Magnetic assembly and manipulation of Janus photonic crystal supraparticles from a colloidal mixture of spheres and ellipsoids

Author(s):  
Mengqi Xiao ◽  
Jingjing Liu ◽  
Zhijie Chen ◽  
Wenxuan Liu ◽  
Chengcheng Zhang ◽  
...  

Photonic crystal supraparticles (PCSs) obtained by self-assembly of colloidal building blocks hold promise for applications in various areas. The majority of PCSs are based on isotropic colloidal spheres, fundamentally limiting...

2008 ◽  
Vol 47-50 ◽  
pp. 1323-1326 ◽  
Author(s):  
Xiang Wei Zhao ◽  
Hua Xu ◽  
Zhong Ze Gu

Photonic crystals have wide applications not only in optoelectronic fields but also in bioassays. In this review, we summarized our work on colloidal photonic crystals as novel biomolecular supports in multiplex bioassays. Except for enhancing the fluorescence signal and encoding the biomolecular carriers in fluorphore labeled bioassays, photonic crystal can also encode suspended arrays. From the point view of practicality, the synthesis and self-assembly of monodispersed colloidal spheres for colloidal crystals is involved.


2012 ◽  
Vol 9 (1) ◽  
pp. 43 ◽  
Author(s):  
Hueyling Tan

Molecular self-assembly is ubiquitous in nature and has emerged as a new approach to produce new materials in chemistry, engineering, nanotechnology, polymer science and materials. Molecular self-assembly has been attracting increasing interest from the scientific community in recent years due to its importance in understanding biology and a variety of diseases at the molecular level. In the last few years, considerable advances have been made in the use ofpeptides as building blocks to produce biological materials for wide range of applications, including fabricating novel supra-molecular structures and scaffolding for tissue repair. The study ofbiological self-assembly systems represents a significant advancement in molecular engineering and is a rapidly growing scientific and engineering field that crosses the boundaries ofexisting disciplines. Many self-assembling systems are rangefrom bi- andtri-block copolymers to DNA structures as well as simple and complex proteins andpeptides. The ultimate goal is to harness molecular self-assembly such that design andcontrol ofbottom-up processes is achieved thereby enabling exploitation of structures developed at the meso- and macro-scopic scale for the purposes oflife and non-life science applications. Such aspirations can be achievedthrough understanding thefundamental principles behind the selforganisation and self-synthesis processes exhibited by biological systems.


2018 ◽  
Author(s):  
Erik Leonhardt ◽  
Jeff M. Van Raden ◽  
David Miller ◽  
Lev N. Zakharov ◽  
Benjamin Aleman ◽  
...  

Extended carbon nanostructures, such as carbon nanotubes (CNTs), exhibit remarkable properties but are difficult to synthesize uniformly. Herein, we present a new class of carbon nanomaterials constructed via the bottom-up self-assembly of cylindrical, atomically-precise small molecules. Guided by supramolecular design principles and circle packing theory, we have designed and synthesized a fluorinated nanohoop that, in the solid-state, self-assembles into nanotube-like arrays with channel diameters of precisely 1.63 nm. A mild solution-casting technique is then used to construct vertical “forests” of these arrays on a highly-ordered pyrolytic graphite (HOPG) surface through epitaxial growth. Furthermore, we show that a basic property of nanohoops, fluorescence, is readily transferred to the bulk phase, implying that the properties of these materials can be directly altered via precise functionalization of their nanohoop building blocks. The strategy presented is expected to have broader applications in the development of new graphitic nanomaterials with π-rich cavities reminiscent of CNTs.


2017 ◽  
Author(s):  
Niamh Mac Fhionnlaoich ◽  
Stephen Schrettl ◽  
Nicholas B. Tito ◽  
Ye Yang ◽  
Malavika Nair ◽  
...  

