Three-dimensional lanthanide–silver heterometallic coordination polymers: syntheses, structures and properties

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Zhi Su ◽  
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Yi-Zhi Li ◽  
...  
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Wei-Yin Sun ◽  
...  

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Yan-Fen Peng ◽  
Bao-Long Li ◽  
...  

2015 ◽  
Vol 68 (6) ◽  
pp. 956 ◽  
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Ming-An Dang ◽  
Zi-Feng Li ◽  
Ying Liu ◽  
Gang Li

Three coordination polymers [Sr(p-H2MOPhIDC)2]n (1) (p-H3MOPhIDC = 2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid), {[Cd2(p-HMOPhIDC)2(4,4′-bipy)]⋅H2O}n (4,4′-bipy = 4,4′-bipyridine) (2), and [Zn(p-HMOPhIDC)(4,4′-bipy)]n (3) have been solvothermally synthesized, and structurally characterized by single-crystal X-ray diffraction. Polymer 1 indicates a three-dimensional framework, which can be simplified as a 6-connected lattice. Polymer 2 is also a three-dimensional framework, and contains mixed bridging ligands HMOPhIDC2– and 4,4′-bipy. Polymer 3 exhibits a sheet structure bearing infinite rectangles. The coordination modes of the p-H3MOPhIDC ligand, and the thermal and solid-state photoluminescence properties of the polymers have been investigated as well.


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