scholarly journals Aμo'pϕωτa No. 1. On a case of superficial colour presented by a homogeneous liquid internally colourless

The author observed that a solution of sulphate of quinine in tartaric acid, largely diluted, although perfectly transparent and colourless when held between the eye and the light, or a white object, yet exhibits in certain aspects, and under certain incidences of the light, an extremely vivid and beautiful celestial blue colour, apparently resulting from the action of the strata which the light first penetrates on entering the liquid ; and which, if not strictly superficial, at least exert their peculiar power of analysing the incident rays, and dispersing those producing the observed tint, only through a very small depth within the medium. The thinnest film of the liquid seems quite as effective in producing this superficial colour as a considerable thickness.

The author inquires whether the peculiar coloured dispersion of white light intromitted into a solution of sulphate of quinine, is the result of an analysis of the incident light into two distinct species, or merely of a simple subdivision analogous to that which takes place in partial reflexion, as exemplified in the colours of thin plates. He endeavours to ascertain the laws which regulate this singular mode of dispersion, which for brevity he terms epipolic , on account of the proximity of the seat of dispersion to the intromitting surface of the fluid. It might have been expected that by passing the same incident beam successively through many such dispersive surfaces, the whole of the blue rays would at length be separated from it, and an orange, or red residual beam be left: but the author establishes, by numerous experiments, the general fact, that an epipolical beam of light , meaning thereby a beam which has been once transmitted through a quiniferous solution, and undergone its dispersing action, is incapable of farther undergoing epipolic dispersion. There were only two liquids, out of all those examined by the author, namely oil of turpentine and pyroxylic spirit, which, when interposed in the incident beam, act like the solutions of quinine in preventing the formation of the blue film: and the only solid in which the author discovered a similar power of epipolic dispersion, is the green fluor of Alston Moor, and which by this action exhibits at its surface a fine deep blue colour.


2008 ◽  
Vol 1 (1) ◽  
pp. 43-54
Author(s):  
Basra Sultana ◽  
Mamun-ur-Rashid Khandker

Vertically stacked optical banyan (VSOB) networks are attractive for serving as optical switching systems due to the desirable properties (such as the small depth and self-routing capability) of banyan network structures. Although banyan-type networks result in severe blocking and crosstalk, both these problems can be minimized by using sufficient number of banyan planes in the VSOB network structure. The number of banyan planes is minimum for rearrangeably nonblocking and maximum for strictly nonblocking structure. Both results are available for VSOB networks when there exist no internal link-failures. Since the issue of link-failure is unavoidable, we intend to find the minimum number of planes required to make a VSOB network nonblocking when some links are broken or failed in the structure. This paper presents the approximate number of planes required to make a VSOB networks rearrangeably nonblocking allowing link-failures. We also show an interesting behavior of the  blocking  probability of a faulty VSOB networks that the blocking probability may not  always  increase monotonously with  the  increase  of  link-failures; blocking probability  decreases  for  certain range of  link-failures, and then increases again. We believe that such fluctuating behavior of blocking probability with the increase of link failure probability deserves special attention in switch design.  Keywords: Banyan networks; Blocking probability; Switching networks; Vertical stacking; Link-failures. © 2009 JSR Publications. ISSN: 2070-0237(Print); 2070-0245 (Online). All rights reserved. DOI: 10.3329/jsr.v1i1.1070


Author(s):  
B. G. Babayan ◽  
S. A. Bagdasaryan ◽  
M. A. Melkumyan ◽  
A. R. Mikaelyan

2009 ◽  
Vol 59 (12) ◽  
pp. 1400-1404
Author(s):  
Marius Tudorascu ◽  
Spiridon Oprea ◽  
Afrodita Doina Marculescu ◽  
Stefania Tudorascu

The mechanism of the enzymatic iodination process of diethylmaleate and diethylfumarate (which present no miscibility with water) in the presence of lactoperoxidase, both in diluted hydrogen peroxide solution and in a generating system of hydrogen peroxide using ammonium and calcium iodides as halide sources in disperse system (after an ultrasonic pretreatment) was studied. The obtained sole product (diethyl-2, 3-diiodosuccinate) after the enzymatic iodination process was directly hydrolyzed to a tartaric acid present in an optically inactive form. The mechanism of obtaining the intermediate and final products and respectively, the existence of both D, L-tartaric acid and meso-tartaric acids (as lithium bitartrates) were also investigated.


