The influence of annealing conditions on Ca/P ratio and phase transformations in bulk calcium phosphates

CrystEngComm ◽  
2022 ◽  
Author(s):  
Diana Griesiute ◽  
Eva Raudonyte-Svirbutaviciene ◽  
Aivaras Kareiva ◽  
Aleksej Zarkov
Keyword(s):  
Phase Transformations ◽  
Calcium Phosphates ◽  
Starting Material ◽  
Annealing Conditions

The present study investigates the influence of annealing conditions on phase transformations in calcium phosphates. Synthetic brushite (CaHPO4∙2H2O) with Ca/P ratio 1:1 was taken as a starting material and annealed...

Heat treatment-induced phase transformations of materials in a system of calcium phosphates and magnesium phosphates with (Ca + Mg)/P = 2

2016 ◽  
Vol 52 (11) ◽  
pp. 1121-1125 ◽  
Author(s):  
M. A. Goldberg ◽  
V. V. Smirnov ◽  
O. S. Antonova ◽  
L. I. Shvorneva ◽  
S. V. Smirnov ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Phase Transformations ◽  
Calcium Phosphates ◽  
Magnesium Phosphates

Phase transformations of calcium phosphates formed in wet field environments

2007 ◽  
Vol 42 (19) ◽  
pp. 8357-8362 ◽  
Author(s):  
O. M. Clarkin ◽  
M. R. Towler ◽  
G. M. Insley ◽  
M. E. Murphy
Keyword(s):  
Phase Transformations ◽  
Calcium Phosphates

The use of high-resolution FESEM to study solid-state phase transformations and reactions

1994 ◽  
Vol 52 ◽  
pp. 1028-1029
Author(s):  
P. G. Kotula ◽  
D. D. Erickson ◽  
C. B. Carter
Keyword(s):  
Solid State ◽  
High Resolution ◽  
Phase Transformations ◽  
High Efficiency ◽  
Sol Gel ◽  
Quantitative Information ◽  
Solid State Reactions ◽  
Critical Dimensions ◽  
Backscattered Electrons ◽  
Backscattered Electron

High-resolution field-emission-gun scanning electron microscopy (FESEM) has recently emerged as an extremely powerful method for characterizing the micro- or nanostructure of materials. The development of high efficiency backscattered-electron detectors has increased the resolution attainable with backscattered-electrons to almost that attainable with secondary-electrons. This increased resolution allows backscattered-electron imaging to be utilized to study materials once possible only by TEM. In addition to providing quantitative information, such as critical dimensions, SEM is more statistically representative. That is, the amount of material that can be sampled with SEM for a given measurement is many orders of magnitude greater than that with TEM.In the present work, a Hitachi S-900 FESEM (operating at 5kV) equipped with a high-resolution backscattered electron detector, has been used to study the α-Fe2O3 enhanced or seeded solid-state phase transformations of sol-gel alumina and solid-state reactions in the NiO/α-Al2O3 system. In both cases, a thin-film cross-section approach has been developed to facilitate the investigation. Specifically, the FESEM allows transformed- or reaction-layer thicknesses along interfaces that are millimeters in length to be measured with a resolution of better than 10nm.

The use of transmission and analytical electron microscopy in studying reactions and phase transformations in thin film

1993 ◽  
Vol 51 ◽  
pp. 842-843
Author(s):  
K. Barmak
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Phase Transformations ◽  
Analytical Electron Microscopy ◽  
Ex Situ ◽  
Multilayer Thin Films ◽  
Absolute Concentration ◽  
Analytical Electron ◽  
Deposition Step

Generally, processing of thin films involves several annealing steps in addition to the deposition step. During the annealing steps, diffusion, transformations and reactions take place. In this paper, examples of the use of TEM and AEM for ex situ and in situ studies of reactions and phase transformations in thin films will be presented.The ex situ studies were carried out on Nb/Al multilayer thin films annealed to different stages of reaction. Figure 1 shows a multilayer with dNb = 383 and dAl = 117 nm annealed at 750°C for 4 hours. As can be seen in the micrograph, there are four phases, Nb/Nb3-xAl/Nb2-xAl/NbAl3, present in the film at this stage of the reaction. The composition of each of the four regions marked 1-4 was obtained by EDX analysis. The absolute concentration in each region could not be determined due to the lack of thickness and geometry parameters that were required to make the necessary absorption and fluorescence corrections.

A Transmission Electron Microscopical Investigation of Phase Transformations in TiNi

1980 ◽  
Vol 38 ◽  
pp. 340-341
Author(s):  
P. Moine ◽  
G. M. Michal ◽  
R. Sinclair
Keyword(s):  
Electron Microscopy ◽  
Phase Transformations ◽  
Applied Stress ◽  
Structural Changes ◽  
Microscopical Investigation ◽  
Temperature Range ◽  
Transmission Electron ◽  
Electron Microscopical ◽  
Diffraction Effects ◽  
Microscopy Images

Premartensitic effects in near equiatomic TiNi have been pointed out by several authors(1-5). These include anomalous contrast in electron microscopy images (mottling, striations, etc. ),diffraction effects(diffuse streaks, extra reflections, etc.), a resistivity peak above Ms (temperature at which a perceptible amount of martensite is formed without applied stress). However the structural changes occuring in this temperature range are not well understood. The purpose of this study is to clarify these phenomena.

Phase transformations in Pd-and Ni-rich Ti-Pd-Ni alloys

2003 ◽  
Vol 112 ◽  
pp. 1043-1046 ◽  
Author(s):  
M. Nagasako ◽  
M. Nishida
Keyword(s):  
Phase Transformations ◽  
Ni Alloys
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