The arrangement of nanoscale building blocks into patterns with microscale periodicity is challenging to achieve via self-assembly processes. Here, we report on the phase transition-driven collective assembly of gold nanoparticles in a thermotropic liquid crystal. A temperature-induced transition from the isotropic to the nematic phase leads to the assembly of individual nanometre-sized particles into arrays of micrometre-sized aggregates, whose size and characteristic spacing can be tuned by varying the cooling rate. This fully reversible process offers hierarchical control over structural order on the molecular, nanoscopic, and microscopic level and is an interesting model system for the programmable patterning of nanocomposites with access to micrometre-sized periodicities.


2021 ◽  
Author(s):  
Alexander Banger ◽  
Julian Sindram ◽  
Marius Otten ◽  
Jessica Kania ◽  
Alexander Strzelczyk ◽  
...  

We present the synthesis of so called amphiphilic glycomacromolecules (APGs) by using solid-phase polymer synthesis. Based on tailor made building blocks, monosdisperse APGs with varying compositions are synthesized, introducing carbohydrate...


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Hamed Azhdari ◽  
Sahel Javahernia

Abstract Increasing the speed of operation in all optical signal processing is very important. For reaching this goal one needs high speed optical devices. Optical half adders are one of the important building blocks required in optical processing. In this paper an optical half adder was proposed by combining nonlinear photonic crystal ring resonators with optical waveguides. Finite difference time domain method wase used for simulating the final structure. The simulation results confirmed that the rise time for the proposed structure is about 1 ps.


2006 ◽  
pp. 4847-4849 ◽  
Author(s):  
Bulusu Jagannadh ◽  
Marepally Srinivasa Reddy ◽  
Chennamaneni Lohitha Rao ◽  
Anabathula Prabhakar ◽  
Bharatam Jagadeesh ◽  
...  

2019 ◽  
Vol 14 (1) ◽  
Author(s):  
Bingfang Zou ◽  
Chunyu Niu ◽  
Ming Ma ◽  
Lu Zhao ◽  
Yongqiang Wang

AbstractThe fabrication of a uniform array film through assembly of colloidal building blocks is of practical interest for the integrated individual and collective functions. Here, a magnetic assembly route was put forward to organize monodisperse noble metal microspheres into a uniform array film for surface-enhanced Raman scattering (SERS) application, which demonstrated the integrated signal sensitivity of single noble metal microspheres and reproducibility of their assembled uniform array film. For this purpose, monodisperse multifunctional Fe3O4@SiO2@TiO2@Ag (FOSTA) colloidal microspheres as building blocks were successfully synthesized through a homemade ultrasonic-assisted reaction system. When used in SERS test, these multifunctional microspheres could firstly bind the analyte (R6G) from solution and then assembled into a uniform film under an external magnetic field, which exhibited high SERS detection sensitivity with good reproducibility. In addition, due to the TiO2 interlayer in FOSTA colloidal microspheres, the building blocks could be recycled and self cleaned through photocatalytic degradation of the adsorbed analyte for recycling SERS application.


Soft Matter ◽  
2021 ◽  
Author(s):  
Jiawei Lu ◽  
Xiangyu Bu ◽  
Xinghua Zhang ◽  
Bing Liu

The shapes of colloidal particles are crucial to the self-assembled superstructures. Understanding the relationship between the shapes of building blocks and the resulting crystal structures is an important fundamental question....


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Hassan Mamnoon-Sofiani ◽  
Sahel Javahernia

Abstract All optical logic gates are building blocks for all optical data processors. One way of designing optical logic gates is using threshold switching which can be realized by combining an optical resonator with nonlinear Kerr effect. In this paper we showed that a novel structure consisting of nonlinear photonic crystal ring resonator which can be used for realizing optical NAND/NOR and majority gates. The delay time of the proposed NAND/NOR and majority gates are 2.5 ps and 1.5 ps respectively. Finite difference time domain and plane wave expansion methods were used for simulating the proposed optical logic gates. The total footprint of the proposed structure is about 988 μm2.


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