scholarly journals Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5% NaCl

RSC Advances ◽  
2020 ◽  
Vol 10 (19) ◽  
pp. 11426-11434 ◽  
Author(s):  
N. Palaniappan ◽  
I. S. Cole ◽  
A. E. Kuznetsov

Octylamine-functionalized graphene oxide chemisorbed onto a Mg alloy surface by non-bonding electron.

RSC Advances ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 662-670
Author(s):  
Palaniappan Nagarajan ◽  
Ivan S. Cole ◽  
Aleksey Kuznetsov ◽  
Sivakumar Manickam

Terbium functionalized graphene oxide interacted with an Mg2+ surface by the active side of GO.


2017 ◽  
Vol 21 (03) ◽  
pp. 179-188 ◽  
Author(s):  
Xia Li ◽  
Kezhen Li ◽  
Dandan Wang ◽  
Jie Huang ◽  
Chunyong Zhang ◽  
...  

In this paper, graphene oxide (GO) sheets covalently functionalized with (5,10,15,20-tetraphenyl) porphinato manganese(III) (MnTPP) has been successfully synthesized and tested as a photocatalyst for hydrogen evolution from water under UV-vis light irradiation. The obtained sample was systematically characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis, Fourier transform infrared (FTIR), and Raman spectroscopy. The results show that the MnTPP moiety has been successfully grafted on the graphene oxide surface to form MnTPP modified GO (GO-MnTPP). The fluorescence quenching and photocurrent enhancement of GO-MnTPP confirm that the rapid electrons transfer from photoexcited the MnTPP moiety to the GO sheets. The platinized GO-MnTPP exhibits enhanced photocatalytic activity for water reduction to produce hydrogen. Moreover, with the assistance of polyvinyl pyrrolidone (PVP), the photocatalytic activity is further improved because of aggregation prevention of the GO-MnTPP nanocomposite. This study provides a facile method to build porphyrin-graphene-based photocatalysts for solar energy conversion.


RSC Advances ◽  
2019 ◽  
Vol 9 (56) ◽  
pp. 32441-32447 ◽  
Author(s):  
N. Palaniappan ◽  
I. S. Cole ◽  
A. E. Kuznetsov ◽  
Balasubramanian K. ◽  
K. R. Justin Thomas

Leucine functionalized graphene oxide chemisorbed on a 111 surface AZ13 magnesium alloy via edge functional groups.


2015 ◽  
Vol 19 (18) ◽  
pp. 1828-1837 ◽  
Author(s):  
George V. Theodosopoulos ◽  
Panayiotis Bilalis ◽  
Georgios Sakellariou

2017 ◽  
Vol 5 (1) ◽  
pp. 220-228 ◽  
Author(s):  
Jinhui Li ◽  
Guoping Zhang ◽  
Rong Sun ◽  
Ching-Ping Wong

A novel composite of reduced functionalized graphene oxide/polyurethane based on Diels–Alder chemistry was developed which could be healed microwaves with high efficiency and applied in healable flexible electronics.


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