Total Petroleum Hydrocarbon Criteria Working Group: A Risk-Based Approach for the Management of Total Petroleum Hydrocarbons In Soil

1998 ◽  
Vol 7 (1) ◽  
pp. 1-15 ◽  
Author(s):  
Wade H. Weisman
Author(s):  
Williams, Janet Olufunmilayo ◽  
Aleruchi Owhonka

This study investigated the potential of Aspergillus sydowii and Fusarium lichenicola as mixed cultures in the biodegradation of Total Petroleum Hydrocarbons TPHs in oilfield wastewater. Oilfield wastewater was collected from an onshore oil producing platform and biodegradation of total petroleum hydrocarbons was investigated using standard methods. Fungi were isolated from oilfield wastewater contaminated soils obtained from the vicinity of the oil producing platform. Experimental control set-up and treatment with mixed culture of fungal isolates were periodically analyzed on days 7 and 21 intervals for total petroleum hydrocarbon degradation using Gas Chromatography (GC). The total amount of TPHs on day 1 recorded 381. 871 mg/l.  The amount of TPHs on days 7 and 21 in the mixed culture of fungi was 108.975 mg/l and 21.105 mg/l respectively while TPHs in control was 342.891 mg/l and 240.749 mg/l respectively. There was a significant difference between the mixed culture and the control on days 7 and 21 at p≤0.05. The results therefore revealed actual and significant reduction of TPHs in the mixed culture. In addition, there was clearance of n-alkanes by the mixed culture. This suggests that fungi have great potentials in biodegradation of TPHs and in remediation of TPH contaminated environments.


2018 ◽  
Vol 3 (2) ◽  
pp. 173
Author(s):  
Deny Yogaswara ◽  
Khozanah Khozanah

Sumba Sea is an Indo-Australian tectonic plate transition zone that has a huge biodiversities resources and also behalf of an international shipping lane zone from southern of Indonesia to Australia and New Zealand, and as the return. In addition, Sumba Sea is also a kind of outer boundary of Indonesia, that is necessary to do basic environmental monitoring as the authorities in the management of outer sea zone. Indonesia does not have representative environmental quality database including the pollution of Total Petroleum Hydrocarbons (TPH). This study purposes to determine the partial distribution and concentration of TPH in sediments in Sumba Sea, East Nusa Tenggara. The research was conducted in August 2016 using Research Vessel of Baruna Jaya VIII. Samples were collected using a box core, preserved in amber glass jar bottle and stored at 4°C for further analysis in the laboratory. In the laboratory, sediment samples were extracted using dichloromethane and n-hexane for three times extraction. Furthermore, samples were evaporated before added by tetrachloroethylene solvent. Samples were measured with Fourier Transform Infra Red (FTIR) at wavelength 2850-2950 cm<sup>-1</sup>. The results showed that the pollution of Total Petroleum Hydrocarbon (TPH) in the Sumba Sea was detected at all sampling station based on identified of hydrocarbon functional groups. The partial distribution of TPH is evenly distributed and covered all stations on low concentrations. The highest concentration of TPH was detected at station 10 as 4.348 ppm


2008 ◽  
Vol 33 (1) ◽  
pp. 35-42 ◽  
Author(s):  
A. R. Nascimento ◽  
R.L. Ziolli ◽  
J.T. Ararun, Jr ◽  
C.S. Pires ◽  
T.B. Silva

No presente trabalho os parâmetros de desempenho (validação intralaboratorial) da metodologia de determinação de TPH (Total Petroleum Hydrocarbons) foram determinados por detecção na região do infravermelho com o equipamento da Infracal TOG/TPH, visando aplicação em amostras de areia contaminadas com petróleo. Os ensaios foram realizados utilizando Óleo Marine Fuel 380, com densidade igual 0,987 g cm-3 e viscosidade de 5313 cP a 20°C. Este óleo foi fornecido pelo Centro de Pesquisa da Petrobrás (CENPES/PETROBRÁS/RJ), sendo o mesmo óleo derramado no acidente ocorrido em janeiro de 2000, na Baia de Guanabara, RJ, quando 1.300 m3 vazaram do duto que interliga a REDUC (Refinaria Duque de Caxias, RJ) ao terminal da Ilha d’Água/RJ, atingindo praias. Os resultados da validação indicaram que o desempenho da metodologia foi favorável à aplicação que se destina. Entre os parâmetros metrológicos obtidos neste trabalho, o limite de detecção do método foi de 4,06 mg L-1, consideravelmente inferior à faixa de concentração normalmente obtida para amostras em tais situações.


2018 ◽  
Vol 2 (2) ◽  
pp. 35
Author(s):  
Prasetyo Handrianto

Exploitation and exploration activities will produce sewage sludge and crude oil spills that cause pollution to the environment and upgrading to the environment, biology and soil chemistry. Monitoring of oil pollution conditions on the soil can be done by detection of all hydrocarbon components, or what is called the total petroleum hydrocarbon (TPH). According to its components, this total petroleum hydrocarbon (TPH) can be classified into 3 points, aliphatic, alicyclic, and aromatic. One of the biological efforts that can be used to overcome petroleum pollution is by using bioremediation technology. There are several methods in bioremediation, one of which is the biostimulation method, where the growth of the original hydrocarbon decomposers is stimulated by adding nutrients, oxygen, pH optimization and temperature. Hydrocarbonoclastic microorganisms have characteristic not possessed by other microorganisms, namely their ability to excrete hydroxylase enzymes, which are hydrocarbon oxidizing enzymes, so that these bacteria can degrade petroleum hydrocarbons. Biodegradation can be formed if there is a structural transformation so that cahnges in molecular integrity occur. This process is a series of enzymatic or biochemical reaction that require ideal environmental conditions with the growth and proliferation of microorganisms. Something that need to be known before remediation are pollutants (organic or inorganic), degraded/ not, dangerous/ not, how many pollutants pollute the soil, the ratio of carbon (C), Nitrogen (N), and phophorus (P), soil type, soil conditions (wet dry), and how long pollutants have been deposited in these locations


