications in energy-saving rechargeable Zn–air batteries.


2021 ◽  
Vol 57 (3) ◽  
pp. 344-350
Author(s):  
X. Zhao ◽  
L. Chen ◽  
Q. Ren ◽  
Z. Wu ◽  
S. Fang ◽  
...  

2017 ◽  
Vol 5 (18) ◽  
pp. 4543-4548 ◽  
Author(s):  
Wenyu Ji ◽  
Ting Wang ◽  
Bingyan Zhu ◽  
Han Zhang ◽  
Rong Wang ◽  
...  

Flexible quantum dot light emitting diodes (QLEDs) are highly desired due to their advantages of foldability, lightweight, and potential applications in lighting and displays.


Synthesis ◽  
2020 ◽  
Vol 52 (04) ◽  
pp. 574-580
Author(s):  
Nicolas Jacob ◽  
Lucas Guillemard ◽  
Joanna Wencel-Delord

Although 3-azoindoles have recently emerged as an appealing family of photoswitch molecules, the synthesis of such compounds has been poorly covered in the literature. Herein a high-yielding and operationally simple protocol is reported allowing the synthesis of 3-azoindoles, featuring important steric hindrance around the azo motif. Remarkably, this C–H coupling is characterized by excellent atom economy and occurs under metal-free conditions, at room temperature, and within few minutes, delivering the expected products in excellent yields (quantitatively in most of the cases). Accordingly, a library of new molecules, with potential applications as photochromic compounds, is prepared.


Author(s):  
Clemens Ruchert ◽  
Carlo Vicario ◽  
Fernando Ardana ◽  
Christoph P. Hauri

RSC Advances ◽  
2020 ◽  
Vol 10 (26) ◽  
pp. 15091-15097 ◽  
Author(s):  
Lei Ge ◽  
Meng Zhang ◽  
Ran Wang ◽  
Na Li ◽  
Lexin Zhang ◽  
...  

New functional CS/GA/RGO/Pd composite hydrogels are prepared via a self-assembly process, demonstrating potential applications in catalysis as well as composite materials.


2015 ◽  
Vol 3 (20) ◽  
pp. 5275-5284 ◽  
Author(s):  
Qiwei Zhang ◽  
Ke Chen ◽  
Leilei Wang ◽  
Haiqin Sun ◽  
Xusheng Wang ◽  
...  

Multifunctional luminescent materials based on rare earth doped ferro-/piezoelectrics have attracted much attention due to their potential applications in novel multifunctional devices.


2016 ◽  
Vol 18 (21) ◽  
pp. 14222-14227 ◽  
Author(s):  
Huimei Liu ◽  
Bo Xu ◽  
J.-M. Liu ◽  
Jiang Yin ◽  
Feng Miao ◽  
...  

ReS2is a stable and efficient photocatalyst with potential applications in the use of solar energy for water splitting.


2015 ◽  
Vol 3 (3) ◽  
pp. 499-505 ◽  
Author(s):  
Lu Wang ◽  
Zhenyu Zhang ◽  
Xiao Cheng ◽  
Kaiqi Ye ◽  
Feng Li ◽  
...  

The present study not only provides a rare example of organic crystals with highly efficient red fluorescence but also indicates the possible application of four-coordinate boron materials in organic solid-state lasers.


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