Efficient separation of transition metals from rare earths by an undiluted phosphonium thiocyanate ionic liquid

2016 ◽  
Vol 18 (23) ◽  
pp. 16039-16045 ◽  
Author(s):  
Alok Rout ◽  
Koen Binnemans
Keyword(s):  
Ionic Liquid ◽  
Rare Earth ◽  
Transition Metal ◽  
Transition Metals ◽  
Metal Ions ◽  
Rare Earths ◽  
Transition Metal Ions ◽  
Rare Earth Ions ◽  
Efficient Separation

Efficient separation of transition metal ions from their mixture with rare-earth ions was achieved by extraction with a phosphonium thiocyanate ionic liquid.

Bond-length distributions for ions bonded to oxygen: Metalloids and post-transition metals

2017 ◽  
Author(s):  
Olivier Charles Gagné ◽  
Frank Christopher Hawthorne
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Metal Ions ◽  
Bond Length ◽  
Lone Pair ◽  
Transition Metal Ions ◽  
Oxygen Lone Pair

Bond-length distributions are examined for thirty-three configurations of the metalloid ions and fifty-six configurations of the post-transition-metal ions bonded to oxygen. Lone-pair stereoactivity is discussed.

Bond-length distributions for ions bonded to oxygen: Metalloids and post-transition metals

2017 ◽  
Author(s):  
Olivier Charles Gagné ◽  
Frank Christopher Hawthorne
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Metal Ions ◽  
Bond Length ◽  
Lone Pair ◽  
Transition Metal Ions ◽  
Oxygen Lone Pair

Bond-length distributions are examined for thirty-three configurations of the metalloid ions and fifty-six configurations of the post-transition-metal ions bonded to oxygen. Lone-pair stereoactivity is discussed.

Extraction Behavior of Rare Earths in Ion Liquid Extraction System Using 1-Butyl-3-Methyl-Imidazolium Hexafluorophosphate and Benzoyl Acetone

2011 ◽  
Vol 335-336 ◽  
pp. 1428-1432 ◽  
Author(s):  
Zhong Wei Pan ◽  
Chang Ma ◽  
Ying Wu Zhang ◽  
Yu Xia Huang ◽  
Xing Lin Chen ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Rare Earth ◽  
Rare Earths ◽  
Liquid Extraction ◽  
Rare Earth Ions ◽  
Extraction System ◽  
Tetraacetic Acid ◽  
Extraction Percentage ◽  
Extraction Solvent ◽  
Extraction Behavior

The extraction behavior of five rare earth ions (RE3+) was investigated in ionic liquid (IL) extraction system using 1-butyl-3-methyl-imidazolium hexafluorophosphate ionic liquid ([Bmim]PF6) as extraction solvent and benzoyl acetone (HA) as extractant. The extraction percentage of RE3+ using [Bmim]PF6 was less than 8% without HA. When sufficient HA was included in IL phase, the extraction percentage of RE3+ could be higher than 98%. The extracted species in the RE3+-[Bmim]PF6-HA system was neutral REA3 and the recovery of RE3+ extracted into [Bmim]PF6 can be achieved using the mixture of hydrazine hydrate and ethylenediamine tetraacetic acid (EDTA) as stripping agent. [Bmim]PF6 can be recycled in the experiment.

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