Composition of the gas-plasma phase in the radioactive graphite - water vapor system
Abstract In this work, the composition and thermophysical properties of the “Reactor graphite-H2O” system at temperatures from 2123 to 3223 K are calculated. It was found that the main components of the vapor phase at a temperature of 2123-2923 K: carbon dioxide, carbon monoxide, water vapor, hydroxide, hydrogen, atomic hydrogen. At temperatures above 3223 K, oxygen and atomic oxygen are added to the gases present. The balances of uranium and plutonium are considered. Uranium at temperatures above 2123 K is present in the system in the form of gaseous and ionized uranium dioxide and trioxide. Plutonium at temperatures above 2123 K is present in the system in the form of gaseous and ionized plutonium oxide, gaseous plutonium dioxide. The calculation of thermophysical properties for the considered system is carried out.