2009 ◽  
Vol 89 (1) ◽  
pp. 21-29 ◽  
Author(s):  
Ravanbakhsh Shirdam ◽  
Ali Daryabeigi Zand ◽  
Gholamreza Nabi Bidhendi ◽  
Nasser Mehrdadi

To date, many developing countries such as Iran have almost completely abandoned the idea of decontaminating oil-polluted soils due to the high costs of conventional (physical/chemical) soil remediation methods. Phytoremediation is an emerging green technology that can become a promising solution to the problem of decontaminating hydrocarbon-polluted soils. Screening the capacity of native tolerant plant species to grow on aged, petroleum hydrocarbon-contaminated soils is a key factor for successful phytoremediation. This study investigated the effect of hydrocarbon pollution with an initial concentration of 40 000 ppm on growth characteristics of sorghum (Sorghum bicolor) and common flax (Linum usitatissumum). At the end of the experiment, soil samples in which plant species had grown well were analyzed for total petroleum hydrocarbons (TPHs) removal by GC-FID. Common flax was used for the first time in the history of phytoremediation of oil-contaminated soil. Both species showed promising remediation efficiency in highly contaminated soil; however, petroleum hydrocarbon contamination reduced the growth of the surveyed plants significantly. Sorghum and common flax reduced TPHs concentration by 9500 and 18500 mg kg‑1, respectively, compared with the control treatment.


2009 ◽  
Vol 7 (1) ◽  
pp. 83-89 ◽  
Author(s):  
Issac Ololade ◽  
Labunmi Lajide ◽  
Isiaka Amoo

AbstractSeasonal changes in petroleum hydrocarbons in water and streambed sediment from selected oil-related areas of Ondo State, Nigeria have been examined using gravimetric and infrared methods. The highest and lowest total petroleum hydrocarbon concentrations (TPH) in water (sediments in brackets) gravimetrically were 3.49 mg L−1 (199.3) mg kg−1 and 0.003 mg L−1 (81.0) mg kg−1 while the concentrations found by IR were 24.0 mg L−1 (135.0 mg kg−1) and 14.0 mg L−1 (33.0 mg kg−1) respectively. The two seasons were positively correlated (α = 0.01) by both methods. The TPH level was well correlated with the sediment organic carbon (OC) during both seasons. The characteristic carbonyl (C=O) vibrations at 1650 cm−1 and 1700 cm−1 indicate oxidation of the oil residue. The study recommends further investigation into the type of organics present to evaluate their toxicity and appropriate remediation.


Author(s):  
Mariana MARINESCU ◽  
M. DUMITRU ◽  
Anca LĂCĂTUŞU ◽  
Gabriela MIHALACHE

Crude oil bioremediation of soils is limited by the bacteria activity in degrading the spills hydrocarbons. The aim of this study is to enhance the bioremediation of soils polluted with crude oil by adding the natural biodegradable product and bacterial inoculum. Biodegradation was quantified by total petroleum hydrocarbons (TPH) analyses. Petroleum hydrocarbon pollution is one of the main environmental problems, not only by the important amounts released but also because of their toxicity. The main objective of this work is to accelerate the biodegradation processes. The enhancement of petroleum hydrocarbons degradation was achieved under natural product treatment and bacterial inoculum. The bacterial inoculum was used to enrich indigenous microbes to enhance biodegradation rate in the green house experiment.


2019 ◽  
Vol 26 (1) ◽  
pp. 14-23 ◽  
Author(s):  
Nisreen Mazin Makkiya ◽  
Israa Abdul wahab Al-baldawi

Due to the deliberate disposal of industrial waste, a great amount of petroleum hydrocarbons pollute the soil and aquatic environments. Bioremediation that depends on the microorganisms in the removal of pollutants is more efficient and cost-effective technology. In this study, five rhizobacteria were isolated from Phragmites australis roots and exposed to real wastewater from Al-Daura refinery with 70 mg/L total petroleum hydrocarbons (TPH) concentration. The five selected rhizobacteria were examined in a biodegradation test for seven days to remove TPH. The results showed that 80% TPH degradation as the maximum value by Sphingomonas Paucimobilis as identified with Vitek® 2 Compact (France).


2021 ◽  
Vol 888 ◽  
pp. 119-128
Author(s):  
Khalid Sayed ◽  
Lavania Baloo ◽  
Shamsudeen Temitope Yekeen ◽  
Mubarak Usman Kankia ◽  
Ahmad Hussaini Jagaba

The study aims to determine Total Petroleum Hydrocarbon (TPH) status in seawater from Teluk Batik beach seawater. In July 2018, fishing vessel sunk two nautical miles off Pematang Damar Laut, a coastal village within the town of George Town, Penang Malaysia, which also impacted the coastline of Perak State. Approximately six tons of diesel and hundreds of liters of fuel oil drifted from the Penang sea to the Perak coast. On further subsequent wave action the TPH concentrations in seawater fluctuated over time. In the coastal water of Teluk Batik Beach, Perak, Malaysia, grab samples were taken from surface seawater for determining the TPH concentrations in November and December 2019. The TPH in seawater was determined by the extractable solvent (Hexane) and the additional petroleum hydrocarbons by the Infrared (IR) method. The values of TPH ranged from 91 to 503 mg/L. Compared to the standards in Malaysian waters, the TPH levels found in this study were high, indicating serious pollution of TPH in the area under study.


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