scholarly journals Steering the methanol steam reforming reactivity of intermetallic Cu–In compounds by redox activation: stability vs. formation of an intermetallic compound–oxide interface

2021 ◽  
Author(s):  
Kevin Ploner ◽  
Andrew Doran ◽  
Martin Kunz ◽  
Albert Gili ◽  
Aleksander Gurlo ◽  
...  
Keyword(s):  
Intermetallic Compound ◽  
Intermetallic Compounds ◽  
Steam Reforming ◽  
Methanol Steam Reforming ◽  
Oxide Interface ◽  
Oxide Interfaces ◽  
Redox Activation ◽  
Stability Limits

To compare the properties of intermetallic compounds and intermetallic compound–oxide interfaces, Cu–In was used as a model to correlate stability limits, self-activation and redox activation with the inherent methanol steam reforming performance.

Surface and Subsurface Dynamics of the Intermetallic Compound ZnNi in Methanol Steam Reforming

2012 ◽  
Vol 116 (28) ◽  
pp. 14930-14935 ◽  
Author(s):  
Matthias Friedrich ◽  
Detre Teschner ◽  
Axel Knop-Gericke ◽  
Marc Armbrüster
Keyword(s):  
Intermetallic Compound ◽  
Steam Reforming ◽  
Methanol Steam Reforming

scholarly journals A Comparative Discussion of the Catalytic Activity and CO2-Selectivity of Cu-Zr and Pd-Zr (Intermetallic) Compounds in Methanol Steam Reforming

Catalysts ◽  
2017 ◽  
Vol 7 (12) ◽  
pp. 53 ◽  
Author(s):  
Norbert Köpfle ◽  
Lukas Mayr ◽  
Daniela Schmidmair ◽  
Johannes Bernardi ◽  
Axel Knop‐Gericke ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Intermetallic Compounds ◽  
Steam Reforming ◽  
Methanol Steam Reforming ◽  
Co2 Selectivity

scholarly journals The Intermetallic Compound ZnPd and Its Role in Methanol Steam Reforming

2013 ◽  
Vol 55 (3) ◽  
pp. 289-367 ◽  
Author(s):  
M. Armbrüster ◽  
M. Behrens ◽  
K. Föttinger ◽  
M. Friedrich ◽  
É. Gaudry ◽  
...  
Keyword(s):  
Intermetallic Compound ◽  
Steam Reforming ◽  
Methanol Steam Reforming

Application of microemulsion method for development of methanol steam reforming Pd/ZnO catalysts

2016 ◽  
Vol 125 (3) ◽  
pp. 1265-1272 ◽  
Author(s):  
Justyna Pawlonka ◽  
Wojciech Gac ◽  
Magdalena Greluk ◽  
Grzegorz Słowik
Keyword(s):  
Steam Reforming ◽  
Methanol Steam Reforming ◽  
Microemulsion Method

scholarly journals Heat Treatment-Induced Microstructure and Property Evolution of Mg/Al Intermetallic Compound Coatings Prepared by Al Electrodeposition on Mg Alloy from Molten Salt Electrolytes

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1407
Author(s):  
Tianyu Yao ◽  
Kui Wang ◽  
Haiyan Yang ◽  
Haiyan Jiang ◽  
Jie Wei ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Intermetallic Compound ◽  
Intermetallic Compounds ◽  
Mg Alloy ◽  
X Ray Diffraction ◽  
Electron Backscattered Diffraction ◽  
Alloy Matrix ◽  
Comprehensive Properties ◽  
Compound Coatings ◽  
Compound Coating

A method of forming an Mg/Al intermetallic compound coating enriched with Mg17Al12 and Mg2Al3 was developed by heat treatment of electrodeposition Al coatings on Mg alloy at 350 °C. The composition of the Mg/Al intermetallic compounds could be tuned by changing the thickness of the Zn immersion layer. The morphology and composition of the Mg/Al intermetallic compound coatings were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electron backscattered diffraction (EBSD). Nanomechanical properties were investigated via nano-hardness (nHV) and the elastic modulus (EIT), and the corrosion behavior was studied through hydrogen evolution and potentiodynamic (PD) polarization. The compact and uniform Al coating was electrodeposited on the Zn-immersed AZ91D substrate. After heat treatment, Mg2Al3 and Mg17Al12 phases formed, and as the thickness of the Zn layer increased from 0.2 to 1.8 μm, the ratio of Mg2Al3 and Mg17Al12 varied from 1:1 to 4:1. The nano-hardness increased to 2.4 ± 0.5 GPa and further improved to 3.5 ± 0.1 GPa. The Mg/Al intermetallic compound coating exhibited excellent corrosion resistance and had a prominent effect on the protection of the Mg alloy matrix. The control over the ratio of intermetallic compounds by varying the thickness of the Zn immersion layer can be an effective approach to achieve the optimal comprehensive performance. As the Zn immersion time was 4 min, the obtained intermetallic compounds had relatively excellent comprehensive properties.

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