2018 ◽  
Vol 21 (4) ◽  
pp. 302-311
Author(s):  
Younes Ghalandarzehi ◽  
Mehdi Shahraki ◽  
Sayyed M. Habibi-Khorassani

Aim & Scope: The synthesis of highly substituted piperidine from the one-pot reaction between aromatic aldehydes, anilines and β-ketoesters in the presence of tartaric acid as a catalyst has been investigated in both methanol and ethanol media at ambient temperature. Different conditions of temperature and solvent were employed for calculating the thermodynamic parameters and obtaining an experimental approach to the kinetics and mechanism. Experiments were carried out under different temperature and solvent conditions. Material and Methods: Products were characterized by comparison of physical data with authentic samples and spectroscopic data (IR and NMR). Rate constants are presented as an average of several kinetic runs (at least 6-10) and are reproducible within ± 3%. The overall rate of reaction is followed by monitoring the absorbance changes of the products versus time on a Varian (Model Cary Bio- 300) UV-vis spectrophotometer with a 10 mm light-path cell. Results: The best result was achieved in the presence of 0.075 g (0.1 M) of catalyst and 5 mL methanol at ambient temperature. When the reaction was carried out under solvent-free conditions, the product was obtained in a moderate yield (25%). Methanol was optimized as a desirable solvent in the synthesis of piperidine, nevertheless, ethanol in a kinetic investigation had none effect on the enhancement of the reaction rate than methanol. Based on the spectral data, the overall order of the reaction followed the second order kinetics. The results showed that the first step of the reaction mechanism is a rate determining step. Conclusion: The use of tartaric acid has many advantages such as mild reaction conditions, simple and readily available precursors and inexpensive catalyst. The proposed mechanism was confirmed by experimental results and a steady state approximation.


GEOgraphia ◽  
2018 ◽  
Vol 19 (41) ◽  
pp. 123
Author(s):  
Gustavo Souza Valladares ◽  
Cláudia Maria Sabóia de Aquino ◽  
Renê Pedro de Aquino ◽  
Raphael Moreira Beirigo

