Photothermal CO2 hydrogenation to hydrocarbons over trimetallic Co-Cu-Mn oxide catalyst

2021 ◽  
Author(s):  
Zhen-Hong He ◽  
Zhu-Hui Li ◽  
Zhong-Yu Wang ◽  
Kuan Wang ◽  
Yong-Chang Sun ◽  
...  
Keyword(s):  
Low Temperature ◽  
Oxide Catalyst ◽  
Co2 Reduction ◽  
Thermal Conditions ◽  
Co2 Hydrogenation ◽  
Mn Oxide

Photocatalytic CO2 reduction is a highly vital process for conversing CO2 into valuable chemicals. However, the reaction always proceeds less efficaciously at low temperature. The combination of photo- and thermal-conditions...

CO2 hydrogenation into CH4 over Ni–Fe catalysts

2018 ◽  
Vol 11 (03) ◽  
pp. 1850057 ◽  
Author(s):  
Reza Meshkini Far ◽  
Olena V. Ischenko ◽  
Alla G. Dyachenko ◽  
Oleksandr Bieda ◽  
Snezhana V. Gaidai ◽  
...  
Keyword(s):  
Low Temperature ◽  
Synergistic Effect ◽  
Atmospheric Pressure ◽  
High Efficiency ◽  
Co2 Hydrogenation ◽  
Hydrogenation Catalysts ◽  
Fe Catalysts ◽  
First Time ◽  
Supported Ni ◽  
Hydrogenation Of Co

Here, we report, for the first time, on the catalytic hydrogenation of CO2 to methane at atmospheric pressure. For the preparation of hydrogenation catalysts based on Ni and Fe metals, a convenient method is developed. According to this method, low-temperature reduction of the co-precipitated Ni and Fe oxides with hydrogen gives the effective and selective bimetallic Ni[Formula: see text]Fe[Formula: see text], Ni[Formula: see text]Fe[Formula: see text] and Ni[Formula: see text]Fe[Formula: see text] catalysts. At the temperature range of 300–400[Formula: see text]C, they exhibit a high efficiency of CH4 production with respect to monometallic Ni and Fe catalysts. The results imply a synergistic effect between Ni and Fe which caused the superior activity of the Ni[Formula: see text]Fe[Formula: see text] catalyst conversing [Formula: see text]% of CO2 into CH4 at 350[Formula: see text]C. To adapt the Ni–Fe catalysts in the industry, the effect of two different carriers on the efficiency of the alumina-supported Ni[Formula: see text]Fe[Formula: see text] catalyst was investigated. It is found that the Ni[Formula: see text]Fe[Formula: see text]/[Formula: see text]-Al2O3 catalyst effectively conversed CO2 giving 100% methane yield already at 275[Formula: see text]C.

scholarly journals Pre-Reduction of Au/Iron Oxide Catalyst for Low-Temperature Water-Gas Shift Reaction Below 150 °C

Catalysts ◽  
2011 ◽  
Vol 1 (1) ◽  
pp. 175-190 ◽  
Author(s):  
Shinji Kudo ◽  
Taisuke Maki ◽  
Takashi Fukuda ◽  
Kazuhiro Mae
Keyword(s):  
Iron Oxide ◽  
Low Temperature ◽  
Oxide Catalyst ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Iron Oxide Catalyst ◽  
Shift Reaction ◽  
Water Gas ◽  
Temperature Water

Ceria-supported niobium oxide catalyst for low-temperature oxidation of 1,3-butadiene

2022 ◽  
Vol 518 ◽  
pp. 112083
Author(s):  
Kourosh Razmgar ◽  
Mohammednoor Altarawneh ◽  
Ibukun Oluwoye ◽  
Gamini Senanayake
Keyword(s):  
Low Temperature ◽  
Niobium Oxide ◽  
Oxide Catalyst ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation

scholarly journals Petrological implications for the production of methane and hydrogen in hyperalkaline springs from the Othrys ophiolite, Greece.

