Production of butene oligomers as transportation fuels using butene for esterification of levulinic acid from lignocellulosic biomass: process synthesis and technoeconomic evaluation

2012 ◽  
Vol 14 (12) ◽  
pp. 3289 ◽  
Author(s):  
S. Murat Sen ◽  
Elif I. Gürbüz ◽  
Stephanie G. Wettstein ◽  
David Martin Alonso ◽  
James A. Dumesic ◽  
...  
Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1234
Author(s):  
Zhiwei Jiang ◽  
Di Hu ◽  
Zhiyue Zhao ◽  
Zixiao Yi ◽  
Zuo Chen ◽  
...  

Efficient conversion of renewable biomass into value-added chemicals and biofuels is regarded as an alternative route to reduce our high dependence on fossil resources and the associated environmental issues. In this context, biomass-based furfural and levulinic acid (LA) platform chemicals are frequently utilized to synthesize various valuable chemicals and biofuels. In this review, the reaction mechanism and catalytic system developed for the generation of furfural and levulinic acid are summarized and compared. Special efforts are focused on the different catalytic systems for the synthesis of furfural and levulinic acid. The corresponding challenges and outlooks are also observed.


2012 ◽  
Vol 67 (1) ◽  
pp. 57-67 ◽  
Author(s):  
S. Murat Sen ◽  
Carlos A. Henao ◽  
Drew J. Braden ◽  
James A. Dumesic ◽  
Christos T. Maravelias

Declining supplies of fossil fuels, increasing population, global industrialization, and demand for transportation fuels have triggered an increase in the demand for renewable energy sources. To address such problems most of the green research in recent years has focused on the development of bioethanol (23 MJ/L) as a substitute to conventional gasoline (34.3 MJ/L) based fuels owing to the similarity in energy density values in addition to several other advantages (American Council on renewable energy, 2010). Second-generation biofuels are derived from lignocellulosic biomass or woody crops, mostly coming from agricultural residues. Extraction of fuel from such biomass is difficult because of their recalcitrant nature (corn stover, rice straw, wheat straw, sugar cane, and sweet sorghum). Lignocellulosic fuel has the potential to solve several problems (food competing with fuel) that are currently associated with first-generation biofuels. Moreover, lignocellulosic fuels can supply a larger proportion of the global fuel leading to sustainability at a lower cost, and with greater environmental benefits (Liz Marsall, 2009). The production of ethanol from the complex sugars in leaves and stalks is a promising strategy to radically broaden the range of possible ethanol feedstock.


2021 ◽  
Vol 7 (12) ◽  
pp. 120240-120262
Author(s):  
Damázio Borba Sant’Ana Júnior ◽  
Fábio de Ávila Rodrigues

In this study, the optimization of four processing schemes were developed for the production of 5 hydroxymethylfurfural (HMF), a chemical platform compound obtained from lignocellulosic biomass and used to make the connection with products from fossil resources. Despite its wide applicability, problems associated with its synthesis hindered its greater use. In this scenario the use of a computer program stands out, as the optimization of processes can be used, evaluating the factors and finding parameters that minimize the costs associated with its production. The optimization of these systems was made from the minimization of the total annual cost of the process carried out through the  Aspen Plus® v.11 software, in addition, the economic feasibility of the process was analyzed and it was possible to obtain the HMF at 1.00$ .kg-1 and the co-product levulinic acid between 1.92 and 3.08 $.kg-1. It was also possible to note that among the operating costs, those from glucose had the greatest effect on its value, whereas in relation to equipment costs, reactors and distillation columns were the ones that had the greatest influence.


2013 ◽  
Vol 6 (1) ◽  
pp. 267-287 ◽  
Author(s):  
Richard C. Baliban ◽  
Josephine A. Elia ◽  
Christodoulos A. Floudas

2014 ◽  
Vol 43 (8) ◽  
pp. 1327-1329 ◽  
Author(s):  
Koji Nemoto ◽  
Ken-ichi Tominaga ◽  
Kazuhiko Sato

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