Molecular ordering and current-voltage characteristics of vacuum-deposited
m-MTDATA(4,4’,4’’-tris[N,-(3-methylphenyl)-N-phenylamino]triphenylamine), widely used as a
hole injection material in OLEDs, thin films were investigated. Molecular ordering was induced by
thermal annealing under electromagnetic field after deposition of m-MTDATA onto the pre-patterned
ITO glass. AFM and XRD analysis were employed to characterize the topology and molecular
ordering of m-MTDATA thin films. The XRD and AFM results show that m-MTDATA can be
molecularly ordered by means of thermal annealing under electromagnetic field. Thermal annealing at
100°C was desirable to get a high degree of molecular ordering with dendritic grains. It was shown
that molecular ordering as well as larger dendritic grains in the thin films influenced on improving the
current-voltage characteristics and increasing the leakage current of the ITO/m-MTDATA/Al device.
Electromagnetic field improved the surface roughness, as well. It is regarded that Rpv seems more
significant than the other roughness parameters. Significantly lower Rpv(peak-to-valley roughness)
obtained by both thermal annealing and electromagnetic field resulted in enhancing the stability of the
current ITO/m-MTDATA/Al device. Ra(average roughness) and Rrms(root-mean-square roughness),
however, did not significantly relate with leakage current.