2013 ◽  
Vol 47 (1) ◽  
pp. 449
Author(s):  
B. Tsikouras ◽  
G. Etiope ◽  
E. Ifandi ◽  
S. Kordella ◽  
G. Papatheodorou ◽  
...  
Keyword(s):  
Low Temperature ◽  
Co2 Hydrogenation ◽  
Ultramafic Rocks ◽  
Mafic Rocks ◽  
Silica Activity ◽  
High Silica ◽  
Greenhouse Gas Budget ◽  
The Origin Of Life ◽  
Life On Earth ◽  
Shed Light

Altered mafic and ultramafic rocks were studied in correspondence with hyperalkaline, CH4-bearing and very low-hydrogen spring waters in the Othrys ophiolite, whose chemical features are typical of present day serpentinisation. The H2 paucity is interpreted as the result of the incorporation of high-silica, aqueous fluids, probably derived from mafic rocks. The vein assemblage of serpentine + magnetite is related to circulation of low-silica fluids whereas serpentine + talc, tremolite after garnet and Fe-rich serpentine in the interior of serpentine veins reflect a late circulation of low-temperature (likely below 120 °C), high silica activity fluids. The highsilica conditions might have limited or interrupted the production of H2, which was subsequently consumed by CO2 hydrogenation to produce CH4. The lack of H2 could also be due to peridotite alteration by CO2-rich fluids. This would imply that the Othrys peridotites, among similar methane-bearing peridotites, may be considered as terrestrial analogues of Martian ultramafic rocks, which are thought to contribute to methane emission in the atmosphere of Mars. Understanding the mechanism of methane abiotic production will likely shed light to the details of some crucial aspects as the greenhouse-gas budget, the production of hydrocarbons and the origin of life on Earth.

scholarly journals Precipitation of Mn Oxides in Quaternary Microbially Induced Sedimentary Structures (MISS), Cape Vani Paleo-Hydrothermal Vent Field, Milos, Greece

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 536
Author(s):  
Stephanos P. Kilias ◽  
Magnus Ivarsson ◽  
Ernest Chi Chi Fru ◽  
Jayne E. Rattray ◽  
Håkan Gustafsson ◽  
...  
Keyword(s):  
Low Temperature ◽  
Hydrothermal Vent ◽  
Microbial Mats ◽  
Paramagnetic Resonance ◽  
Sedimentary Structures ◽  
Mn Oxide ◽  
Bedding Planes ◽  
Transmission Electron ◽  
Aerobic Methanotrophs ◽  
Hydrothermal Vent Field

Understanding microbial mediation in sediment-hosted Mn deposition has gained importance in low-temperature ore genesis research. Here we report Mn oxide ores dominated by todorokite, vernadite, hollandite, and manjiroite, which cement Quaternary microbially induced sedimentary structures (MISS) developed along bedding planes of shallow-marine to tidal-flat volcaniclastic sandstones/sandy tuffs, Cape Vani paleo-hydrothermal vent field, Milos, Greece. This work aims to decipher the link between biological Mn oxide formation, low-T hydrothermalism, and, growth and preservation of Mn-bearing MISS (MnMISS). Geobiological processes, identified by microtexture petrography, scanning and transmission electron microscopy, lipid biomarkers, bulk- and lipid-specific δ13Corganic composition, and field data, and, low-temperature hydrothermal venting of aqueous Mn2+ in sunlit shallow waters, cooperatively enabled microbially-mediated Mn (II) oxidation and biomineralization. The MnMISS biomarker content and δ13Corg signatures strongly resemble those of modern Mn-rich hydrothermal sediments, Milos coast. Biogenic and syngenetic Mn oxide precipitation established by electron paramagnetic resonance (EPR) spectroscopy and petrography, combined with hydrothermal fluid flow-induced pre-burial curing/diagenesis, may account for today’s crystalline Mn oxide resource. Our data suggests that MISS are not unique to cyanobacteria mats. Furthermore, microbial mats inhabited by aerobic methanotrophs may have contributed significantly to the formation of the MnMISS, thus widening the spectrum of environments responsible for marine Mn biometallogenesis.

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