scholarly journals Efficient non-noble Ni–Cu based catalysts for the valorization of palmitic acid through a decarboxylation reaction

2021 ◽  
Author(s):  
Camila P. Ferraz ◽  
Anouchka Kiméné ◽  
Karen Silva Vargas ◽  
Svetlana Heyte ◽  
Claire Durlin ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Synergistic Effect ◽  
Palmitic Acid ◽  
Bimetallic Catalyst ◽  
Reduction Temperature ◽  
Decarboxylation Reaction ◽  
The Stability

The synergistic effect Ni–Cu in the bimetallic catalyst Ni–Cu/C improved the stability and reduction temperature as well as enhanced the catalytic activity for the decarboxylation of palmitic acid.

scholarly journals Influence of the Reduction Temperature and the Nature of the Support on the Performance of Zirconia and Alumina-Supported Pt Catalysts for n-Dodecane Hydroisomerization

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 88
Author(s):  
Diana García-Pérez ◽  
Maria Consuelo Alvarez-Galvan ◽  
Jose M. Campos-Martin ◽  
Jose L. G. Fierro
Keyword(s):  
Catalytic Activity ◽  
Surface Area ◽  
Catalytic Properties ◽  
Catalytic Performance ◽  
Major Influence ◽  
Pt Catalysts ◽  
Reduction Temperature ◽  
Metal Dispersion ◽  
Tungsten Oxides ◽  
Supported Pt Catalysts

Catalysts based on zirconia- and alumina-supported tungsten oxides (15 wt % W) with a small loading of platinum (0.3 wt % Pt) were selected to study the influence of the reduction temperature and the nature of the support on the hydroisomerization of n-dodecane. The reduction temperature has a major influence on metal dispersion, which impacts the catalytic activity. In addition, alumina and zirconia supports show different catalytic properties (mainly acid site strength and surface area), which play an important role in the conversion. The NH3-TPD profiles indicate that the acidity in alumina-based catalysts is clearly higher than that in their zirconia counterparts; this acidity can be attributed to a stronger interaction of the WOx species with alumina. The PtW/Al catalyst was found to exhibit the best catalytic performance for the hydroisomerization of n-dodecane based on its higher acidity, which was ascribed to its larger surface area relative to that of its zirconia counterparts. The selectivity for different hydrocarbons (C7–10, C11 and i-C12) was very similar for all the catalysts studied, with branched C12 hydrocarbons being the main products obtained (~80%). The temperature of 350 °C was clearly the best reduction temperature for all the catalysts studied in a trickled-bed-mode reactor.

Exploring the synergistic effect of B–N doped defective graphdiyne for N2 fixation

2021 ◽  
Vol 45 (14) ◽  
pp. 6327-6335
Author(s):  
Jingeng Cao ◽  
Nan Li ◽  
Xin Zeng
Keyword(s):  
Catalytic Activity ◽  
Synergistic Effect ◽  
N2 Fixation

The synergistic effect of B–N can effectively improve the catalytic activity of graphdiyne.

Effect of the ionizing radiation on the catalytic activity of the BASF K-3-10 catalyst in the low-temperature conversion of carbon monoxide by water vapour. Stability of the radiation catalytic effects

1986 ◽  
Vol 51 (8) ◽  
pp. 1571-1578 ◽  
Author(s):  
Alois Motl
Keyword(s):  
Carbon Monoxide ◽  
Catalytic Activity ◽  
Low Temperature ◽  
Catalytic Effect ◽  
Catalytic Properties ◽  
Beta Radiation ◽  
Fast Neutrons ◽  
Time Interval ◽  
The Stability ◽  
Catalytic Effects

The radiation catalytic properties of the BASF K-3-10 catalyst were studied, namely the dependence of these effects on the time interval between the catalyst irradiation and the reaction itself and also on the length of the catalyst use. The catalytic effects decrease exponentially with the interval between the irradiation and the reaction if the catalyst is kept in the presence of air. The stability of effects induced by various types of radiations increases in the sequence beta radiation - gamma radiation - fast neutrons. The radiation catalytic effect stability in the reaction increases in the same sequence.

