scholarly journals Calculated Phase Relations in the System NCKFMASH (Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O) for High-Pressure Metapelites

2005 ◽  
Vol 47 (2) ◽  
pp. 385-408 ◽  
Author(s):  
CHUNJING WEI ◽  
ROGER POWELL
Keyword(s):  
High Pressure ◽  
Phase Relations ◽  
Calculated Phase

High Pressure Phase Relations for KDP-Type Compounds

1979 ◽  
pp. 261-265
Author(s):  
E. Rapoport ◽  
J. B. Clark ◽  
P. W. Richter
Keyword(s):  
High Pressure ◽  
Phase Relations ◽  
High Pressure Phase ◽  
Pressure Phase

Phase relations of camphene at high pressure up to 9.5 GPa

1998 ◽  
Vol 109 (2) ◽  
pp. 670-675 ◽  
Author(s):  
Kaichi Suito ◽  
Akihiro Ohta ◽  
Noriko Sakurai ◽  
Akifumi Onodera ◽  
Muneyuki Motoyama ◽  
...  
Keyword(s):  
High Pressure ◽  
Phase Relations

Phase relations of iron–silicon alloys at high pressure and high temperature

2009 ◽  
Vol 36 (9) ◽  
pp. 511-518 ◽  
Author(s):  
Yasuhiro Kuwayama ◽  
Toshimitsu Sawai ◽  
Kei Hirose ◽  
Nagayoshi Sata ◽  
Yasuo Ohishi
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Phase Relations ◽  
Silicon Alloys ◽  
Iron Silicon

Origin of corundum within anorthite megacrysts from anorthositic amphibolites, Granulite Terrane, Southern India

2020 ◽  
Vol 105 (8) ◽  
pp. 1161-1174
Author(s):  
Shreya Karmakar ◽  
Subham Mukherjee ◽  
Upama Dutta
Keyword(s):  
High Pressure ◽  
Grain Boundaries ◽  
Chemical Potential ◽  
Regional Metamorphism ◽  
Phase Relations ◽  
Southern India ◽  
Triple Junctions ◽  
Medium Temperature ◽  
Hp Metamorphism ◽  
Basic Rocks

Abstract Growth of corundum in metamorphosed anorthosites and related basic-ultra-basic rocks is an exceptional feature, and its origin remains elusive. We describe the occurrence of and offer an explanation for the genesis of corundum in anorthositic amphibolites from ~2.5 Ga old basement of the Granulite Terrane of Southern India (GTSI). The studied amphibolites from two localities, Manavadi (MvAm) and Ayyarmalai (AyAm), contain anorthite lenses (An90–99) with euhedral to elliptical outline set in a finer-grained matrix of calcic plagioclase (An85–90) and aluminous amphibole (pargasite-magnesiohastingsite). The lenses, interpreted as primary magmatic megacrysts, and the matrix are both recrystallized under static condition presumably during the regional high pressure (HP) metamorphism (~800 °C, 8–11 kbar) at ~2.45 Ga. Corundum occurs in the core of some of the recrystallized anorthite lenses (An95–99) in two modes: (1) Dominantly, it forms aggregates with magnetite (with rare inclusion of hercynite; in MvAm) or spinel (and occasionally hematite-ilmenite; in AyAm). The aggregates cut across the polygonal grain boundaries of the anorthite and contain inclusions of anorthite. (2) Corundum also occurs along the grain boundaries or at the triple junctions of the polygonal anorthite grains, where it forms euhedral tabular grains, sieved with inclusions of anorthite or forms skeletal rims around the recrystallized anorthite, such that it seems to be intergrown with anorthite. Combined petrological data and computed phase relations are consistent with growth of corundum in an open system during regional metamorphism in the presence of intergranular fluids. Two mechanisms are proposed to explain the formation of the corundum in the amphibolites: (1) corundum + magnetite/spinel aggregates formed dominantly by oxy-exsolution of pre-existing Al-Fe-Mg-(Ti)-spinel. This pre-existing spinel may be primary magmatic inclusions within the anorthite phenocrysts or could have formed due to reaction of primary magmatic inclusions of olivine with the host anorthite. Pseudosections of fO2-nH2O-T-P in the CaO–FeO–MgO–Al2O3–SiO2–H2O (CFMASH) system indicate that fO2 and H2O strongly influence the formation of corundum + amphibole from the initial magmatic assemblage of anorthite (phenocrysts) + spinel ± olivine (inclusions). (2) The corundum with anorthite presumably formed through desilification and decalcification of anorthite, as is indicated by computed phase relations in isobaric-isothermal chemical potential diagrams (µSiO2-µCaO) in parts of the CASH system. Growth of corundum in this mode is augmented by high activity of anorthite in plagioclase, high pressure, and low-to-medium temperature of metamorphism. This study thus presents a new viable mechanism for the origin of corundum in anorthositic amphibolites, and basic-ultra-basic rocks in general, which should provide new insight into lower crustal processes like high-pressure metamorphism.

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