Ionization energy of o-fluoroaniline and vibrational levels of o-fluoroaniline cation determined by mass-analyzed threshold ionization spectroscopy

2000 ◽  
Vol 2 (17) ◽  
pp. 3759-3763 ◽  
Author(s):  
Jung Lee Lin ◽  
Wen Bih Tzeng
2015 ◽  
Vol 113 (24) ◽  
pp. 3918-3924 ◽  
Author(s):  
Clément Lauzin ◽  
Ugo Jacovella ◽  
Frédéric Merkt

1976 ◽  
Vol 54 (20) ◽  
pp. 2074-2092 ◽  
Author(s):  
E. Miescher

The absorption spectrum of cold NO gas has been photographed at high resolution between 1400 and 1250 Å for two isotopic species. Resolved bands of the Rydberg series converging to vibrational levels of the 1Σ+ ground state of NO+ are studied. They include nf–X bands up to n = 15 and ns–X bands up to n = 11, all of which show sharp rotational structure. The higher members of the np–X series are generally very diffuse with only npσ being sufficiently sharp to show broadened rotational lines. Also mostly diffuse are the ndδ–X bands. The bands ndσ, π–X are not observed. The rapidly (n−3) narrowing structure of the nf complexes is discussed and the ionization energy [Formula: see text] accurately determined by extrapolation of selected rotational lines. Interactions between Rydberg states are numerous, s ~ d mixing produces a strong effect above n = 6 when (n + 1)s levels fuse with nl levels into 'supercomplexes'. Matrix elements are given for observed 8f ~ 9s and 6f ~ 6dδ interactions.Valence levels are not observed above the ionization energy, except for the repulsive state A′2Σ+ arising from the first dissociation limit and seemingly assuming Rydberg character at molecular internuclear distance. Observed anomalies are qualitatively discussed.


LAP 2012 ◽  
2012 ◽  
pp. 85-88
Author(s):  
Jae Han Kim ◽  
Do Won Kang ◽  
Yong Jun Hong ◽  
Hyonseok Hwang ◽  
Hong Lae Kim ◽  
...  

1992 ◽  
Vol 162 (2-3) ◽  
pp. 433-438 ◽  
Author(s):  
Naoki Sato ◽  
Yahachi Saito ◽  
Hisanori Shinohara

2003 ◽  
Vol 380 (3-4) ◽  
pp. 337-341 ◽  
Author(s):  
Bing Zhang ◽  
Udo Aigner ◽  
Heinrich Ludwig Selzle ◽  
Edward William Schlag

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