A new three-phase heterocrystal catalysts and their superior treatment efficiency for tetracycline

2016 ◽  
Vol 10 (03) ◽  
pp. 1750015
Author(s):  
Feng-Rui Wang ◽  
Hui-Ping Sun ◽  
Yan Wang ◽  
Jin-Ku Liu ◽  
Yi Fang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Band Structure ◽  
Antibiotic Residues ◽  
Treatment Efficiency ◽  
Electron Hole ◽  
Three Phase ◽  
Catalytic Material ◽  
Water Based ◽  
The Stability ◽  
Functional Components

An easy recyclable and interesting Ag3PO4@Pt@TiO2 (APTP) three-phase heterocrystal chains were self-assembled by the cohesive action and chemical construction of polyvinylpyrrolidone (PVP). We found that a new electron–hole transmission path has been built via the rematch of the band structure of Ag3PO4, Pt and TiO2 which extends the light absorption and promoted the electron–hole separation to treat the antibiotic residues in the water. Based on the thorough investigations, a new catalytic material was provided for antibiotics degradation. The catalytic activity of APTP toward the degradation of tetracycline solution was enhanced by 166.67% and the stability increased remarkably compared with pure Ag3PO4 through the integration of different functional components.

scholarly journals Higher Performance of DSSC with Dyes from Cladophora sp. as Mixed Cosensitizer through Synergistic Effect

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Andery Lim ◽  
Noramaliyana Haji Manaf ◽  
Kushan Tennakoon ◽  
R. L. N. Chandrakanthi ◽  
Linda Biaw Leng Lim ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Structural Changes ◽  
Dye Sensitized Solar Cells ◽  
Life Time ◽  
Effect Of Temperature ◽  
Synergistic Activity ◽  
Electron Recombination ◽  
Positive Interaction ◽  
Effective Electron ◽  
The Stability

Chlorophyll and xanthophyll dyes extracted from a single source of filamentous freshwater green algae (Cladophora sp.) were used to sensitize dye sensitized solar cells and their performances were investigated. A more positive interaction is expected as the derived dyes come from a single natural source because they work mutually in nature. Cell sensitized with mixed chlorophyll and xanthophyll showed synergistic activity with improved cell performance of 1.5- to 2-fold higher than that sensitized with any individual dye. The effect of temperature and the stability of these dyes were also investigated. Xanthophyll dye was found to be more stable compared to chlorophyll that is attributed in the ability of xanthophyll to dissipate extra energy via reversible structural changes. Mixing the dyes resulted to an increase in effective electron life time and reduced the process of electron recombination during solar cell operation, hence exhibiting a synergistic effect.

scholarly journals Effect of Pyrolysis Conditions on the Performance of Co–Doped MOF–Derived Carbon Catalysts for Oxygen Reduction Reaction

Catalysts ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1163
Author(s):  
Ning Cui ◽  
Kexiao Bi ◽  
Wei Sun ◽  
Qianqian Wu ◽  
Yinan Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Heating Rate ◽  
Reduction Reaction ◽  
Half Wave ◽  
Step Heating ◽  
The Stability ◽  
Carbon Catalysts ◽  
Co Doped

MOF–derived porous carbon is a type of promising catalyst to replace expensive Pt–based catalysts for oxygen reduction reaction (ORR). The catalytic activity for ORR depends closely on pyrolysis conditions. In this work, a Co–doped ZIF–8 material was chosen as a research object. The effect of pyrolysis conditions (temperature, heating rate, two–step heating) on the ORR performance of ZIF–derived carbon catalysts was systematically studied. The Co–ZIF–8 catalyst carbonized at 900 °C exhibits better ORR catalytic activity than that carbonized at 800 °C and 1000 °C. Moreover, a low heating rate can enhance catalytic activity. Two–step pyrolysis is proven to be an effective way to improve the performance of catalysts. Reducing the heating rate in the low–temperature stage is more beneficial to the ORR performance, compared to the heating rate in the high–temperature stage. The results show that the Co–ZIF–8 catalyst exhibits the best performance when the precursor was heated to 350 °C at 2 °C/min, and then heated to 900 °C at 5 °C/min. The optimum Co–ZIF–8 catalyst shows a half–wave potential of 0.82 V and a current density of 5.2 mA·cm−2 in 0.1 M KOH solution. It also exhibits high content of defects and good graphitization. TEM mapping shows that Co and N atoms are highly dispersed in the polyhedral carbon skeleton. However, two–step pyrolysis has no significant effect on the stability of the catalyst.

Synergistic effect of the Pd–Ni bimetal/carbon nanofiber composite catalyst in Suzuki coupling reaction

2019 ◽  
Vol 6 (3) ◽  
pp. 352-361 ◽  
Author(s):  
Guangyang Bao ◽  
Jie Bai ◽  
Chunping Li
Keyword(s):  
Catalytic Activity ◽  
Synergistic Effect ◽  
Carbon Nanofiber ◽  
Coupling Reaction ◽  
Suzuki Coupling ◽  
Composite Catalyst ◽  
Sustainable Chemistry ◽  
Nanofiber Composite ◽  
Suzuki Coupling Reaction ◽  
Nanocomposite Catalyst

A novel Pd1Ni4 bimetal nanocomposite catalyst was prepared and showed better performance than their monometallic counterpart. What's more, the catalyst could be reused ten times without significant change in catalytic activity, which met the request of sustainable chemistry.

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