Resumo: O Parque Nacional da Serra da Capivara (PNSC) tem alguns dos sítios arqueológicos mais importantes das Américas. A área onde os solos foram amostrados corresponde ao Parque Nacional da Serra da Capivara (PNSC) e uma área tampão de 10km no entorno de seus limites oficiais, no sudeste do Piauí. Para a elaboração do presente trabalho foram selecionados solos considerados frágeis, devido ao alto risco de degradação por erosão, formados de diferentes materiais geológicos representativos do PNSC. Todos os solos estudados são pouco evoluídos, com desenvolvimento pedogenético ainda incipiente, e enquadram-se nas ordens dos Neossolos ou Cambissolos. O bioma representativo da área de estudo é a caatinga, que pela vegetação com pouca biomassa e características decíduas confere pouca cobertura aos solos, aumentando a susceptibilidade dos mesmos à erosão. Foram coletados sete perfis de solos, em diferentes posições na paisagem e formados de materiais de origem. As amostras foram secas ao ar e analisados atributos químicos e granulométricos. Os solos estudados apresentam grandes variações em seus atributos morfológicos, químicos e granulométricos, reflexo dos diferentes materiais de origem. A fragilidade em quase todos os perfis é reflexo da incipiência dos solos, representada pelo baixo grau de agregação e coesão entre as partículas, pequena profundidade e o fator de formação relevo induz na maior erosão de cinco dos sete perfis estudados. Os solos frágeis do PNSC necessitam de cuidados especiais quanto ao manejo, pois alguns deles, principalmente os originários de rochas pelíticas da Formação Pimenteiras, encontram-se em forte processo de degradação, em muitas áreas com as rochas expostas. Palavras-chave: Conservação do solo. Classificação de solos. Degradação ambiental. Semiárido tropical. FRAGILE SOILS OF SERRA DA CAPIVARA NATIONAL PARK, PIAUÍ Abstract: The Serra da Capivara National Park (PNSC) are some of the most important archaeological sites in the Americas. The area where the soils were sampled corresponds to the PNSC and a buffer area of 10km around of its official limits in southeastern of Piauí. For this work were considered fragile soils, due to the high risk of degradation by erosion, formed in different geological materials representative of PNSC. All soils are poorly evolved, with pedogenic development incipient fall in orders of Entisols or Inceptisols. The representative of the study area biome is the caatinga, which vegetation with little biomass and deciduous characteristics, gives little coverage to the soil, increasing susceptibility to erosion. Seven soil profiles were collected at different positions and mother rocks. The soils were classified according to the Brazilian System of Soil Classification (SiBCS). The samples were air dried and analyzed the chemical attributes and texture. The soils vary widely in their morphological, chemical and grain size, reflecting the different source material attributes. The weakness in nearly all profiles reflects the incipient soil, represented by a low degree of aggregation and cohesion between the particles of soil and small depth of relief factor induces the formation of further erosion profiles 5 of the 7 studied. Fragile soils of PNSC require special care in the mangement, because some soils, especially those originating from pelitic rocks by Pimenteiras Formation, are in strong degradation process in many areas with exposed rocks. Keywords: Soil conservation. Soil classification. Environmental degradation. Tropical semiarid. SUELOS FRÁGILES DEL PARQUE NACIONAL DE LA SIERRA DE CAPYBARA, PIAUÍ Resumen: El Parque Nacional de la Sierra de Capybara (PNSC) tiene algunos de los sitios arqueológicos más importantes de las Américas. El área donde los suelos fueron muestreados corresponde al PNSC y un área tampón de 10km en el entorno de sus límites oficiales, en el sureste del Piauí. Para la elaboración del presente trabajo se seleccionaron suelos considerados frágiles, debido al alto riesgo de degradación por erosión, formados de diferentes materiales geológicos representativos del PNSC. Todos los suelos estudiados son poco evolucionados, con desarrollo pedogenético aún incipiente, y se encuadran en las órdenes de los Neossolos o Cambissolos (en portugués). El bioma representativo del área de estudio es la caatinga, que por la vegetación con poca biomasa y características deciduas, confiere poca cobertura a los suelos, aumentando la susceptibilidad de los mismos a la erosión. Se recogieron muestras de siete perfiles de suelos, en diferentes posiciones en el paisaje y formados de materiales geológicos distintos. Las muestras fueron secas al aire y analizados los atributos químicos y granulométricos. Los suelos estudiados presentan grandes variaciones en sus atributos morfológicos, químicos y granulométricos, reflejo de los diferentes materiales de origen. La fragilidad en casi todos los perfiles es reflejo de la incipiente de los suelos, representada por el bajo grado de agregación y cohesión entre las partículas, pequeña profundidad y el factor de formación relieve induce en la mayor erosión de cinco de los siete perfiles estudiados. Los suelos frágiles del PNSC necesitan cuidados especiales en cuanto al manejo, pues algunos de ellos, principalmente los originarios de rocas pelíticas de la Formación Pimenteiras, se encuentran en fuerte proceso de degradación, en muchas áreas con las rocas expuestas. Palabras clave: Conservación del suelo. Clasificación de suelos. Degradación ambiental. Semiárido tropical.


1983 ◽  
Vol 48 (11) ◽  
pp. 3223-3228 ◽  
Author(s):  
Peter Ševčík ◽  
Ľubica Adamčíková

The kinetic parameters of the reaction steps of the oscillation cycle and the parameters of modified oscillation reactions of the Belousov-Zhabotinskii (BZ) type with oxalic acid, tartaric acid, and hypophosphite ions were compared with predictions of Edelson's analysis based on the mechanism of the classical BZ reaction.


Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2277
Author(s):  
Piotr M. Kuś ◽  
Igor Jerković

Recently, we proposed a new sample preparation method involving reduced solvent and sample usage, based on dehydration homogeneous liquid–liquid extraction (DHLLE) for the screening of volatiles and semi-volatiles from honey. In the present research, the method was applied to a wide range of honeys (21 different representative unifloral samples) to determine its suitability for detecting characteristic honey compounds from different chemical classes. GC-FID/MS disclosed 130 compounds from different structural and chemical groups. The DHLLE method allowed the extraction and identification of a wide range of previously reported specific and nonspecific marker compounds belonging to different chemical groups (including monoterpenes, norisoprenoids, benzene derivatives, or nitrogen compounds). For example, DHLLE allowed the detection of cornflower honey chemical markers: 3-oxo-retro-α-ionols, 3,4-dihydro-3-oxoedulan, phenyllactic acid; coffee honey markers: theobromine and caffeine; linden honey markers: 4-isopropenylcyclohexa-1,3-diene-1-carboxylic acid and 4-(2-hydroxy-2-propanyl)cyclohexa-1,3-diene-1-carboxylic acid, as well as furan derivatives from buckwheat honey. The obtained results were comparable with the previously reported data on markers of various honey varieties. Considering the application of much lower volumes of very common reagents, DHLLE may provide economical and ecological advantages as an alternative sample preparation method for routine purposes.


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