Rhodium(III)-Catalyzed Cascade C−H Functionalization/Annulation of Sulfoximines with Iodonium Ylides for the Synthesis of Cyclohexanone-1,2-benzothiazines

Author(s):  
Lu Chen ◽  
Zhichao Wang ◽  
Yangyang Wang ◽  
Liqiang Hao ◽  
Xiaobo Xu ◽  
...  

A highly efficient Rh(III)-catalyzed cascade C−H activation/annulation of sulfoximines with iodonium ylides under metal-oxidant-free conditions has been reported. The fused cyclohexanone-1,2-benzothiazine scaffold is readily achieved with a one-pot process in...

2013 ◽  
Vol 10 (10) ◽  
pp. 764-769 ◽  
Author(s):  
Akbar Mobinikhaledi ◽  
Alireza Amiri

2018 ◽  
Vol 5 (2) ◽  
pp. 122-128 ◽  
Author(s):  
Srinivas L. Nakkalwar ◽  
Shivaji B. Patwari ◽  
Mohasim M. Patel ◽  
Vivekanand B. Jadhav

2021 ◽  
Vol 76 (2) ◽  
pp. 85-90
Author(s):  
Abdolkarim Zare ◽  
Manije Dianat

Abstract A highly efficient and green protocol for the synthesis of pyrimido[4,5-b]quinolines has been described. The one-pot multicomponent reaction of dimedone with arylaldehydes and 6-amino-1,3-dimethyluracil in the presence of N,N-diethyl-N-sulfoethanaminium chloride ([Et3N–SO3H][Cl]) as an ionic liquid (IL) catalyst under solvent-free conditions afforded the mentioned compounds in high yields and short reaction times. Our protocol is superior to many of the reported protocols in terms of two or more of these factors: the reaction times, yields, conditions (solvent-free versus usage of organic solvents), temperature and catalyst amount.


2015 ◽  
Vol 12 (9) ◽  
pp. 1603-1612 ◽  
Author(s):  
Mohammad Navid Soltani Rad ◽  
Somayeh Behrouz ◽  
Elham Zarenezhad ◽  
Narjes Kaviani

2010 ◽  
Vol 60 (3) ◽  
pp. 517-528 ◽  
Author(s):  
Marcio R Loos ◽  
Volker Abetz ◽  
Karl Schulte

2014 ◽  
Vol 50 (50) ◽  
pp. 6574-6577 ◽  
Author(s):  
Sam E. R. Auty ◽  
Oliver Andrén ◽  
Michael Malkoch ◽  
Steven P. Rannard

We present the first xanthate surface functional dendrimers which undergo rapid one-pot deprotection to thiols and subsequent acrylate Michael addition .


RSC Advances ◽  
2015 ◽  
Vol 5 (61) ◽  
pp. 49295-49300 ◽  
Author(s):  
Handan Pamuk ◽  
Burak Aday ◽  
Fatih Şen ◽  
Muharrem Kaya

Pt NPs@GO has been used for the first time for synthesizing acridinedione from dimedone, aromatic aldehydes and various amines as a catalyst.


ChemInform ◽  
2016 ◽  
Vol 47 (24) ◽  
Author(s):  
Anatoly N. Vereshchagin ◽  
Michail N. Elinson ◽  
Alexander D. Korshunov ◽  
Mikhail P. Egorov

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